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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2E)-6-chloro-2-(6-chloro-3-oxo-1-benzothiophen-2-ylidene)-4-methyl-1-benzothiophen-3-one —— C17H8Cl2O2S2
    (2E)-6-chloro-2-(6-chloro-3-oxo-1-benzothiophen-2-ylidene)-4-methyl-1-benzothiophen-3-one
    —— 2,2,11,11-tetra(methyleneamine)-4,9-dithiadodecane 688310-92-1 C14H34N4S2
    2,2,11,11-tetra(methyleneamine)-4,9-dithiadodecane
    —— (2-Thioxo-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-5-yl)-acetonitrile 690253-18-0 C7H5NS5
    (2-Thioxo-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-5-yl)-acetonitrile
    —— (2S,3S,4S)-2-Bromo-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-5-phenylsulfanyl-pentanoic acid methyl ester 688364-62-7 C19H31BrO3SSi
    (2S,3S,4S)-2-Bromo-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-5-phenylsulfanyl-pentanoic acid methyl ester
    —— 2,2,10,10-tetra(methyleneamine)-4,8-dithiaundecane 688310-82-9 C13H32N4S2
    2,2,10,10-tetra(methyleneamine)-4,8-dithiaundecane
    —— 1-methylsulfanyl-1-methylsulfinylpent-1-ene 68992-45-0 C7H14OS2
    1-methylsulfanyl-1-methylsulfinylpent-1-ene
    —— 6-(3-choloropropyl)-4-(phenylthio)-1,2,5,6-tetrahydro-2-pyridinone 871950-82-2 C14H16ClNOS
    6-(3-choloropropyl)-4-(phenylthio)-1,2,5,6-tetrahydro-2-pyridinone
    —— 4-[2-(3-oxo-propyl)-1,3-dithian-2-yl]-but-2-enal 871469-07-7 C11H16O2S2
    4-[2-(3-oxo-propyl)-1,3-dithian-2-yl]-but-2-enal
    —— (Z)-3-Chloro-2-methyl-3-p-tolylsulfanyl-prop-2-en-1-ol 883106-85-2 C11H13ClOS
    (Z)-3-Chloro-2-methyl-3-p-tolylsulfanyl-prop-2-en-1-ol
    —— 879416-74-7 C24H41ClSSn
    —— O-methyl N-methyl-N-(methylamino)carbamothioate 802309-88-2 C4H10N2OS
    O-methyl N-methyl-N-(methylamino)carbamothioate
    —— 4-[2-(3-Methoxymethoxy-propyl)-[1,3]dithian-2-yl]-1-nitro-butan-2-ol 909036-08-4 C13H25NO5S2
    4-[2-(3-Methoxymethoxy-propyl)-[1,3]dithian-2-yl]-1-nitro-butan-2-ol
    —— 2-(2,2,2-Trifluoro-ethylsulfanyl)-pyrimidin-5-ol 914377-37-0 C6H5F3N2OS
    2-(2,2,2-Trifluoro-ethylsulfanyl)-pyrimidin-5-ol
    —— (2R,3R,4R,5R)-5-(methoxymethoxy)-3,4-(methylenedioxy)-2-(trifluoroacetamido)cyclohexanone propane-1,3-diyl dithioacetal 911387-97-8 C14H20F3NO5S2
    (2R,3R,4R,5R)-5-(methoxymethoxy)-3,4-(methylenedioxy)-2-(trifluoroacetamido)cyclohexanone propane-1,3-diyl dithioacetal
    —— (2R,3R,4R,5R)-2-acetamido-5-(methoxymethoxy)-3,4-(methylenedioxy)cyclohexanone propane-1,3-diyl dithioacetal 911387-93-4 C14H23NO5S2
    (2R,3R,4R,5R)-2-acetamido-5-(methoxymethoxy)-3,4-(methylenedioxy)cyclohexanone propane-1,3-diyl dithioacetal
    —— 926036-84-2 C22H12S6
    —— 926036-83-1 C22H12S6
    —— <3>staffane-3,3''-dithiol 145384-33-4 C15H20S2
    <3>staffane-3,3''-dithiol
    —— 1,4-dithiino[2,3-c;5,6-c']dipyridine 5-oxide 1004986-49-5 C10H6N2OS2
    1,4-dithiino[2,3-c;5,6-c']dipyridine 5-oxide
    —— N-tert-butyl-2-(benzo[d][1,3]dioxol-5-ylthio)benzamide 1002759-98-9 C18H19NO3S
    N-tert-butyl-2-(benzo[d][1,3]dioxol-5-ylthio)benzamide
    —— 2-(6-methoxypyridin-3-ylthio)-N-tert-butylbenzamide 1002759-99-0 C17H20N2O2S
    2-(6-methoxypyridin-3-ylthio)-N-tert-butylbenzamide
    —— 1,4-dithiino[2,3-c;6,5-c']dipyridine 10-oxide 1004986-51-9 C10H6N2OS2
    1,4-dithiino[2,3-c;6,5-c']dipyridine 10-oxide
    —— 11,24-Bis[4,5-bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-2,2,7,7,15,15,20,20-octamethyl-10,12,23,25,28,30-hexathia-27,29-diazaheptacyclo[19.5.1.13,6.18,14.116,19.09,13.022,26]triaconta-1(26),3,5,8,13,16,18,21-octaene 1000874-46-3 C48H58N2S14
    11,24-Bis[4,5-bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-2,2,7,7,15,15,20,20-octamethyl-10,12,23,25,28,30-hexathia-27,29-diazaheptacyclo[19.5.1.13,6.18,14.116,19.09,13.022,26]triaconta-1(26),3,5,8,13,16,18,21-octaene
    —— 1-(2-(2-methoxyethoxy)ethyl)-3-methylthiourea 1253053-91-6 C7H16N2O2S
    1-(2-(2-methoxyethoxy)ethyl)-3-methylthiourea
    —— 7,10,13,21,24,27-Hexamethyl-3,17-diphenyl-30,33-dithia-7,10,13,21,24,27-hexazatetracyclo[13.13.6.05,29.019,34]tetratriaconta-1,3,5(29),15(34),16,18-hexaene 1006056-73-0 C44H60N6S2
    7,10,13,21,24,27-Hexamethyl-3,17-diphenyl-30,33-dithia-7,10,13,21,24,27-hexazatetracyclo[13.13.6.05,29.019,34]tetratriaconta-1,3,5(29),15(34),16,18-hexaene
    —— 1,4-bis(5-amino-6-cyano-2-thioxothiopyrano[2,3-d]thiazolyl)benzene 1019848-50-0 C20H12N6S6
    1,4-bis(5-amino-6-cyano-2-thioxothiopyrano[2,3-d]thiazolyl)benzene
    —— 1,1'-thio-bis-(2-(1-oxa-3-oxo-4-aza-6-chlorohexyl)-naphthalene) 1198335-35-1 C28H26Cl2N2O4S
    1,1'-thio-bis-(2-(1-oxa-3-oxo-4-aza-6-chlorohexyl)-naphthalene)
    —— 3,3'-(o-dithiophenyl)-dipropionic acid 1160124-78-6 C12H14O4S2
    3,3'-(o-dithiophenyl)-dipropionic acid
    —— [(3'aR,5'R,7'aR)-2',2'-dimethylspiro[1,3-dithiane-2,7'-4,5,6,7a-tetrahydro-3aH-1,3-benzodioxole]-5'-yl]methanol 1166841-79-7 C13H22O3S2
    [(3'aR,5'R,7'aR)-2',2'-dimethylspiro[1,3-dithiane-2,7'-4,5,6,7a-tetrahydro-3aH-1,3-benzodioxole]-5'-yl]methanol
    —— 1-[(3aR,4R,6S,6aS)-2-methoxy-6-(phenylsulfanylmethyl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl]pyrimidine-2,4-dione 1167433-54-6 C17H18N2O6S
    1-[(3aR,4R,6S,6aS)-2-methoxy-6-(phenylsulfanylmethyl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl]pyrimidine-2,4-dione
    —— 4,5-dihydro-2H-benzo[b]thiocin-6(3H)-one 1158077-88-3 C11H12OS
    4,5-dihydro-2H-benzo[b]thiocin-6(3H)-one
    —— 1,5-anhydro-D-tagatose diethyldithioacetal 1169759-57-2 C10H20O4S2
    1,5-anhydro-D-tagatose diethyldithioacetal
    —— (R)-(+)-4-hydroxy-1-(1'-phenyl-ethyl)-3-methylsulfanyl-1H-pyridin-2-one 1174637-76-3 C14H15NO2S
    (R)-(+)-4-hydroxy-1-(1'-phenyl-ethyl)-3-methylsulfanyl-1H-pyridin-2-one
    —— (+/-)-4-methyl-4,5-dihydro-2H-benzo[b]thiocin-6(3H)-one 1158077-91-8 C12H14OS
    (+/-)-4-methyl-4,5-dihydro-2H-benzo[b]thiocin-6(3H)-one
    —— Tert-butyl 4,12-dimethyl-13-[2-(4-methylphenyl)sulfanylethyl]-11-oxo-5-(3-oxo-3-prop-2-enoxypropyl)-7,10-diazatricyclo[8.3.0.03,7]trideca-1,3,5,12-tetraene-6-carboxylate 1182308-02-6 C33H40N2O5S
    Tert-butyl 4,12-dimethyl-13-[2-(4-methylphenyl)sulfanylethyl]-11-oxo-5-(3-oxo-3-prop-2-enoxypropyl)-7,10-diazatricyclo[8.3.0.03,7]trideca-1,3,5,12-tetraene-6-carboxylate
    —— 1,4-Bis(prop-2-enylsulfanyl)butane 1173006-63-7 C10H18S2
    1,4-Bis(prop-2-enylsulfanyl)butane
    —— (4S,5S,e)-6-(2-((R)-1-methoxyallyl)-1,3-dithian-2-yl)-5-((2-methoxyethoxy)methoxy)-2,4-dimethylhex-2-enal 1141748-06-2 C20H34O5S2
    (4S,5S,e)-6-(2-((R)-1-methoxyallyl)-1,3-dithian-2-yl)-5-((2-methoxyethoxy)methoxy)-2,4-dimethylhex-2-enal
    —— 2,5-dibromo-3,4-ethylenedithioselenophene 1186372-58-6 C6H4Br2S2Se
    2,5-dibromo-3,4-ethylenedithioselenophene
    —— 2,3-dichloro-1,1,4,4-tetrakis(4-pyridylsulfanyl)buta-1,3-diene 1189129-96-1 C24H16Cl2N4S4
    2,3-dichloro-1,1,4,4-tetrakis(4-pyridylsulfanyl)buta-1,3-diene
    —— 1-(3,5-O-isopropylidene-2-deoxy-2-(p-thiocresyl)-α-D-xylofuranosyl)-3-propene 1185748-19-9 C18H24O3S
    1-(3,5-O-isopropylidene-2-deoxy-2-(p-thiocresyl)-α-D-xylofuranosyl)-3-propene
    —— 5-Chloro-2-(1-methylethoxy)-3-(phenylthio)pyrazine 1194041-66-1 C13H13ClN2OS
    5-Chloro-2-(1-methylethoxy)-3-(phenylthio)pyrazine
    —— 6-methoxy-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198405-90-1 C11H11N7O3S
    6-methoxy-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— (2S)-1-[2-(2,2-diethoxyethyl)-1,3-dithian-2-yl]pent-4-en-2-ol 1169687-59-5 C15H28O3S2
    (2S)-1-[2-(2,2-diethoxyethyl)-1,3-dithian-2-yl]pent-4-en-2-ol
    —— 14,38,62,86-Tetrakis[4,5-bis(butylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(3),1,4(24),12(16),25,27,36(40),48,50,52(72),60(64),73(98),75(97),76(96),84(88)-pentadecaene 1220349-54-1 C104H138N8O8S40
    14,38,62,86-Tetrakis[4,5-bis(butylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(3),1,4(24),12(16),25,27,36(40),48,50,52(72),60(64),73(98),75(97),76(96),84(88)-pentadecaene
    —— [(E,3R,4R)-4-[cyclopentyl-[(2S)-1-[2-(2,2-diethoxyethyl)-1,3-dithian-2-yl]pent-4-en-2-yl]oxy-ethynylsilyl]oxy-3-methylhept-5-enyl] 2,2-dimethylpropanoate 1169687-56-2 C35H60O6S2Si
    [(E,3R,4R)-4-[cyclopentyl-[(2S)-1-[2-(2,2-diethoxyethyl)-1,3-dithian-2-yl]pent-4-en-2-yl]oxy-ethynylsilyl]oxy-3-methylhept-5-enyl] 2,2-dimethylpropanoate
    —— 6-allylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198405-99-0 C13H13N7O2S2
    6-allylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— N-acetyl-5-p-tolylsulfanyl-3,3-dimethylindoline 1190867-41-4 C19H21NOS
    N-acetyl-5-p-tolylsulfanyl-3,3-dimethylindoline
    —— 6-methylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198405-98-9 C11H11N7O2S2
    6-methylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— 6-benzyloxy-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198405-92-3 C17H15N7O3S
    6-benzyloxy-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— (R)-2,2,2-trifluoro-1-(4'-methylsulfanylphenyl)ethanol 1135312-04-7 C9H9F3OS
    (R)-2,2,2-trifluoro-1-(4'-methylsulfanylphenyl)ethanol