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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Aminomethyl-2-tert-butylthio-pyridine 864266-68-2 C10H16N2S
    5-Aminomethyl-2-tert-butylthio-pyridine
    —— Benzenemethanamine, 4-[(2,5-difluorophenyl)thio]-I+/--methyl- 1154894-64-0 C14H13F2NS
    Benzenemethanamine, 4-[(2,5-difluorophenyl)thio]-I+/--methyl-
    —— Benzo[b]thiophen-3-amine, 2,3-dihydro-5,6-dimethyl-N-propyl- 1154342-08-1 C13H19NS
    Benzo[b]thiophen-3-amine, 2,3-dihydro-5,6-dimethyl-N-propyl-
    —— Methyl 3-[(5-amino-2-pyridinyl)thio]propanoate 176658-53-0 C9H12N2O2S
    Methyl 3-[(5-amino-2-pyridinyl)thio]propanoate
    —— N-(4-fluorobenzyl)-2-((6-morpholinopyrimidin-4-yl)thio)acetamide 1171934-76-1 C17H19FN4O2S
    N-(4-fluorobenzyl)-2-((6-morpholinopyrimidin-4-yl)thio)acetamide
    —— (2S)-1-(4-methylphenyl)sulfanyldec-3-yn-2-ol 1160482-47-2 C17H24OS
    (2S)-1-(4-methylphenyl)sulfanyldec-3-yn-2-ol
    —— 3,4-dihydro-N-[(2S)-3-[(2-methylphenyl)thio]-2-methylpropyl]-2H-(3R)-1,5-benzoxathiepin-3-amine 1169759-74-3 C20H25NOS2
    3,4-dihydro-N-[(2S)-3-[(2-methylphenyl)thio]-2-methylpropyl]-2H-(3R)-1,5-benzoxathiepin-3-amine
    —— (5S,8aR)-6,6-dimethyl-5-(phenylsulfanylmethyl)-2,3,5,7,8,8a-hexahydro-1H-naphthalene 1187954-14-8 C19H26S
    (5S,8aR)-6,6-dimethyl-5-(phenylsulfanylmethyl)-2,3,5,7,8,8a-hexahydro-1H-naphthalene
    —— 2-[4-(4-tert-Butyl-phenylsulfanyl)-3-chloro-phenyl]-2H-[1,2,4]triazine-3,5-dione 78983-72-9 C19H18ClN3O2S
    2-[4-(4-tert-Butyl-phenylsulfanyl)-3-chloro-phenyl]-2H-[1,2,4]triazine-3,5-dione
    —— 3-Chloro-6-(4-chloro-phenyl)-4-methylsulfanyl-pyran-2-one 203171-89-5 C12H8Cl2O2S
    3-Chloro-6-(4-chloro-phenyl)-4-methylsulfanyl-pyran-2-one
    —— N-[5-(methylthio)-1,3,4-thiadiazol-2-yl]sulfamide 1098266-13-7 C3H6N4O2S3
    N-[5-(methylthio)-1,3,4-thiadiazol-2-yl]sulfamide
    —— 2-(4,6-bis((E)-2-(4-octylthiophen-2-yl)vinyl)thieno[3,4-d]-1,3-dithiol-2-ylidene)-4,6-bis((E)-2-(4-octylthiophen-2-yl)vinyl)thieno[3,4-d]-1,3-dithiole 1196715-07-7 C66H84S10
    2-(4,6-bis((E)-2-(4-octylthiophen-2-yl)vinyl)thieno[3,4-d]-1,3-dithiol-2-ylidene)-4,6-bis((E)-2-(4-octylthiophen-2-yl)vinyl)thieno[3,4-d]-1,3-dithiole
    —— 2-amino-N-(4-methylthiazol-2-yl)-5-(phenylthio)benzamide 1146340-39-7 C17H15N3OS2
    2-amino-N-(4-methylthiazol-2-yl)-5-(phenylthio)benzamide
    —— 2-[(3,4-Dichlorophenyl)thio]-5-(trifluoromethyl)benzenamine 195045-27-3 C13H8Cl2F3NS
    2-[(3,4-Dichlorophenyl)thio]-5-(trifluoromethyl)benzenamine
    —— 6-nitro-2-(phenylthiomethyl)thiazolo[5,4-b]pyridine 1206549-66-7 C13H9N3O2S2
    6-nitro-2-(phenylthiomethyl)thiazolo[5,4-b]pyridine
    —— Tert-butyl-[[4-[tert-butyl(diphenyl)silyl]oxy-2-(5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-1,3-benzodithiol-7-yl]oxy]-diphenylsilane 1206719-64-3 C44H44O2S6Si2
    Tert-butyl-[[4-[tert-butyl(diphenyl)silyl]oxy-2-(5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-1,3-benzodithiol-7-yl]oxy]-diphenylsilane
    —— 1-methyl-2-(4-phenylsulfanylphenyl)ethylamine 1204749-21-2 C15H17NS
    1-methyl-2-(4-phenylsulfanylphenyl)ethylamine
    —— (2R,4aS,6S,6aS,9aR)-7-Benzyl-2-phenyl-6-(phenylsulfanyl)hexahydro-2H-[1,3]dioxino[4',5':5,6]pyrano[3,4-d][1,3]oxazol-8(6H)-one 910805-49-1 C27H25NO5S
    (2R,4aS,6S,6aS,9aR)-7-Benzyl-2-phenyl-6-(phenylsulfanyl)hexahydro-2H-[1,3]dioxino[4',5':5,6]pyrano[3,4-d][1,3]oxazol-8(6H)-one
    —— [5-(4-Fluorophenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium;chloride 1050502-70-9 C15H17ClFN5OS
    [5-(4-Fluorophenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium;chloride
    —— 3-methyl-1,1-bis-methylsulfanyl-buta-1,2-diene 67945-61-3 C7H12S2
    3-methyl-1,1-bis-methylsulfanyl-buta-1,2-diene
    —— [2-Bromo-4-(2-chlorophenyl)sulfanylphenyl]methanol 1226773-50-7 C13H10BrClOS
    [2-Bromo-4-(2-chlorophenyl)sulfanylphenyl]methanol
    —— 2-[(4-Bromophenyl)thio]-4-methylcyclohexanecarbonitrile 1218288-33-5 C14H16BrNS
    2-[(4-Bromophenyl)thio]-4-methylcyclohexanecarbonitrile
    —— 4-[1-[[4-(Methylthio)phenyl]amino]ethyl]phenol 1019586-14-1 C15H17NOS
    4-[1-[[4-(Methylthio)phenyl]amino]ethyl]phenol
    —— 4-(p-tert-Butylphenylmercapto)-phenylisonitril 83270-45-5 C17H17NS
    4-(p-tert-Butylphenylmercapto)-phenylisonitril
    —— 2-[(3,4-Difluorophenyl)thio]-3-methylbutanoic acid 1098352-15-8 C11H12F2O2S
    2-[(3,4-Difluorophenyl)thio]-3-methylbutanoic acid
    —— 2-[(3,4-Difluorophenyl)thio]-N-hydroxyethanimidamide 1097125-24-0 C8H8F2N2OS
    2-[(3,4-Difluorophenyl)thio]-N-hydroxyethanimidamide
    —— S-[2-(methylamino)ethyl] 2-methylsulfonylethanethioate;hydrochloride 1190228-02-4 C6H13NO3S2*ClH
    S-[2-(methylamino)ethyl] 2-methylsulfonylethanethioate;hydrochloride
    —— 2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)-N-(thiophen-2-ylsulfonyl)acetamide 1057256-33-3 C24H18N2O4S3
    2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)-N-(thiophen-2-ylsulfonyl)acetamide
    —— 2-benzyl-N-phenethyl-3-(phenylthio)propanamide 1146929-35-2 C24H25NOS
    2-benzyl-N-phenethyl-3-(phenylthio)propanamide
    —— 4-(2-Pyrimidinylthio)-3-quinolinecarboximidamide 1153327-13-9 C14H11N5S
    4-(2-Pyrimidinylthio)-3-quinolinecarboximidamide
    —— 2-amino-4,6-bis{[2-(diisopropoxyphosphorylmethoxy)-ethyl]sulfanyl}pyrimidine 1160513-42-7 C22H43N3O8P2S2
    2-amino-4,6-bis{[2-(diisopropoxyphosphorylmethoxy)-ethyl]sulfanyl}pyrimidine
    —— Benzenamine, 2-methyl-4-(propylthio)- 1155084-81-3 C10H15NS
    Benzenamine, 2-methyl-4-(propylthio)-
    —— 1-[(2-Fluorophenyl)thio]-3-(propylamino)-2-propanol 1152878-97-1 C12H18FNOS
    1-[(2-Fluorophenyl)thio]-3-(propylamino)-2-propanol
    —— 1,4-bis(6-methoxy-s-tetrazin-3-ylthio)butane 1206227-56-6 C10H14N8O2S2
    1,4-bis(6-methoxy-s-tetrazin-3-ylthio)butane
    —— 4-[4-(methylsulfanyl)phenyl]-4,7-dihydrofuro[3,4-d]pyrimidine-2,5(1H,3H)-dione 1223888-73-0 C13H12N2O3S
    4-[4-(methylsulfanyl)phenyl]-4,7-dihydrofuro[3,4-d]pyrimidine-2,5(1H,3H)-dione
    —— 4-Chloro-2-(4-methylpyrimidin-2-ylthio)thiazole-5-carbaldehyde 914348-70-2 C9H6ClN3OS2
    4-Chloro-2-(4-methylpyrimidin-2-ylthio)thiazole-5-carbaldehyde
    —— 4-chloro-2-(1-methyl-1H-imidazol-2-ylthio)thiazole-5-carbaldehyde 914348-72-4 C8H6ClN3OS2
    4-chloro-2-(1-methyl-1H-imidazol-2-ylthio)thiazole-5-carbaldehyde
    —— 4-Fluorothioanisole-d4 1189510-57-3 C7H7FS
    4-Fluorothioanisole-d4
    —— [(4-Methyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]acetonitrile 834899-99-9 C5H5N3S3
    [(4-Methyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]acetonitrile
    —— 5-(4-(Methylthio)phenyl)isoxazole-3-carboxylic acid 763109-74-6 C11H9NO3S
    5-(4-(Methylthio)phenyl)isoxazole-3-carboxylic acid
    —— 4-(Methylthio)-3-pyridinecarbonitrile 435271-25-3 C7H6N2S
    4-(Methylthio)-3-pyridinecarbonitrile
    —— 1-Methyl-4-(methylthio)-1h-pyrrole-2-carbaldehyde 482585-33-1 C7H9NOS
    1-Methyl-4-(methylthio)-1h-pyrrole-2-carbaldehyde
    —— 3-(Methylsulfinyl)-1-propen-2-ol 191920-24-8 C4H8O2S
    3-(Methylsulfinyl)-1-propen-2-ol
    —— N-(Aminothioxomethyl)cyclobutanecarboxamide 161063-31-6 C6H10N2OS
    N-(Aminothioxomethyl)cyclobutanecarboxamide
    —— N-Methyl-N-(N'-methylcarbamimidoyl)thiourea 535975-83-8 C4H10N4S
    N-Methyl-N-(N'-methylcarbamimidoyl)thiourea
    —— 1-Methyl-1H-imidazol-2-yl carbamimidothioate 739320-81-1 C5H8N4S
    1-Methyl-1H-imidazol-2-yl carbamimidothioate
    —— N-[2-(Aziridin-1-yl)ethyl]-N-methylthiourea 502485-49-6 C6H13N3S
    N-[2-(Aziridin-1-yl)ethyl]-N-methylthiourea
    —— [1,2,4]Triazolo[3,4-b][1,3]thiazepine 585528-62-7 C6H5N3S
    [1,2,4]Triazolo[3,4-b][1,3]thiazepine
    —— 5,6-dihydro-1-methyl-3-methylthiopyrazin-2(1H)-one 562814-54-4 C6H10N2OS
    5,6-dihydro-1-methyl-3-methylthiopyrazin-2(1H)-one
    —— N-methyl-N-(2-methylsulfanylethyl)-thioacetamide 786686-41-7 C6H13NS2
    N-methyl-N-(2-methylsulfanylethyl)-thioacetamide