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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Bromo-4-methoxy-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one 109880-29-7 C13H14BrN3O2S
    5-Bromo-4-methoxy-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one
    —— Pyrimidine, 2-chloro-4-(1,3,4-thiadiazol-2-ylthio)- 1250316-57-4 C6H3ClN4S2
    Pyrimidine, 2-chloro-4-(1,3,4-thiadiazol-2-ylthio)-
    —— 4-Fluoro-2-[(2-methylpropyl)thio]benzenamine 1249593-40-5 C10H14FNS
    4-Fluoro-2-[(2-methylpropyl)thio]benzenamine
    —— 4-(Ethoxymethylthio)phenylboronic acid 2096331-89-2 C9H13BO3S
    4-(Ethoxymethylthio)phenylboronic acid
    —— N-[(7S,8aS)-2-methyloctahydropyrrolo[1,2-a]pyrazin-7-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]propanamide 1331944-77-4 C14H23N5OS2
    N-[(7S,8aS)-2-methyloctahydropyrrolo[1,2-a]pyrazin-7-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]propanamide
    —— 2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]thio}acetohydrazide 1306738-34-0 C14H18N6OS
    2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]thio}acetohydrazide
    —— 2-[(5-{1-[(4-Bromophenyl)amino]ethyl}-4-methyl-4H-1,2,4-triazol-3-yl)thio]acetohydrazide 1306738-58-8 C13H17BrN6OS
    2-[(5-{1-[(4-Bromophenyl)amino]ethyl}-4-methyl-4H-1,2,4-triazol-3-yl)thio]acetohydrazide
    —— 5-Bromo-2-[(1,3-dimethyl-1H-pyrazol-5-yl)thio]-3-pyridinamine 1249028-11-2 C10H11BrN4S
    5-Bromo-2-[(1,3-dimethyl-1H-pyrazol-5-yl)thio]-3-pyridinamine
    —— 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4-((trifluoromethyl)thio)phenol 2096340-17-7 C13H16BF3O3S
    2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4-((trifluoromethyl)thio)phenol
    —— 2-Chlor-3-<(2-amino-phenyl)-thiomethyl>-pyridin 92696-10-1 C12H11ClN2S
    2-Chlor-3-<(2-amino-phenyl)-thiomethyl>-pyridin
    —— 5-Methyl-6-(2-pyrimidinylthio)-3-pyridinamine 1249465-17-5 C10H10N4S
    5-Methyl-6-(2-pyrimidinylthio)-3-pyridinamine
    —— 2-[3-[(2-Methylphenyl)thio]propyl]pyrrolidine 1250115-40-2 C14H21NS
    2-[3-[(2-Methylphenyl)thio]propyl]pyrrolidine
    —— 5-methyl-6-(methylthio)pyridin-3-amine 935252-77-0 C7H10N2S
    5-methyl-6-(methylthio)pyridin-3-amine
    —— 2-[(E)-7-[2-[(2S)-butan-2-yl]-1,3-dithian-2-yl]hept-2-enoxy]oxane 1354575-64-6 C20H36O2S2
    2-[(E)-7-[2-[(2S)-butan-2-yl]-1,3-dithian-2-yl]hept-2-enoxy]oxane
    —— 3-(cyclopentylthio)-6-(3,5-dimethylpyrazol-1-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine 1300041-13-7 C13H16N8S
    3-(cyclopentylthio)-6-(3,5-dimethylpyrazol-1-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine
    —— 3-(6-chloro-1-isothiazol-4-yl-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid 1359980-62-3 C19H13ClN2O2S2
    3-(6-chloro-1-isothiazol-4-yl-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid
    —— Methanesulfenyl chloride, dichloro 42172-24-7 C2H3Cl3S
    Methanesulfenyl chloride, dichloro
    —— Einecs 252-850-9 36058-55-6 C14H12Cl5N3SZn
    Einecs 252-850-9
    —— Thioimidodicarbonic diamide (((H2N)C(S))2NH), mixt. with sodium hydroxide (Na(OH)) 87558-76-7 C2H6N3NaOS2
    Thioimidodicarbonic diamide (((H2N)C(S))2NH), mixt. with sodium hydroxide (Na(OH))
    —— Thioimidodicarbonic acid ((HO)C(O)NHC(S)(OH)), O1,O3-dipropyl ester 39142-31-9 C8H15NO2S2
    Thioimidodicarbonic acid ((HO)C(O)NHC(S)(OH)), O1,O3-dipropyl ester
    —— 4-methylcarbamoyloxy-2,3-dihydro-benzo[<i>b</i>]thiophene 22069-03-0 C10H11NO2S
    4-methylcarbamoyloxy-2,3-dihydro-benzo[<i>b</i>]thiophene
    —— 4-(3-(4-Imidazolyl)thioacryloyl)morpholine 88167-13-9 C10H13N3O2S
    4-(3-(4-Imidazolyl)thioacryloyl)morpholine
    —— N,N'-Thioperoxydicarbamic acid 93892-75-2 C26H52N2S4
    N,N'-Thioperoxydicarbamic acid
    —— Pseudourea, 2,2'-(iminodiethylene)bis(2-thio-, dihydrobromide 90000-16-1 C6H17Br2N5S2
    Pseudourea, 2,2'-(iminodiethylene)bis(2-thio-, dihydrobromide
    —— N-[2-(2-Thienylthio)ethyl]-2-heptanamine 1247783-33-0 C13H23NS2
    N-[2-(2-Thienylthio)ethyl]-2-heptanamine
    —— 2-[(Difluoromethyl)thio]-N-(2-methoxy-1-methylethyl)benzenamine 1247342-24-0 C11H15F2NOS
    2-[(Difluoromethyl)thio]-N-(2-methoxy-1-methylethyl)benzenamine
    —— 5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-23-9 C21H26N4S2
    5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 1-Propanamine, N-(2-methoxyethyl)-2-(2-pyridinylthio)- 1251380-34-3 C11H18N2OS
    1-Propanamine, N-(2-methoxyethyl)-2-(2-pyridinylthio)-
    —— N-Methyl-4-[(2-methylphenyl)thio]-1-butanamine 1249382-73-7 C12H19NS
    N-Methyl-4-[(2-methylphenyl)thio]-1-butanamine
    —— 3-Fluoro-7-(methylthio)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4(8H)-one 1353761-16-6 C5H4FN5OS
    3-Fluoro-7-(methylthio)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4(8H)-one
    —— 5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine 1321891-13-7 C23H30N4OS2
    5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine
    —— N1,N1-Dimethyl-N3-[2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]ethyl]-1,3-propanediamine 1247632-04-7 C10H21N5S
    N1,N1-Dimethyl-N3-[2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]ethyl]-1,3-propanediamine
    —— 5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine 1321891-19-3 C22H28N4OS2
    5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine
    —— N-(2-Methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]-1-propanamine 1249836-01-8 C8H17N5OS
    N-(2-Methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]-1-propanamine
    —— 7-Methylsulfanyl-3-pyridin-1-ium-1-yl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-olate 1353761-18-8 C10H8N6OS
    7-Methylsulfanyl-3-pyridin-1-ium-1-yl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-olate
    —— 5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-12-6 C22H28N4S2
    5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 5,6-dimethyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-35-3 C20H24N4S2
    5,6-dimethyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 4-[(1,3-Dimethyl-1H-pyrazol-5-yl)thio]-N-methyl-1-butanamine 1247450-27-6 C10H19N3S
    4-[(1,3-Dimethyl-1H-pyrazol-5-yl)thio]-N-methyl-1-butanamine
    —— 3-butylsulfanyl-4-methyl-aniline 100056-24-4 C11H17NS
    3-butylsulfanyl-4-methyl-aniline
    —— 1-carbamoyl-2-methyl-3-phenylthio-1H-pyrrole 1353137-65-1 C12H12N2OS
    1-carbamoyl-2-methyl-3-phenylthio-1H-pyrrole
    —— 7-methyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-57-1 C18H18N2OS2
    7-methyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-55-9 C12H14N2OS
    7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 4-[di(ethoxycarbonyl)methyl]-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-48-0 C19H24N2O5S
    4-[di(ethoxycarbonyl)methyl]-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 4-cyano-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-46-8 C13H13N3OS
    4-cyano-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— Cycloheptanecarboxamide, N-[1-(aminothioxomethyl)propyl]- 1250406-45-1 C12H22N2OS
    Cycloheptanecarboxamide, N-[1-(aminothioxomethyl)propyl]-
    —— triethyl-[(1R,2S)-2-methyl-5-phenylsulfanylcyclohepta-3,5-dien-1-yl]oxysilane 1349053-88-8 C20H30OSSi
    triethyl-[(1R,2S)-2-methyl-5-phenylsulfanylcyclohepta-3,5-dien-1-yl]oxysilane
    —— Propanamide, N-(2-amino-1-methyl-2-thioxoethyl)-3-methoxy-N-methyl- 1250900-55-0 C8H16N2O2S
    Propanamide, N-(2-amino-1-methyl-2-thioxoethyl)-3-methoxy-N-methyl-
    —— 4-methyl-3-propylsulfanyl-aniline 104396-08-9 C10H15NS
    4-methyl-3-propylsulfanyl-aniline
    —— 4-methyl-3-phenylsulfanyl-aniline 105901-47-1 C13H13NS
    4-methyl-3-phenylsulfanyl-aniline
    —— 3-ethylsulfanyl-4-methyl-aniline 98960-72-6 C9H13NS
    3-ethylsulfanyl-4-methyl-aniline