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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <(ethoxythiocarbonyl)sulfanyl>(hept-4(Z)-enyloxy)acetic acid methyl ester 161254-26-8 C13H22O4S2
    <(ethoxythiocarbonyl)sulfanyl>(hept-4(Z)-enyloxy)acetic acid methyl ester
    —— {5-chloro-6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid ethyl ester 917761-22-9 C23H24ClFN2O5S2
    {5-chloro-6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid ethyl ester
    —— Di-cyclohex-2-enyl-disulfid 96080-58-9 C12H18S2
    Di-cyclohex-2-enyl-disulfid
    —— S-(2-cyclohexenyl) N-methylthiocarbamate 188400-12-6 C8H13NOS
    S-(2-cyclohexenyl) N-methylthiocarbamate
    —— 1-Methyl-3,3-bis(methylthio)-2-pyrrolidon 63017-89-0 C7H13NOS2
    1-Methyl-3,3-bis(methylthio)-2-pyrrolidon
    —— 4-cyclohexyl-2-(2,5-dimethyl-benzylsulfanyl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 301177-43-5 C20H23N3OS
    4-cyclohexyl-2-(2,5-dimethyl-benzylsulfanyl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 1,2,3,4-Tetrahydro-1-methyl-2,4-diphenyl-6-phenylthio-S-Tetrazin 51808-05-0 C21H20N4S
    1,2,3,4-Tetrahydro-1-methyl-2,4-diphenyl-6-phenylthio-S-Tetrazin
    —— 4-cyclopropyl-2-(2,5-dimethylbenzylsulfanyl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 1383539-72-7 C17H17N3OS
    4-cyclopropyl-2-(2,5-dimethylbenzylsulfanyl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 2-((tert-butyldimethylsilyloxy)(tetrahydrofuran-2-yl)methylthio)pyridine 1076691-81-0 C16H27NO2SSi
    2-((tert-butyldimethylsilyloxy)(tetrahydrofuran-2-yl)methylthio)pyridine
    —— 2-(2,5-dimethyl-benzylsulfanyl)-4-(1-methyl-piperidin-4-yl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 1383539-74-9 C20H24N4OS
    2-(2,5-dimethyl-benzylsulfanyl)-4-(1-methyl-piperidin-4-yl)-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 2-(1-hydroxy-1-methylethyl)-6-carboxydiphenyl sulfide 75893-91-3 C16H16O3S
    2-(1-hydroxy-1-methylethyl)-6-carboxydiphenyl sulfide
    —— 2-(2,5-dimethyl-benzylsulfanyl)-4-isopropyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 1383539-71-6 C17H19N3OS
    2-(2,5-dimethyl-benzylsulfanyl)-4-isopropyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 4-Methyl-2-(thiophenoxymethyl)anilin 53165-11-0 C14H15NS
    4-Methyl-2-(thiophenoxymethyl)anilin
    —— N,N-dimethyl-10H-pyridazino[4,3-b][1,4]benzothiazin-3-amine 10337-78-7 C12H12N4S
    N,N-dimethyl-10H-pyridazino[4,3-b][1,4]benzothiazin-3-amine
    —— 3-tert.Butylthiete-1,1-dioxid 25903-16-6 C7H12O2S
    3-tert.Butylthiete-1,1-dioxid
    —— 2,6-Bis(phenylthio)cyclohexanon 35874-90-9 C18H18OS2
    2,6-Bis(phenylthio)cyclohexanon
    —— 3-(phenylthio)thietane 1,1-dioxide 75299-22-8 C9H10O2S2
    3-(phenylthio)thietane 1,1-dioxide
    —— 2-(3,6-Dichloropyridazin-4-yl)sulfanylaniline 10344-41-9 C10H7Cl2N3S
    2-(3,6-Dichloropyridazin-4-yl)sulfanylaniline
    —— Methyl ((3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-YL)thio)acetate 75621-68-0 C6H7N3O4S
    Methyl ((3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-YL)thio)acetate
    —— Bis-(3-thietanyl-1.1-dioxid)-sulfid 89599-40-6 C6H10O4S3
    Bis-(3-thietanyl-1.1-dioxid)-sulfid
    —— 3-Methyl-sulfonylpropanolacetat 26981-50-0 C6H12O4S
    3-Methyl-sulfonylpropanolacetat
    —— 1,1-dioxo-1λ<sup>6</sup>-thionane-3,8-dione 71138-48-2 C8H12O4S
    1,1-dioxo-1λ<sup>6</sup>-thionane-3,8-dione
    —— [2-(4-chlorobenzylthio)phenyl]-acetic acid 120974-95-0 C15H13ClO2S
    [2-(4-chlorobenzylthio)phenyl]-acetic acid
    —— 3-Methoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile 65322-14-7 C9H11NO2S2
    3-Methoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile
    —— Didodecyldodecanbis(dithioat) 65222-84-6 C36H70S4
    Didodecyldodecanbis(dithioat)
    —— 4-Phenyl-but-1-ynylsulfanyl-benzene 125829-48-3 C16H14S
    4-Phenyl-but-1-ynylsulfanyl-benzene
    —— Didodecylhexanbis(dithioat) 65222-82-4 C30H58S4
    Didodecylhexanbis(dithioat)
    —— (3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-(4-chloro-phenylsulfanyl)-acetic acid methyl ester 54326-52-2 C19H16ClNO3S3
    (3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-(4-chloro-phenylsulfanyl)-acetic acid methyl ester
    —— 1,1-Bis-t-butylsulfonyl-ethan 19170-12-8 C10H22O4S2
    1,1-Bis-t-butylsulfonyl-ethan
    —— 3-Ethoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile 65322-15-8 C10H13NO2S2
    3-Ethoxy-1-methyl-5-methylsulfanyl-1-oxo-1λ<sup>6</sup>-thiopyran-4-carbonitrile
    —— tert-butyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate 909911-52-0 C24H32O4S
    tert-butyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylthio)cyclopent-3-ene-1-carboxylate
    —— (7-chloro-8-methyl-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-4-yl)acetic acid 958781-93-6 C11H10ClNO5S2
    (7-chloro-8-methyl-1,1,3-trioxo-3,4-dihydro-2H-1,5,2-benzo[f]dithiazepin-4-yl)acetic acid
    —— thiophenyl-β-D-ribo-hexopyranoside-3-ulose 1451062-71-7 C12H14O5S
    thiophenyl-β-D-ribo-hexopyranoside-3-ulose
    —— Phenyl 2,3:4,6-bis-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-1-thio-β-D-glucopyranoside 145259-84-3 C36H68O7SSi4
    Phenyl 2,3:4,6-bis-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-1-thio-β-D-glucopyranoside
    —— (2-amino-phenylsulfanyl)-(3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-acetic acid methyl ester 54255-29-7 C19H18N2O3S3
    (2-amino-phenylsulfanyl)-(3-benzyl-4-oxo-2-thioxo-thiazolidin-5-yl)-acetic acid methyl ester
    —— 1,2-Dichloro-3-(2-chloromethyl-phenylsulfanyl)-benzene 79962-31-5 C13H9Cl3S
    1,2-Dichloro-3-(2-chloromethyl-phenylsulfanyl)-benzene
    —— (3R,3aR,6aS)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one 909911-32-6 C14H14O3S
    (3R,3aR,6aS)-3-(hydroxymethyl)-6a-(phenylthio)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one
    —— ethyl 4-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]butanoate 84608-08-2 C9H13N3O4S
    ethyl 4-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]butanoate
    —— 2-(2,3-Dichlorophenylthio)benzoic Acid 79962-20-2 C13H8Cl2O2S
    2-(2,3-Dichlorophenylthio)benzoic Acid
    —— 2-(2,3-Dichlorophenylthio)benzyl Alcohol 79962-21-3 C13H10Cl2OS
    2-(2,3-Dichlorophenylthio)benzyl Alcohol
    —— 3,6-diethyl-2-cyanomethylthiopyrazine 116196-67-9 C10H13N3S
    3,6-diethyl-2-cyanomethylthiopyrazine
    —— 4,4',6,6'-tetra(pyridin-4-yl)-5H,5'H-2,2'-bi[1,3]dithiolo[4,5-c]pyrrolylidene 1389288-76-9 C30H18N6S4
    4,4',6,6'-tetra(pyridin-4-yl)-5H,5'H-2,2'-bi[1,3]dithiolo[4,5-c]pyrrolylidene
    —— 2-oxo-N-propan-2-yl-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide 1426959-62-7 C18H22N2O2S
    2-oxo-N-propan-2-yl-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide
    —— t-butyl S-3,6-diethylpyrazin-2-ylthiolcarbonate 104272-94-8 C13H20N2O2S
    t-butyl S-3,6-diethylpyrazin-2-ylthiolcarbonate
    —— ({[(3-Bromo-2-chloropropyl)sulfanyl](dichloro)methyl}sulfanyl)cyclohexane 19095-93-3 C10H16BrCl3S2
    ({[(3-Bromo-2-chloropropyl)sulfanyl](dichloro)methyl}sulfanyl)cyclohexane
    —— Bis[2-(methylsulfanyl)phenyl](phenyl)arsane 19980-62-2 C20H19AsS2
    Bis[2-(methylsulfanyl)phenyl](phenyl)arsane
    —— Disulfide, bis(2-chloro-1,1-dimethylethyl) 16621-42-4 C8H16Cl2S2
    Disulfide, bis(2-chloro-1,1-dimethylethyl)
    —— 2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-propionic acid ethyl ester 75621-69-1 C8H11N3O4S
    2-(3,5-Dioxo-2,3,4,5-tetrahydro-[1,2,4]triazin-6-ylsulfanyl)-propionic acid ethyl ester
    —— (Z)-2,2-dimethyl-4,7-dihydro-1λ4,3-dithiepine 1-oxide 1242163-10-5 C7H12OS2
    (Z)-2,2-dimethyl-4,7-dihydro-1λ4,3-dithiepine 1-oxide
    —— ethyl 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]octanoate 87733-47-9 C13H21N3O4S
    ethyl 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]octanoate