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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Z-5-t-Butylthiocycloocten 64818-52-6 C12H22S
    Z-5-t-Butylthiocycloocten
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dimethoxy-[1,3]dithiolo[4,5-d]pyridazine 1359021-10-5 C18H24N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-4,7-dimethoxy-[1,3]dithiolo[4,5-d]pyridazine
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-d]pyridazine-4,7-dione 1359021-05-8 C16H20N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-5,6-dihydro-[1,3]dithiolo[4,5-d]pyridazine-4,7-dione
    —— (3-fluorobenzyl)(p-tolyl)sulfane 712296-58-7 C14H13FS
    (3-fluorobenzyl)(p-tolyl)sulfane
    —— octanethiolate 134257-67-3 C8H17S
    octanethiolate
    —— 4-((4,4,5,5,5-pentafluoropentyl)sulfinyl)butan-1-ol 1332392-75-2 C9H15F5O2S
    4-((4,4,5,5,5-pentafluoropentyl)sulfinyl)butan-1-ol
    —— 2-[3-cyano-4-(3-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine 918880-54-3 C18H9FN4S2
    2-[3-cyano-4-(3-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine
    —— 2-[3-cyano-4-(2-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine 918880-45-2 C18H9FN4S2
    2-[3-cyano-4-(2-fluorophenylthio)phenyl]thiazolo[5,4-d]pyrimidine
    —— 2-(3-cyano-4-phenylthiophenyl)thiazolo[5,4-d]pyrimidine 918880-46-3 C18H10N4S2
    2-(3-cyano-4-phenylthiophenyl)thiazolo[5,4-d]pyrimidine
    —— 2-amino-5-[(m-fluorobenzyl)thio]-1,3,4-thiadiazole 685108-09-2 C9H8FN3S2
    2-amino-5-[(m-fluorobenzyl)thio]-1,3,4-thiadiazole
    —— 6-(4-chlorophenylthio)-2,4(1H,3H)-quinazolinedione 1354385-99-1 C14H9ClN2O2S
    6-(4-chlorophenylthio)-2,4(1H,3H)-quinazolinedione
    —— N-tert-butyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-20-7 C12H22F5NO2S
    N-tert-butyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 4-((4,4,5,5,5-pentafluoropentyl)thio)butan-1-ol 1332392-74-1 C9H15F5OS
    4-((4,4,5,5,5-pentafluoropentyl)thio)butan-1-ol
    —— methyl 3-{[5,6-bis(methoxymethoxy)pyridin-3-yl]sulfanyl} propanoate 1417710-69-0 C13H19NO6S
    methyl 3-{[5,6-bis(methoxymethoxy)pyridin-3-yl]sulfanyl} propanoate
    —— 5-[(3-FIuorobenzyI)sulfanyl]-2,3-bis(methoxymethoxy)-pyridine 1417710-70-3 C16H18FNO4S
    5-[(3-FIuorobenzyI)sulfanyl]-2,3-bis(methoxymethoxy)-pyridine
    —— 2-propyl-2-(10,12-dioxatridecyl)-1,3-dithiane 317801-89-1 C18H36O2S2
    2-propyl-2-(10,12-dioxatridecyl)-1,3-dithiane
    —— N-methyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphinyl]propan-1-amine 228569-85-5 C9H16F5NOS
    N-methyl-3-[(4,4,5,5,5-pentafluoropentyl)sulphinyl]propan-1-amine
    —— N-{3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}cyclopropanamine 1353009-18-3 C11H18F5NO2S
    N-{3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}cyclopropanamine
    —— N-(2,2-difluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-22-9 C10H16F7NO2S
    N-(2,2-difluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 6-(4-fluorophenylthio)-2,4(1H,3H)-quinazolinedione 1354386-00-7 C14H9FN2O2S
    6-(4-fluorophenylthio)-2,4(1H,3H)-quinazolinedione
    —— 6-(4-tolylthio)-2,4(1H,3H)-quinazolinedione 1354385-98-0 C15H12N2O2S
    6-(4-tolylthio)-2,4(1H,3H)-quinazolinedione
    —— 2-methyl-1-({3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}amino)propan-2-ol 1353009-14-9 C12H22F5NO3S
    2-methyl-1-({3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propyl}amino)propan-2-ol
    —— N-(2-fluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine 1353009-17-2 C10H17F6NO2S
    N-(2-fluoroethyl)-3-[(4,4,5,5,5-pentafluoropentyl)sulphonyl]propan-1-amine
    —— 3-chloropropyl 4,4,5,5,5-pentafluoropentyl sulphide 199730-47-7 C8H12ClF5S
    3-chloropropyl 4,4,5,5,5-pentafluoropentyl sulphide
    —— 3-chloropropyl-4,4,5,5,5-pentafluoropentylsulphoxide 240121-79-3 C8H12ClF5OS
    3-chloropropyl-4,4,5,5,5-pentafluoropentylsulphoxide
    —— 2-Amino-6,7-dihydro-4-methylthio-5H-cyclopentapyrimidin 7511-83-3 C8H11N3S
    2-Amino-6,7-dihydro-4-methylthio-5H-cyclopentapyrimidin
    —— 4-(4-chloro-phenylsulfanyl)-6,7-dihydro-5<i>H</i>-cyclopentapyrimidin-2-ylamine 108758-99-2 C13H12ClN3S
    4-(4-chloro-phenylsulfanyl)-6,7-dihydro-5<i>H</i>-cyclopentapyrimidin-2-ylamine
    —— 2-Methylthio-trans-buten-(2)-(Z) 50406-82-1 C5H10S
    2-Methylthio-trans-buten-(2)-(Z)
    —— Thioacetyl-N,N-diisopropyl-hydrazin 29280-89-5 C8H18N2S
    Thioacetyl-N,N-diisopropyl-hydrazin
    —— 2-Amino-3-methylmercapto-crotonitril 32303-44-9 C5H8N2S
    2-Amino-3-methylmercapto-crotonitril
    —— 2-Methylthio-cis-buten-(2)-(E) 50406-81-0 C5H10S
    2-Methylthio-cis-buten-(2)-(E)
    —— 3-methyl-4,4-bis-methylsulfanyl-pent-1-ene 62418-89-7 C8H16S2
    3-methyl-4,4-bis-methylsulfanyl-pent-1-ene
    —— 3,3-bis-methylsulfanyl-but-1-ene 66312-60-5 C6H12S2
    3,3-bis-methylsulfanyl-but-1-ene
    —— 4,4-bis-methylsulfanyl-pent-1-ene 62418-88-6 C7H14S2
    4,4-bis-methylsulfanyl-pent-1-ene
    —— 2,2-dimethoxy-2-(2-methylsulfanylpyrimidin-4-yl)ethylamine 521092-49-9 C9H15N3O2S
    2,2-dimethoxy-2-(2-methylsulfanylpyrimidin-4-yl)ethylamine
    —— N-(1,3-dihydroxypropan-2-yl)ethanethioamide 1084772-40-6 C5H11NO2S
    N-(1,3-dihydroxypropan-2-yl)ethanethioamide
    —— 4-(Methylthio)-1,2,3-thiadiazole-5-carboxylic acid, ethyl ester 114393-65-6 C6H8N2O2S2
    4-(Methylthio)-1,2,3-thiadiazole-5-carboxylic acid, ethyl ester
    —— 3,3-dimethyl-4-thioxo-pentan-2-one 62234-58-6 C7H12OS
    3,3-dimethyl-4-thioxo-pentan-2-one
    —— 3-<Tris(phenylthio)methyl>-cyclohexanon 56003-65-7 C25H24OS3
    3-<Tris(phenylthio)methyl>-cyclohexanon
    —— 5-(3-bromo-4-hydroxybenzylidene)-3-(4-methylthiophenyl)-1,3-oxazolidin-2,4-dione 1379032-01-5 C17H12BrNO4S
    5-(3-bromo-4-hydroxybenzylidene)-3-(4-methylthiophenyl)-1,3-oxazolidin-2,4-dione
    —— 5-chloromethyl-3-[4-methylthiophenyl]-2-oxazolidinone 82768-00-1 C11H12ClNO2S
    5-chloromethyl-3-[4-methylthiophenyl]-2-oxazolidinone
    —— 4-Brom-4'-isothiocyanatodiphenylsulfid 19822-37-8 C13H8BrNS2
    4-Brom-4'-isothiocyanatodiphenylsulfid
    —— 1-Bromo-4-[(4-isothiocyanatophenyl)sulfanylmethyl]benzene 42498-05-5 C14H10BrNS2
    1-Bromo-4-[(4-isothiocyanatophenyl)sulfanylmethyl]benzene
    —— 1-Methoxy-1-phenylsulfanylcyclooctane 127700-33-8 C15H22OS
    1-Methoxy-1-phenylsulfanylcyclooctane
    —— 7-thiaoctyl bromide 87243-82-1 C7H15BrS
    7-thiaoctyl bromide
    —— (4S,5S)-4-Hydroxymethyl-2-<2-(4-methylphenylsulfanyl)phenyl>-5-phenyl-4,5-dihydro-1,3-oxazole 160246-28-6 C23H21NO2S
    (4S,5S)-4-Hydroxymethyl-2-<2-(4-methylphenylsulfanyl)phenyl>-5-phenyl-4,5-dihydro-1,3-oxazole
    —— 4-Heptylsulfanylbutan-2-amine 94381-71-2 C11H25NS
    4-Heptylsulfanylbutan-2-amine
    —— tert-butyl-dimethyl-[[(4S,5S)-2-[2-(4-methylphenyl)sulfanylphenyl]-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methoxy]silane 175477-27-7 C29H35NO2SSi
    tert-butyl-dimethyl-[[(4S,5S)-2-[2-(4-methylphenyl)sulfanylphenyl]-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methoxy]silane
    —— PhSCH2Si(CH3)2N(H)Si(CH3)2CH2SPh 688736-35-8 C18H27NS2Si2
    PhSCH2Si(CH3)2N(H)Si(CH3)2CH2SPh
    —— 4-bromophenyl 1-cyclohexenyl sulfide 1351526-39-0 C12H13BrS
    4-bromophenyl 1-cyclohexenyl sulfide