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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(para-tolyl)urea 417715-69-6 C25H22N4O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(para-tolyl)urea
    —— Benzenemethanamine, I+/--[[(3-chlorophenyl)thio]methyl]-N-ethyl-2-methyl- 1462237-18-8 C17H20ClNS
    Benzenemethanamine, I+/--[[(3-chlorophenyl)thio]methyl]-N-ethyl-2-methyl-
    —— 2-Butanamine, N-propyl-4-(2-pyrazinylthio)- 1343824-89-4 C11H19N3S
    2-Butanamine, N-propyl-4-(2-pyrazinylthio)-
    —— 1,2-Butanediamine, N1,N1,3-trimethyl-N2-[1-methyl-2-(methylsulfonyl)ethyl]- 1341367-70-1 C11H26N2O2S
    1,2-Butanediamine, N1,N1,3-trimethyl-N2-[1-methyl-2-(methylsulfonyl)ethyl]-
    —— 2-Propanamine, N-ethyl-1-[(1-methyl-1H-pyrazol-4-yl)thio]- 1339660-97-7 C9H17N3S
    2-Propanamine, N-ethyl-1-[(1-methyl-1H-pyrazol-4-yl)thio]-
    —— Ethyl 2-(4-propylsulfanylphenyl)acetate 15560-16-4 C13H18O2S
    Ethyl 2-(4-propylsulfanylphenyl)acetate
    —— Cyclopropanemethanamine, I+/--[[(3,4-dimethylphenyl)thio]methyl]-N-methyl- 1342385-24-3 C14H21NS
    Cyclopropanemethanamine, I+/--[[(3,4-dimethylphenyl)thio]methyl]-N-methyl-
    —— 2-Butanamine, 3,3-dimethyl-1-[(1-methylpropyl)sulfonyl]- 1342150-57-5 C10H23NO2S
    2-Butanamine, 3,3-dimethyl-1-[(1-methylpropyl)sulfonyl]-
    —— 1-Propanamine, N-(1,1-dimethylethyl)-3-(methylsulfinyl)- 1344275-69-9 C8H19NOS
    1-Propanamine, N-(1,1-dimethylethyl)-3-(methylsulfinyl)-
    —— 2-Butanamine, 1-[(1,1-dimethylethyl)sulfonyl]-N-ethyl- 1339479-28-5 C10H23NO2S
    2-Butanamine, 1-[(1,1-dimethylethyl)sulfonyl]-N-ethyl-
    —— 2-Butanamine, 3,3-dimethyl-1-(propylsulfinyl)- 1340346-17-9 C9H21NOS
    2-Butanamine, 3,3-dimethyl-1-(propylsulfinyl)-
    —— 3-Pentanamine, N-propyl-2-(2-pyrimidinylthio)- 1344015-80-0 C12H21N3S
    3-Pentanamine, N-propyl-2-(2-pyrimidinylthio)-
    —— N-t-butoxycarbonyl-(4-fluoro-2-(methylthio)phenyl)methanamine 869591-73-1 C13H18FNO2S
    N-t-butoxycarbonyl-(4-fluoro-2-(methylthio)phenyl)methanamine
    —— 1-[3-(n-Pentylthio)phenyl]ethanol 1443304-46-8 C13H20OS
    1-[3-(n-Pentylthio)phenyl]ethanol
    —— Acetamide, 2-[[3-(1-hydroxyethyl)phenyl]thio]-N-(1-methylbutyl)- 1378381-42-0 C15H23NO2S
    Acetamide, 2-[[3-(1-hydroxyethyl)phenyl]thio]-N-(1-methylbutyl)-
    —— 1-Propanamine, 3-(cyclohexylsulfonyl)-N-propyl- 1342742-35-1 C12H25NO2S
    1-Propanamine, 3-(cyclohexylsulfonyl)-N-propyl-
    —— 2-methyl-6-(4-methylphenyl)-sulfanylnicotinic acid 888022-55-7 C14H13NO2S
    2-methyl-6-(4-methylphenyl)-sulfanylnicotinic acid
    —— 2-(3-chloro-4-methylsulfanylphenyl)-3-[(3R)-8,8-dimethyl-6,10-dioxaspiro[4.5]decan-3-yl]propanoic acid 952517-41-8 C20H27ClO4S
    2-(3-chloro-4-methylsulfanylphenyl)-3-[(3R)-8,8-dimethyl-6,10-dioxaspiro[4.5]decan-3-yl]propanoic acid
    —— Methyl 4-(n-pentylthio)phenyl sulfide 1443345-26-3 C12H18S2
    Methyl 4-(n-pentylthio)phenyl sulfide
    —— Cyclohexanamine, 3-[(3-chloro-2-pyridinyl)thio]-N-methyl- 1340283-23-9 C12H17ClN2S
    Cyclohexanamine, 3-[(3-chloro-2-pyridinyl)thio]-N-methyl-
    —— Cyclopentanamine, N-methyl-3-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]- 1339208-95-5 C9H16N4S
    Cyclopentanamine, N-methyl-3-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]-
    —— (2R)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-2,3-dihydropyran-4-one 1373398-06-1 C15H18O2S
    (2R)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-2,3-dihydropyran-4-one
    —— 4-benzylsulfanyl-2-methyl-1,3-thiazole 1382676-17-6 C11H11NS2
    4-benzylsulfanyl-2-methyl-1,3-thiazole
    —— Cyclopentanamine, 3-[(3-bromo-2-pyridinyl)thio]- 1343158-96-2 C10H13BrN2S
    Cyclopentanamine, 3-[(3-bromo-2-pyridinyl)thio]-
    —— (2R,4S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,4-dihydro-2H-pyran-4-ol 1373398-07-2 C15H20O2S
    (2R,4S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,4-dihydro-2H-pyran-4-ol
    —— (3R)-3-methyl-4-phenylsulfanylbutanal 1373398-04-9 C11H14OS
    (3R)-3-methyl-4-phenylsulfanylbutanal
    —— N-[[2-[(2,6-Dichlorophenyl)thio]phenyl]methyl]-1-pyrrolidineethanamine 415718-61-5 C19H22Cl2N2S
    N-[[2-[(2,6-Dichlorophenyl)thio]phenyl]methyl]-1-pyrrolidineethanamine
    —— ethoxycarbonyl-thiocarbonimidic acid dimethyl ester 51291-78-2 C6H11NO3S
    ethoxycarbonyl-thiocarbonimidic acid dimethyl ester
    —— 3-(2-Iodoethanesulfonyl)propanamide 185564-46-9 C5H10INO3S
    3-(2-Iodoethanesulfonyl)propanamide
    —— 4-(methylthio)trifluoroacetophenone oxime 253585-96-5 C9H8F3NOS
    4-(methylthio)trifluoroacetophenone oxime
    —— 1-Propanol, 3-[(4-methyl-2-pyrimidinyl)thio]-2-(propylamino)- 1339928-26-5 C11H19N3OS
    1-Propanol, 3-[(4-methyl-2-pyrimidinyl)thio]-2-(propylamino)-
    —— tert-butyl N-[(2S)-1-(4-fluorophenyl)sulfanylpentan-2-yl]carbamate 377083-59-5 C16H24FNO2S
    tert-butyl N-[(2S)-1-(4-fluorophenyl)sulfanylpentan-2-yl]carbamate
    —— 1-Amino-2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pentan-2-ol 1343209-78-8 C9H17N3OS2
    1-Amino-2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pentan-2-ol
    —— 2-Phenylmercapto-2-amino-2-methyl-propanol, 2-Phenylmercaptomethyl-2-amino-propanol 2015-12-5 C10H15NOS
    2-Phenylmercapto-2-amino-2-methyl-propanol, 2-Phenylmercaptomethyl-2-amino-propanol
    —— 1-Benzenesulfonyl-5-phenylsulfanyl-3-(1H-pyrazol-4-yl)-1H-pyrrolo[2,3-b]pyridine 923583-59-9 C22H16N4O2S2
    1-Benzenesulfonyl-5-phenylsulfanyl-3-(1H-pyrazol-4-yl)-1H-pyrrolo[2,3-b]pyridine
    —— [6-fluoro-3-(2-fluoro-4-methanesulfonyl-phenylsulfanyl)-2-methyl-indolizin-1-yl]acetic acid 1034653-59-2 C18H15F2NO4S2
    [6-fluoro-3-(2-fluoro-4-methanesulfonyl-phenylsulfanyl)-2-methyl-indolizin-1-yl]acetic acid
    —— N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1S,2S)-2,3-dihydroxy-1-methylpropyl]amino}pyrimidin-4-yl)azetidine-1-sulfonamide 1204707-74-3 C18H23F2N5O4S2
    N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1S,2S)-2,3-dihydroxy-1-methylpropyl]amino}pyrimidin-4-yl)azetidine-1-sulfonamide
    —— N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1R,2S)-2,3-dihydroxy-1-methylpropyl]amino}pyrimidin-4-yl)azetidine-1-sulfonamide 1204707-72-1 C18H23F2N5O4S2
    N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1R,2S)-2,3-dihydroxy-1-methylpropyl]amino}pyrimidin-4-yl)azetidine-1-sulfonamide
    —— 6-(methylsulfonyl)-hex-1-yne 79797-12-9 C7H12O2S
    6-(methylsulfonyl)-hex-1-yne
    —— 3-fluoro-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinic acid 1034922-57-0 C16H9FN4O2S3
    3-fluoro-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinic acid
    —— tert-butyl (6-(5-(3-fluoro-2-(2-hydroxy-2-phenylpentylcarbamoyl)pyridin-4-ylthio)thiazol-2-ylamino)pyridin-3-yl)methyl(methyl)carbamate 1034922-54-7 C32H37FN6O4S2
    tert-butyl (6-(5-(3-fluoro-2-(2-hydroxy-2-phenylpentylcarbamoyl)pyridin-4-ylthio)thiazol-2-ylamino)pyridin-3-yl)methyl(methyl)carbamate
    —— 4-(2-(5-((tert-butoxycarbonylamino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinic acid 1034922-20-7 C20H20FN5O4S2
    4-(2-(5-((tert-butoxycarbonylamino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinic acid
    —— (S)-3-fluoro-N-(2-hydroxy-2-phenylpentyl)-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinamide 1034922-55-8 C27H24FN5O2S3
    (S)-3-fluoro-N-(2-hydroxy-2-phenylpentyl)-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinamide
    —— 4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinic acid 1034922-48-9 C24H27FN6O4S2
    4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinic acid
    —— methyl 4-(2-(5-aminopyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate 1034922-46-7 C15H12FN5O2S2
    methyl 4-(2-(5-aminopyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate
    —— methyl 4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate 1034922-47-8 C25H29FN6O4S2
    methyl 4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate
    —— 3-fluoro-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid 1034922-30-9 C16H13FN4O3S2
    3-fluoro-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid
    —— 4-(2-(4-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)-N-(2-phenylcyclopropyl)picolinamide 1034922-04-7 C24H21N5O2S2
    4-(2-(4-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)-N-(2-phenylcyclopropyl)picolinamide
    —— 4-(2-(4-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid 1034922-06-9 C15H12N4O3S2
    4-(2-(4-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid
    —— 4-[(2,3-Dicyanophenyl)sulfanyl]-N,N-bis(2-ethoxyethyl)benzamide 879098-02-9 C23H25N3O3S
    4-[(2,3-Dicyanophenyl)sulfanyl]-N,N-bis(2-ethoxyethyl)benzamide