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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(methylsulfonyl)-7-azido-2-heptanol 1346434-30-7 C8H17N3O3S
    1-(methylsulfonyl)-7-azido-2-heptanol
    —— 5-[(5-amino-4H-1,2,4-triazol-3-yl)thio]-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol 666752-79-0 C16H17F2N7O2S2
    5-[(5-amino-4H-1,2,4-triazol-3-yl)thio]-2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol
    —— S-Ethyl-N-propyl-isothioharnstoff 100319-27-5 C6H14N2S
    S-Ethyl-N-propyl-isothioharnstoff
    —— 5-(prop-2-yn-1-ylthio)-4H-1,2,4-triazol-3-amine 53918-44-8 C5H6N4S
    5-(prop-2-yn-1-ylthio)-4H-1,2,4-triazol-3-amine
    —— S-Methyl-N-propyl-isothioharnstoff 925-59-7 C5H12N2S
    S-Methyl-N-propyl-isothioharnstoff
    —— 6-ethylsulfanyl-5-methyl-3-oxo-2-phenyl-2,3-dihydro-pyridazine-4-carbonitrile 160146-42-9 C14H13N3OS
    6-ethylsulfanyl-5-methyl-3-oxo-2-phenyl-2,3-dihydro-pyridazine-4-carbonitrile
    —— 3-Ethylsulfanyl-5-phenyl-isothiazole-4-carbonitrile 223440-06-0 C12H10N2S2
    3-Ethylsulfanyl-5-phenyl-isothiazole-4-carbonitrile
    —— 3,3'-methylenebis(sulfanediyl)bis(5-phenylisothiazole-4-carbonitrile) 915395-64-1 C21H12N4S4
    3,3'-methylenebis(sulfanediyl)bis(5-phenylisothiazole-4-carbonitrile)
    —— 5-Ethyl-1-((cyclohexyloxy)methyl)-6-(phenylthio)-2-thiouracil 136160-41-3 C19H24N2O2S2
    5-Ethyl-1-((cyclohexyloxy)methyl)-6-(phenylthio)-2-thiouracil
    —— 5-Ethyl-1-(cyclohexyloxy)methyl)-6-(phenylthio)uracil 136160-40-2 C19H24N2O3S
    5-Ethyl-1-(cyclohexyloxy)methyl)-6-(phenylthio)uracil
    —— 5-amino-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide 1102466-92-1 C12H11BrN4O3S
    5-amino-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide
    —— 4,4-Bis(ethylsulfonyl)pimelonitril 62943-41-3 C11H18N2O4S2
    4,4-Bis(ethylsulfonyl)pimelonitril
    —— 6-[(6-amino-9H-purin-8-yl)thio]-1,3-benzodioxole-5-carbonitrile 958026-14-7 C13H8N6O2S
    6-[(6-amino-9H-purin-8-yl)thio]-1,3-benzodioxole-5-carbonitrile
    —— tert-butyl 4-(2-{6-amino-8-[(6-bromo-2,2-d<sub>2</sub>-benzo[d][1,3]dioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidine-1-carboxylate 1425565-36-1 C24H29BrN6O4S
    tert-butyl 4-(2-{6-amino-8-[(6-bromo-2,2-d<sub>2</sub>-benzo[d][1,3]dioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidine-1-carboxylate
    —— 8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-9-(pent-4-ynyl)adenine 873436-90-9 C17H14IN5O2S
    8-(6-iodo-benzo[1,3]dioxol-5-ylsulfanyl)-9-(pent-4-ynyl)adenine
    —— 8-[(6-bromo-2,2-difluoro-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-6-amine 958026-17-0 C12H6BrF2N5O2S
    8-[(6-bromo-2,2-difluoro-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-6-amine
    —— 8-(6-amino-2,3-dihydrobenzofuran-5-ylthio)-9H-purin-6-amine 1289544-20-2 C13H12N6OS
    8-(6-amino-2,3-dihydrobenzofuran-5-ylthio)-9H-purin-6-amine
    —— 8-[(7-nitro-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine 1156467-97-8 C13H10N6O4S
    8-[(7-nitro-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine
    —— 8-(2,3-dihydrobenzofuran-6-ylthio)-9H-purin-6-amine 1289544-14-4 C13H11N5OS
    8-(2,3-dihydrobenzofuran-6-ylthio)-9H-purin-6-amine
    —— 2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethanol 477533-78-1 C12H13NOS2
    2-(4-methyl-2-phenylsulfanylthiazol-5-yl)ethanol
    —— methyl (4-methyl-2-phenylsulfanylthiazol-5-yl)acetate 477533-77-0 C13H13NO2S2
    methyl (4-methyl-2-phenylsulfanylthiazol-5-yl)acetate
    —— 2-Bromo-7-chloro-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidine 333743-68-3 C12H5BrClF2N3S2
    2-Bromo-7-chloro-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidine
    —— 7-chloro-5-(2,3-difluoro-benzylsulfanyl)-3H-thiazolo[4,5-d]pyrimidin-2-one 333743-70-7 C12H6ClF2N3OS2
    7-chloro-5-(2,3-difluoro-benzylsulfanyl)-3H-thiazolo[4,5-d]pyrimidin-2-one
    —— 7-chloro-5-[(2,3-difluorophenylmethyl)thio]-2-methoxythiazolo[4,5-d]pyrimidine 333743-69-4 C13H8ClF2N3OS2
    7-chloro-5-[(2,3-difluorophenylmethyl)thio]-2-methoxythiazolo[4,5-d]pyrimidine
    —— 1,3,5-Oxadiazinane-4-thione 23375-59-9 C3H6N2OS
    1,3,5-Oxadiazinane-4-thione
    —— methyl [(2-bromo-4-chlorophenyl)thio]acetate 882689-77-2 C9H8BrClO2S
    methyl [(2-bromo-4-chlorophenyl)thio]acetate
    —— [(2-bromo-4-chlorophenyl)thio]acetic acid 882689-76-1 C8H6BrClO2S
    [(2-bromo-4-chlorophenyl)thio]acetic acid
    —— 1-phenylsulfanyl-2(S)-3-buten-2-ol 783322-43-0 C10H12OS
    1-phenylsulfanyl-2(S)-3-buten-2-ol
    —— Ethyl 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoate 676481-38-2 C30H33ClO5S
    Ethyl 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoate
    —— 5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoic acid 676481-42-8 C28H29ClO5S
    5-[4-(3-benzyloxyphenylthio)-2-chlorophenyl]-2-ethoxycarbonyl-2-methylpentanoic acid
    —— (3-cyano-6-methyl-4-methoxymethyl-2-pyridylthio)acetic acid 170885-42-4 C11H12N2O3S
    (3-cyano-6-methyl-4-methoxymethyl-2-pyridylthio)acetic acid
    —— Pyridine-3-carbonitrile, 2-(2-amino-2-oxoethylthio)-4-methoxymethyl-6-methyl- 185430-17-5 C11H13N3O2S
    Pyridine-3-carbonitrile, 2-(2-amino-2-oxoethylthio)-4-methoxymethyl-6-methyl-
    —— (rac)-6-bromo-2,3-dihydrobenzo[b]thiophen-3-ol 737802-11-8 C8H7BrOS
    (rac)-6-bromo-2,3-dihydrobenzo[b]thiophen-3-ol
    —— Bis<(methylthio)methylthio>-methan 35167-22-7 C5H12S4
    Bis<(methylthio)methylthio>-methan
    —— methyl 3-((2-amino-4-chlorophenyl)thio)benzoate 1451261-93-0 C14H12ClNO2S
    methyl 3-((2-amino-4-chlorophenyl)thio)benzoate
    —— 3-bromothioindoxyl 67866-90-4 C8H5BrOS
    3-bromothioindoxyl
    —— methyl 2-((2-amino-4-chlorophenyl)thio)benzoate hydrochloride salt 1071718-24-5 C14H12ClNO2S*ClH
    methyl 2-((2-amino-4-chlorophenyl)thio)benzoate hydrochloride salt
    —— N-(vinyloxyethyl)dithiocarbamic acid 103538-67-6 C5H9NOS2
    N-(vinyloxyethyl)dithiocarbamic acid
    —— 7-(o-hydroxyphenyl)-N-phenyl-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylic acid anhydride 98664-30-3 C14H9NO4S3
    7-(o-hydroxyphenyl)-N-phenyl-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylic acid anhydride
    —— (Z)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene 85914-69-8 C12H14Cl2S
    (Z)-1,1-dichloro-3-methyl-5-phenylthio-3-pentene
    —— (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl 4-(morpholin-4-yl)butanoate 1404474-05-0 C30H38BrN7O6S
    (2S)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-yl 4-(morpholin-4-yl)butanoate
    —— 5-S-benzylthio-2-N,N-dimethylaminopyridine 1083329-64-9 C14H16N2S
    5-S-benzylthio-2-N,N-dimethylaminopyridine
    —— 4-bromo-2,3-dihydro-benzo[b]thiophen-3-ol 737802-12-9 C8H7BrOS
    4-bromo-2,3-dihydro-benzo[b]thiophen-3-ol
    —— n-pentadecylmethyl sulphide 62155-10-6 C16H34S
    n-pentadecylmethyl sulphide
    —— 6-cyano-7-(o-hydroxyphenyl)-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione 98664-27-8 C13H10N2OS3
    6-cyano-7-(o-hydroxyphenyl)-5,6-dihydrothiopyrano<2,3-d>thiazolidine-2-thione
    —— (1R,5S)-1-hydroxymethyl-2-methylene-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene 925413-80-5 C15H16OS
    (1R,5S)-1-hydroxymethyl-2-methylene-7-phenylsulfanylbicyclo[3.2.0]hept-6-ene
    —— dimethyl 7-(o-hydroxyphenyl)thiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylate 98664-31-4 C16H13NO5S3
    dimethyl 7-(o-hydroxyphenyl)thiopyrano<2,3-d>thiazolidine-2-thione-5,6-dicarboxylate
    —— (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carbaldehyde 686737-96-2 C22H30O2SSi
    (1S,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxybicyclo[3.2.0]hept-6-ene-1-carbaldehyde
    —— 1-[(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]prop-2-en-1-ol 686737-80-4 C24H34O2SSi
    1-[(1R,2S,5R)-2-ethenyl-7-phenylsulfanyl-2-triethylsilyloxy-1-bicyclo[3.2.0]hept-6-enyl]prop-2-en-1-ol
    —— 1-Benzenesulfenylmethyl-1-(2-propyl)cyclopropane 148258-88-2 C13H18S
    1-Benzenesulfenylmethyl-1-(2-propyl)cyclopropane