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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-hydroxybutyl octyl sulfone 68749-08-6 C12H26O3S
    4-hydroxybutyl octyl sulfone
    —— (4R,6S)-2,2-dimethyl-4-phenylsulfanyl-6-(triisopropylsilyloxymethyl)-1,3-dioxane 732290-11-8 C22H38O3SSi
    (4R,6S)-2,2-dimethyl-4-phenylsulfanyl-6-(triisopropylsilyloxymethyl)-1,3-dioxane
    —— N-{6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4-pyrimidinyl}[1,3]thiazolo[5,4-b]pyridin-2-amine 1246034-60-5 C22H23N5O2S2
    N-{6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4-pyrimidinyl}[1,3]thiazolo[5,4-b]pyridin-2-amine
    —— 2-tert.-Butylthio-1-butanol 2327-14-2 C8H18OS
    2-tert.-Butylthio-1-butanol
    —— Thiazolidine, 3-(4-(5-iodo-2-pyridyl)thiobutyl)-, hydrochloride 41956-55-2 C12H18ClIN2S2
    Thiazolidine, 3-(4-(5-iodo-2-pyridyl)thiobutyl)-, hydrochloride
    —— (5R,6S,7R)-5-isopropyl-2,2,3,3,6,9,9,10,10-nonamethyl-7-((2-((S)-1-((4R,5S,6R)-2,2,5-trimethyl-6-((triisopropylsilyloxy)methyl)-1,3-dioxan-4-yl)ethyl)-1,3-dithian-2-yl)methyl)-4,8-dioxa-3,9-disilaundecane 1373047-93-8 C43H90O5S2Si3
    (5R,6S,7R)-5-isopropyl-2,2,3,3,6,9,9,10,10-nonamethyl-7-((2-((S)-1-((4R,5S,6R)-2,2,5-trimethyl-6-((triisopropylsilyloxy)methyl)-1,3-dioxan-4-yl)ethyl)-1,3-dithian-2-yl)methyl)-4,8-dioxa-3,9-disilaundecane
    —— Thiazolidine, 3-(6-(5-iodo-2-pyridyl)thiohexyl)-, hydrochloride 41956-63-2 C14H22ClIN2S2
    Thiazolidine, 3-(6-(5-iodo-2-pyridyl)thiohexyl)-, hydrochloride
    —— 1-Methyl-5-(3-acetylpropyl)thio-1,2,3,4-tetrazole 80087-31-6 C7H12N4OS
    1-Methyl-5-(3-acetylpropyl)thio-1,2,3,4-tetrazole
    —— Thiazolidine, 3-(3-(5-chloro-2-pyridyl)thiopropyl)-, hydrochloride 41956-51-8 C11H16Cl2N2S2
    Thiazolidine, 3-(3-(5-chloro-2-pyridyl)thiopropyl)-, hydrochloride
    —— 2-methyl-2-(3'-chloropropyl)-1,3-dithiane 144227-07-6 C8H15ClS2
    2-methyl-2-(3'-chloropropyl)-1,3-dithiane
    —— Thiazolidine, 3-(5-(5-iodo-2-pyridyl)thiopentyl)-, hydrochloride 41956-59-6 C13H20ClIN2S2
    Thiazolidine, 3-(5-(5-iodo-2-pyridyl)thiopentyl)-, hydrochloride
    —— Thiazolidine, 3-(5-(5-chloro-2-pyridyl)thiopentyl)-, dihydrochloride 41956-58-5 C13H21Cl3N2S2
    Thiazolidine, 3-(5-(5-chloro-2-pyridyl)thiopentyl)-, dihydrochloride
    —— Thiazolidine, 3-(4-(5-chloro-2-pyridyl)thiobutyl)-, hydrochloride 41922-69-4 C12H18Cl2N2S2
    Thiazolidine, 3-(4-(5-chloro-2-pyridyl)thiobutyl)-, hydrochloride
    —— <Benzthiazolyl-(2)>-<5-chlor-pyridyl-(2)>-sulfid 19954-09-7 C12H7ClN2S2
    <Benzthiazolyl-(2)>-<5-chlor-pyridyl-(2)>-sulfid
    —— 3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid methyl ester 1227843-18-6 C13H10ClNO2S
    3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid methyl ester
    —— 1-chloro-2-(3-fluoro-phenylsulfanyl)-3-methoxy-benzene 791642-70-1 C13H10ClFOS
    1-chloro-2-(3-fluoro-phenylsulfanyl)-3-methoxy-benzene
    —— 5-tert.-Butylsulfonyl-pentanol-2 62296-32-6 C9H20O2S
    5-tert.-Butylsulfonyl-pentanol-2
    —— 2-(2-phenylsulfanyl-1H-indol-3-ylmethyl)-malonic acid dimethyl ester 499970-30-8 C20H19NO4S
    2-(2-phenylsulfanyl-1H-indol-3-ylmethyl)-malonic acid dimethyl ester
    —— (Z)-8-methyl-1,4-dithiacyclooct-7-ene 144227-16-7 C7H12S2
    (Z)-8-methyl-1,4-dithiacyclooct-7-ene
    —— 2-methyl-2-(3'-chloropropyl)-1,3-dithiolane 144227-06-5 C7H13ClS2
    2-methyl-2-(3'-chloropropyl)-1,3-dithiolane
    —— 8-methylene-1,4-dithiacyclooctane 144227-20-3 C7H12S2
    8-methylene-1,4-dithiacyclooctane
    —— 3-[8-(5-chloropyridin-2-yl)sulfanyloctyl]-1,3-thiazolidine;hydron;chloride —— C16H26Cl2N2S2
    3-[8-(5-chloropyridin-2-yl)sulfanyloctyl]-1,3-thiazolidine;hydron;chloride
    —— (E)-1-acetoxy-2-phenylthiopent-1-ene 123630-46-6 C13H16O2S
    (E)-1-acetoxy-2-phenylthiopent-1-ene
    —— (E)-2-acetoxy-1-phenylthiopent-1-ene 123630-45-5 C13H16O2S
    (E)-2-acetoxy-1-phenylthiopent-1-ene
    —— Thiazolidine, 3-(7-(5-bromo-2-pyridyl)thioheptyl)-, dihydrochloride 41956-65-4 C15H25BrCl2N2S2
    Thiazolidine, 3-(7-(5-bromo-2-pyridyl)thioheptyl)-, dihydrochloride
    —— Thiazolidine, 3-(3-(3,5-dichloro-2-pyridyl)thiopropyl)-, hydrochloride 41956-50-7 C11H15Cl3N2S2
    Thiazolidine, 3-(3-(3,5-dichloro-2-pyridyl)thiopropyl)-, hydrochloride
    —— Thiazolidine, 3-(5-(5-bromo-2-pyridyl)thiopentyl)-, hydrochloride 41956-57-4 C13H20BrClN2S2
    Thiazolidine, 3-(5-(5-bromo-2-pyridyl)thiopentyl)-, hydrochloride
    —— hydron;1-(3-phenylsulfanylpropyl)piperidine;chloride —— C14H22ClNS
    hydron;1-(3-phenylsulfanylpropyl)piperidine;chloride
    —— 2-(dodecylsulfinyl)acetic acid 13887-91-7 C14H28O3S
    2-(dodecylsulfinyl)acetic acid
    —— Thiazolidine, 3-(3-(5-iodo-2-pyridyl)thiopropyl)-, hydrochloride 41956-52-9 C11H16ClIN2S2
    Thiazolidine, 3-(3-(5-iodo-2-pyridyl)thiopropyl)-, hydrochloride
    —— alpha-(2-Phenylthioethyl)-alpha-(2-diethylaminoethyl)phenylacetonitrile hydrochloride 41932-66-5 C22H29ClN2S
    alpha-(2-Phenylthioethyl)-alpha-(2-diethylaminoethyl)phenylacetonitrile hydrochloride
    —— 4-propyl-4-(methylthio)-3-methyl-1-heptene 94202-95-6 C12H24S
    4-propyl-4-(methylthio)-3-methyl-1-heptene
    —— 3-[4-(3,5-dichloropyridin-2-yl)sulfanylbutyl]-1,3-thiazolidine;hydron;chloride —— C12H17Cl3N2S2
    3-[4-(3,5-dichloropyridin-2-yl)sulfanylbutyl]-1,3-thiazolidine;hydron;chloride
    —— 2-[2-(Diethylamino)ethyl]-2-phenyl-4-phenylsulfanylbutanenitrile 41932-65-4 C22H28N2S
    2-[2-(Diethylamino)ethyl]-2-phenyl-4-phenylsulfanylbutanenitrile
    —— Thiazolidine, 3-(7-(5-iodo-2-pyridyl)thioheptyl)-, hydrochloride 41956-67-6 C15H24ClIN2S2
    Thiazolidine, 3-(7-(5-iodo-2-pyridyl)thioheptyl)-, hydrochloride
    —— Thiazolidine, 3-(4-(5-bromo-2-pyridyl)thiobutyl)-, hydrochloride 41956-54-1 C12H18BrClN2S2
    Thiazolidine, 3-(4-(5-bromo-2-pyridyl)thiobutyl)-, hydrochloride
    —— (o-CD3SC6H4)2PN(CH3)P(o-CD3SC6H4)2 892415-94-0 C29H31NP2S4
    (o-CD3SC6H4)2PN(CH3)P(o-CD3SC6H4)2
    —— Thiazolidine, 3-(6-(5-chloro-2-pyridyl)thiohexyl)-, hydrochloride 41956-62-1 C14H22Cl2N2S2
    Thiazolidine, 3-(6-(5-chloro-2-pyridyl)thiohexyl)-, hydrochloride
    —— Thiazolidine, 3-(6-(5-bromo-2-pyridyl)thiohexyl)-, hydrochloride 41956-61-0 C14H22BrClN2S2
    Thiazolidine, 3-(6-(5-bromo-2-pyridyl)thiohexyl)-, hydrochloride
    —— Thiazolidine, 3-(7-(3,5-dichloro-2-pyridyl)thioheptyl)-, hydrochloride 41956-64-3 C15H23Cl3N2S2
    Thiazolidine, 3-(7-(3,5-dichloro-2-pyridyl)thioheptyl)-, hydrochloride
    —— 1-[[4-amino-3-[2-(4-hydroxyphenyl)ethyl]-4H-1,2,4-triazol-5-yl]thioacetyl]-3-(2-thienyl)-5-phenyl-2-pyrazoline 1246567-66-7 C25H24N6O2S2
    1-[[4-amino-3-[2-(4-hydroxyphenyl)ethyl]-4H-1,2,4-triazol-5-yl]thioacetyl]-3-(2-thienyl)-5-phenyl-2-pyrazoline
    —— Thiazolidine, 3-(10-(3,5-dichloro-2-pyridyl)thiodecyl)-, hydrochloride 41956-70-1 C18H29Cl3N2S2
    Thiazolidine, 3-(10-(3,5-dichloro-2-pyridyl)thiodecyl)-, hydrochloride
    —— Thiazolidine, 3-(6-(3,5-dichloro-2-pyridyl)thiohexyl)-, hydrochloride 41956-60-9 C14H21Cl3N2S2
    Thiazolidine, 3-(6-(3,5-dichloro-2-pyridyl)thiohexyl)-, hydrochloride
    —— 2-methyl-2-(6-trifluoromethyl-pyridin-3-ylsulfanyl)-propionic acid ethyl ester 1004770-67-5 C12H14F3NO2S
    2-methyl-2-(6-trifluoromethyl-pyridin-3-ylsulfanyl)-propionic acid ethyl ester
    —— ethyl 2-(3-bromophenylsulphanyl)-2-methylpropionate 862767-73-5 C12H15BrO2S
    ethyl 2-(3-bromophenylsulphanyl)-2-methylpropionate
    —— 6,7-dichloro-1-benzothiophen-3(2H)-one 64791-34-0 C8H4Cl2OS
    6,7-dichloro-1-benzothiophen-3(2H)-one
    —— 3-[10-(5-chloropyridin-2-yl)sulfanyldecyl]-1,3-thiazolidine;hydron;dichloride —— C18H31Cl3N2S2
    3-[10-(5-chloropyridin-2-yl)sulfanyldecyl]-1,3-thiazolidine;hydron;dichloride
    —— 2-bromo-3,7,8,12,13,17,18-heptakis(octylsulfanyl)-5,10,15,20-21H,23H-porphyrazine 676520-51-7 C72H121BrN8S7
    2-bromo-3,7,8,12,13,17,18-heptakis(octylsulfanyl)-5,10,15,20-21H,23H-porphyrazine
    —— 4-Amino-4'-dimethylaminodiphenylsulfid 63029-16-3 C14H16N2S
    4-Amino-4'-dimethylaminodiphenylsulfid
    —— Thiazolidine, 3-(5-(3,5-dichloro-2-pyridyl)thiopentyl)-, hydrochloride 42258-25-3 C13H19Cl3N2S2
    Thiazolidine, 3-(5-(3,5-dichloro-2-pyridyl)thiopentyl)-, hydrochloride