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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-acetyl-2-phenylthiobut-3-enoate 99683-08-6 C14H16O3S
    ethyl 2-acetyl-2-phenylthiobut-3-enoate
    —— (4-bromo-2-methylphenyl)(cyclopropyl)sulfane 1310947-48-8 C10H11BrS
    (4-bromo-2-methylphenyl)(cyclopropyl)sulfane
    —— 1-(2-Phenylsulfanyl-ethyl)-cyclopentanol 114694-23-4 C13H18OS
    1-(2-Phenylsulfanyl-ethyl)-cyclopentanol
    —— 2,6-Dimethyl-3,3-bis-(phenylthio)-heptan-2-ol 69221-15-4 C21H28OS2
    2,6-Dimethyl-3,3-bis-(phenylthio)-heptan-2-ol
    —— 3-(methylthio)pyrazine-2-carbonitrile 128142-12-1 C6H5N3S
    3-(methylthio)pyrazine-2-carbonitrile
    —— methyl 3-(3-cyanopyrazin-2-ylthio)propanoate 907597-25-5 C9H9N3O2S
    methyl 3-(3-cyanopyrazin-2-ylthio)propanoate
    —— 1,2-Dimethyldithiocarbazat 53326-78-6 C3H8N2S2
    1,2-Dimethyldithiocarbazat
    —— 3-((5-(benzylthio)-1,3,4-thiadiazol-2-yl)thio)pyrazine-2-carbonitrile 1000269-38-4 C14H9N5S3
    3-((5-(benzylthio)-1,3,4-thiadiazol-2-yl)thio)pyrazine-2-carbonitrile
    —— methyl<3-methyl-5-(2-methylpropyl)-4-phenylthiocyclohex-3-ene>-1-carboxylate 69063-48-5 C19H26O2S
    methyl<3-methyl-5-(2-methylpropyl)-4-phenylthiocyclohex-3-ene>-1-carboxylate
    —— N,N'-ethylene-2,2'-thiodibenzamide 1393085-56-7 C16H14N2O2S
    N,N'-ethylene-2,2'-thiodibenzamide
    —— 2-methyl-2-(4-methyl-3-phenylthiopenten-3-yl)-1,3-dioxolane 163068-80-2 C16H22O2S
    2-methyl-2-(4-methyl-3-phenylthiopenten-3-yl)-1,3-dioxolane
    —— 2,6-dimethyl-2,3-bisphenylthiohept-3-ene 98837-91-3 C21H26S2
    2,6-dimethyl-2,3-bisphenylthiohept-3-ene
    —— 2,2,3,3-Tetramethyl-cyclobutanethione 67079-66-7 C8H14S
    2,2,3,3-Tetramethyl-cyclobutanethione
    —— 2-chloro-β-phenethylsulfonyl azide 96129-63-4 C8H8ClN3O2S
    2-chloro-β-phenethylsulfonyl azide
    —— 7-methyl-4,4-bisphenylthio-octan-3-ol 88065-32-1 C21H28OS2
    7-methyl-4,4-bisphenylthio-octan-3-ol
    —— 2,6-dimethyl-2,3-bisphenylthiohept-3-ene 69063-44-1 C21H26S2
    2,6-dimethyl-2,3-bisphenylthiohept-3-ene
    —— 7-methyl-2-phenylthio-octan-4-one 98711-71-8 C15H22OS
    7-methyl-2-phenylthio-octan-4-one
    —— 1,1-Bis(phenylthio)-2-methyl-1-octen-4-yl acetate 157955-31-2 C23H28O2S2
    1,1-Bis(phenylthio)-2-methyl-1-octen-4-yl acetate
    —— <cyclohexylidene(phenylthio)methyl>trimethylsilane 71342-13-7 C16H24SSi
    <cyclohexylidene(phenylthio)methyl>trimethylsilane
    —— α-Phenylthio-cyclohexylidenacetaldehyd 37605-80-4 C14H16OS
    α-Phenylthio-cyclohexylidenacetaldehyd
    —— tert.-Butyl-2,6-dibrom-4-tolylsulfid 62261-16-9 C11H14Br2S
    tert.-Butyl-2,6-dibrom-4-tolylsulfid
    —— (decane-1-sulfinyl)-acetic acid 13887-90-6 C12H24O3S
    (decane-1-sulfinyl)-acetic acid
    —— 3-Amino-1,2-propandithiol 15049-98-6 C3H9NS2
    3-Amino-1,2-propandithiol
    —— 2,2-dimethyl-4<i>H</i>-benzo[1,3]dithiine 6247-53-6 C10H12S2
    2,2-dimethyl-4<i>H</i>-benzo[1,3]dithiine
    —— 4-isopropyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one 96540-47-5 C13H16O2S
    4-isopropyl-3-phenylthio-4,5-dihydrofuran-2(3H)-one
    —— 2-Methoxy-7-(1-methyl-3-phenylsulfanyl-but-3-enyl)-oxepane 424835-15-4 C18H26O2S
    2-Methoxy-7-(1-methyl-3-phenylsulfanyl-but-3-enyl)-oxepane
    —— 2-Methoxy-7-(3-phenylsulfanyl-but-3-enyl)-oxepane 424835-14-3 C17H24O2S
    2-Methoxy-7-(3-phenylsulfanyl-but-3-enyl)-oxepane
    —— 2-(N'-Methoxycarbonylguanidino)-5-phenylthio-methoxyacetanilid 92088-58-9 C18H20N4O4S
    2-(N'-Methoxycarbonylguanidino)-5-phenylthio-methoxyacetanilid
    —— 2,2,3,3-tetrafluoropropylisothiocyanate 79668-14-7 C4H3F4NS
    2,2,3,3-tetrafluoropropylisothiocyanate
    —— Trimethylsiloxy-tert-butyldimethylsilylmethyl-phenylsulphide 129584-68-5 C16H30OSSi2
    Trimethylsiloxy-tert-butyldimethylsilylmethyl-phenylsulphide
    —— 1-(dimethylsulfamoyl)-5-(2-methyl-6-ethylphenylthio)-4-hydroxypyrazole 143535-43-7 C14H19N3O3S2
    1-(dimethylsulfamoyl)-5-(2-methyl-6-ethylphenylthio)-4-hydroxypyrazole
    —— 1-isocyanato-4-isothiocyanato-cyclohexane 108748-91-0 C8H10N2OS
    1-isocyanato-4-isothiocyanato-cyclohexane
    —— 5-methyl-4-(4-(methylthio)phenyl)-3-phenylisoxazole 181696-81-1 C17H15NOS
    5-methyl-4-(4-(methylthio)phenyl)-3-phenylisoxazole
    —— [4-[4-(methylthio)phenyl]-3-phenylisoxazol-5-yl]acetic acid 181696-89-9 C18H15NO3S
    [4-[4-(methylthio)phenyl]-3-phenylisoxazol-5-yl]acetic acid
    —— (5Z)-1-(4-methoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-1,3-diazinane-2,4,6-trione 5963-67-7 C23H18N2O5S
    (5Z)-1-(4-methoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-1,3-diazinane-2,4,6-trione
    —— thioacetimidic acid butyl ester; hydrochloride 115809-46-6 C6H13NS*ClH
    thioacetimidic acid butyl ester; hydrochloride
    —— 4-(4-(3-(4-fluorophenyl)thioureido)phenylthio)-N-methylpicolinamide 1417344-62-7 C20H17FN4OS2
    4-(4-(3-(4-fluorophenyl)thioureido)phenylthio)-N-methylpicolinamide
    —— 2-acetyl-6,7-dihydro-5-methylthiothieno<2,3-b><1,4>thiazepine 161939-40-8 C10H11NOS3
    2-acetyl-6,7-dihydro-5-methylthiothieno<2,3-b><1,4>thiazepine
    —— (2-methoxyethyl)-(2-phenylthiocyclopentyl)amine 648419-44-7 C14H21NOS
    (2-methoxyethyl)-(2-phenylthiocyclopentyl)amine
    —— N'-Methyl-N'-(2-chlor-propyl)-N-sulfinyl-hydrazin 20570-04-1 C4H9ClN2OS
    N'-Methyl-N'-(2-chlor-propyl)-N-sulfinyl-hydrazin
    —— Tert-butyl-imino-methyl-oxo-lambda6-sulfane 1356395-48-6 C5H13NOS
    Tert-butyl-imino-methyl-oxo-lambda6-sulfane
    —— 2-bromo-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]iminomethyl]phenol 5489-94-1 C18H15BrClN3OS
    2-bromo-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]iminomethyl]phenol
    —— Tetrathiodiglykol 15576-64-4 C4H10O2S4
    Tetrathiodiglykol
    —— N'-Methyl-N'-(2-chloraethyl)-N-sulfinyl-hydrazin 20570-03-0 C3H7ClN2OS
    N'-Methyl-N'-(2-chloraethyl)-N-sulfinyl-hydrazin
    —— 2-(2-bromoallyl)-3-(phenylsulfanyl)-1-tosyl-1H-pyrrole 1447766-51-9 C20H18BrNO2S2
    2-(2-bromoallyl)-3-(phenylsulfanyl)-1-tosyl-1H-pyrrole
    —— N-methyl-4,5-ethylenedithio-1,3-thiazol-2-thione 917078-03-6 C6H7NS4
    N-methyl-4,5-ethylenedithio-1,3-thiazol-2-thione
    —— 2,4-dimethoxy-5-chlorodiphenyl sulfide 75787-00-7 C14H13ClO2S
    2,4-dimethoxy-5-chlorodiphenyl sulfide
    —— Bis-(2-methyl-<1,3>dithian-2-yl)-phenyl-methanol 4883-00-5 C17H24OS4
    Bis-(2-methyl-<1,3>dithian-2-yl)-phenyl-methanol
    —— 2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde 1134633-64-9 C18H12N4OS
    2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde
    —— Benzothiazole, 2-[[4-nitro-2-(trifluoromethyl)phenyl]thio]- 91512-40-2 C14H7F3N2O2S2
    Benzothiazole, 2-[[4-nitro-2-(trifluoromethyl)phenyl]thio]-