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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-chloro-1-(isopropylsulfonyl)propan-2-one 1271024-75-9 C6H11ClO3S
    1-chloro-1-(isopropylsulfonyl)propan-2-one
    —— 4-[4-(3-isopropyl-[1,2,4]oxadiazol-5-yl)-piperidin-1-yl]-6-(6-methylsulfanyl-pyridin-3-ylamino)-pyrimidine-5-carbonitrile 733751-24-1 C21H24N8OS
    4-[4-(3-isopropyl-[1,2,4]oxadiazol-5-yl)-piperidin-1-yl]-6-(6-methylsulfanyl-pyridin-3-ylamino)-pyrimidine-5-carbonitrile
    —— (2R)-2-[[2-amino-5-[(2-chlorophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol 463953-94-8 C18H22ClN5OS2
    (2R)-2-[[2-amino-5-[(2-chlorophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol
    —— 3-(2,5-difluorophenylthio)cyclobutanone 1080636-90-3 C10H8F2OS
    3-(2,5-difluorophenylthio)cyclobutanone
    —— 2-Propanol, 1-[(2,4-difluorophenyl)thio]-3-methoxy- 1340168-51-5 C10H12F2O2S
    2-Propanol, 1-[(2,4-difluorophenyl)thio]-3-methoxy-
    —— 4-[6-(1,2,3,9b-Tetraaza-cyclopenta[a]naphthalen-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile 944924-17-8 C20H16N6OS
    4-[6-(1,2,3,9b-Tetraaza-cyclopenta[a]naphthalen-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile
    —— 5-bromo-2-(2-(methylthio)thiazol-5-yl)pyridine 1190219-73-8 C9H7BrN2S2
    5-bromo-2-(2-(methylthio)thiazol-5-yl)pyridine
    —— 4-[3-(2-Hydrazino-quinolin-6-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 1056615-95-2 C21H20N4OS
    4-[3-(2-Hydrazino-quinolin-6-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(7-methoxy-6-(2-(methylsulfonyl)ethoxy)quinazolin-4-ylthio)phenyl)urea 1188907-87-0 C26H29N5O6S2
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(7-methoxy-6-(2-(methylsulfonyl)ethoxy)quinazolin-4-ylthio)phenyl)urea
    —— 4-[6-([1,2,4]Triazolo[1,5-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile 944924-11-2 C21H17N5OS
    4-[6-([1,2,4]Triazolo[1,5-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile
    —— 1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(3-methoxy-5-(trifluoromethyl)phenyl)urea 1188908-40-8 C25H21F3N4O4S
    1-(3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl)-3-(3-methoxy-5-(trifluoromethyl)phenyl)urea
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-(piperidin-1-yl)ethoxy)quinazolin-4-ylthio)phenyl)urea 1188907-79-0 C30H36N6O4S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-(piperidin-1-yl)ethoxy)quinazolin-4-ylthio)phenyl)urea
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-morpholinoethoxy)quinazolin-4-ylthio)phenyl)urea 1188907-70-1 C29H34N6O5S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-morpholinoethoxy)quinazolin-4-ylthio)phenyl)urea
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(7-(2-(4-(2-hydroxyethyl)piperazin-1-yl)ethoxy)-6-methoxyquinazolin-4-ylthio)phenyl)urea 1188907-83-6 C31H39N7O5S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(7-(2-(4-(2-hydroxyethyl)piperazin-1-yl)ethoxy)-6-methoxyquinazolin-4-ylthio)phenyl)urea
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-ethoxy-7-methoxyquinazolin-4-ylthio)phenyl)urea 1188907-53-0 C25H27N5O4S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-ethoxy-7-methoxyquinazolin-4-ylthio)phenyl)urea
    —— 1-(4-methoxy-3-(trifluoromethyl)phenyl)-3-(3-(7-methoxy-6-(3-(4,4-dioxothiomorpholino)propoxy)quinazolin-4-ylthio)phenyl)urea 1188910-54-4 C31H32F3N5O6S2
    1-(4-methoxy-3-(trifluoromethyl)phenyl)-3-(3-(7-methoxy-6-(3-(4,4-dioxothiomorpholino)propoxy)quinazolin-4-ylthio)phenyl)urea
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-(4-methylpiperazin-1-yl)ethoxy)quinazolin-4-ylthio)phenyl)urea 1188907-82-5 C30H37N7O4S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(6-methoxy-7-(2-(4-methylpiperazin-1-yl)ethoxy)quinazolin-4-ylthio)phenyl)urea
    —— (2E)-3-amino-2-cyano-4,4-dimethylpent-2-enthioamide 41808-33-7 C8H13N3S
    (2E)-3-amino-2-cyano-4,4-dimethylpent-2-enthioamide
    —— (2-methylsulfanyl-ethyl)-thiourea 98026-13-2 C4H10N2S2
    (2-methylsulfanyl-ethyl)-thiourea
    —— 2-methyl-2-(2-methyl-propane-2-sulfonyl)-propionic acid 1017539-80-8 C8H16O4S
    2-methyl-2-(2-methyl-propane-2-sulfonyl)-propionic acid
    —— 6,6a(2)-Thiobis[3,4-dihydro-3-phenyl-2H-1,3-benzoxazine] 228118-04-5 C28H24N2O2S
    6,6a(2)-Thiobis[3,4-dihydro-3-phenyl-2H-1,3-benzoxazine]
    —— 4-dimethylamino-2-methylsulfanyl-6-morpholinopyrimidine 1190067-74-3 C11H18N4OS
    4-dimethylamino-2-methylsulfanyl-6-morpholinopyrimidine
    —— 5-fluoro-2-(2-amino-phenylsulfanyl)benzoic acid ethyl ester 1201672-75-4 C15H14FNO2S
    5-fluoro-2-(2-amino-phenylsulfanyl)benzoic acid ethyl ester
    —— 1-[4-Amino-3-(2-aminoethylsulfanyl)phenyl]pyridin-2-one 1039517-34-4 C13H15N3OS
    1-[4-Amino-3-(2-aminoethylsulfanyl)phenyl]pyridin-2-one
    —— Ethanesulfonyl chloride, 2-[(3-bromo-2-pyridinyl)thio]- 1342293-60-0 C7H7BrClNO2S2
    Ethanesulfonyl chloride, 2-[(3-bromo-2-pyridinyl)thio]-
    —— 3-(2-benzyloxy-5-cyclopropylmethyl-3-isopropyl-6-methyl-pyridin-4-ylsulfanyl)-5-methyl-benzonitrile 1205514-53-9 C28H30N2OS
    3-(2-benzyloxy-5-cyclopropylmethyl-3-isopropyl-6-methyl-pyridin-4-ylsulfanyl)-5-methyl-benzonitrile
    —— 2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoic acid 1192004-52-6 C13H20N2O3S
    2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoic acid
    —— 5-(3-cyclopropylmethyl-5-isopropyl-6-methoxy-2-methyl-pyridin-4-ylsulfanyl)-isophthalonitrile 1205514-42-6 C22H23N3OS
    5-(3-cyclopropylmethyl-5-isopropyl-6-methoxy-2-methyl-pyridin-4-ylsulfanyl)-isophthalonitrile
    —— 7-hydroxy-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one 1303510-46-4 C8H8N2O4S
    7-hydroxy-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one
    —— 7-Hydroxy-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one 1303510-58-8 C7H6N2O4S
    7-Hydroxy-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one
    —— 5-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-6-(tetrahydro-2H-pyran-4-yl)-1-{5-[(tetrahydro-2H-pyran-2-yloxy)methyl]-1,3-thiazol-2-yl}hexane-1,4-dione 1192004-55-9 C25H35N3O5S2
    5-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-6-(tetrahydro-2H-pyran-4-yl)-1-{5-[(tetrahydro-2H-pyran-2-yloxy)methyl]-1,3-thiazol-2-yl}hexane-1,4-dione
    —— N-Carbamothioylethanethioamide 91936-07-1 C3H6N2S2
    N-Carbamothioylethanethioamide
    —— (3-Bromo-4-((methoxymethoxy)methyl)phenyl)(phenyl)sulfane 1226773-52-9 C15H15BrO2S
    (3-Bromo-4-((methoxymethoxy)methyl)phenyl)(phenyl)sulfane
    —— Isopropyl-trimethyl-thioharnstoff 32773-12-9 C7H16N2S
    Isopropyl-trimethyl-thioharnstoff
    —— Propanamide, 2-methyl-2-(methylsulfonyl)-N-2-propen-1-yl- 1341845-76-8 C8H15NO3S
    Propanamide, 2-methyl-2-(methylsulfonyl)-N-2-propen-1-yl-
    —— Cyclopentanemethanamine, N-[2-(ethylsulfonyl)ethyl]-I+/--methyl- 1342595-29-2 C11H23NO2S
    Cyclopentanemethanamine, N-[2-(ethylsulfonyl)ethyl]-I+/--methyl-
    —— 3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid 1227843-19-7 C12H8ClNO2S
    3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid
    —— 3-aminomethyl-6-[(3,3-dimethylcyclohexyl)thio]-pyridine 928648-47-9 C14H22N2S
    3-aminomethyl-6-[(3,3-dimethylcyclohexyl)thio]-pyridine
    —— <3-Chlor-2-methyl-propyl>-ethyl-sulfid 13012-63-0 C6H13ClS
    <3-Chlor-2-methyl-propyl>-ethyl-sulfid
    —— 2-[2-(2-fluoromethylphenylsulfanyl)ethyl]aldehyde 758717-10-1 C10H11FOS
    2-[2-(2-fluoromethylphenylsulfanyl)ethyl]aldehyde
    —— 4-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine 96592-39-1 C10H12N4S
    4-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine
    —— 3-Pyridinamine, 2-[(1,1-dimethylethyl)thio]-4-methyl- 1344306-64-4 C10H16N2S
    3-Pyridinamine, 2-[(1,1-dimethylethyl)thio]-4-methyl-
    —— 2-Phenylthio-3-amino-4-methylpyridin 53421-01-5 C12H12N2S
    2-Phenylthio-3-amino-4-methylpyridin
    —— 2-Methylthio-4-hydroxy-6-fluormethyl-pyrimidin 6096-24-8 C6H7FN2OS
    2-Methylthio-4-hydroxy-6-fluormethyl-pyrimidin
    —— 3,3-dimethyl-2H-1-benzothiophene-6-carboxylic acid 874279-53-5 C11H12O2S
    3,3-dimethyl-2H-1-benzothiophene-6-carboxylic acid
    —— N-[3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenyl]-benzenesulfonamide 1184181-73-4 C21H20N2O6S2
    N-[3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenyl]-benzenesulfonamide
    —— 2-Pyrazinecarboxylic acid, 5-(2-pyrazinylthio)- 1344240-98-7 C9H6N4O2S
    2-Pyrazinecarboxylic acid, 5-(2-pyrazinylthio)-
    —— 3,3-dimethyl-2H-1-benzothiophene-4-carboxylic acid 874279-52-4 C11H12O2S
    3,3-dimethyl-2H-1-benzothiophene-4-carboxylic acid
    —— ethyl N-(4-sulfanylbutoxy)ethanimidate 60302-08-1 C8H17NO2S
    ethyl N-(4-sulfanylbutoxy)ethanimidate
    —— ethyl 4-ethyl-2-oxo-6-[4-(methylthio)phenyl]-2H-pyran-3-carboxylate 675618-12-9 C17H18O4S
    ethyl 4-ethyl-2-oxo-6-[4-(methylthio)phenyl]-2H-pyran-3-carboxylate