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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methylsulphenyl-4-methylamino-5-methyl-pyrimidine 500352-50-1 C7H11N3S
    2-methylsulphenyl-4-methylamino-5-methyl-pyrimidine
    —— 2-(methylthio)-4-(phenylamino)pyrimidine-5-carbonitrile 280582-33-4 C12H10N4S
    2-(methylthio)-4-(phenylamino)pyrimidine-5-carbonitrile
    —— 3-methylthio-5-cyclohexyl-1,2,4-thiadiazole 699003-70-8 C9H14N2S2
    3-methylthio-5-cyclohexyl-1,2,4-thiadiazole
    —— 5-(4-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-82-2 C10H16N2S2
    5-(4-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 5-(2-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-80-0 C10H16N2S2
    5-(2-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 5-(3-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-76-4 C10H16N2S2
    5-(3-methylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— methyl[(2-chloroethyl)sulfinyl]acetate 1378712-28-7 C5H9ClO3S
    methyl[(2-chloroethyl)sulfinyl]acetate
    —— 5-(3-ethylcyclohexyl)-3-methylthio-1,2,4-thiadiazole 699003-84-4 C11H18N2S2
    5-(3-ethylcyclohexyl)-3-methylthio-1,2,4-thiadiazole
    —— 3-methylthio-5-cyclopentyl-1,2,4-thiadiazole 699003-72-0 C8H12N2S2
    3-methylthio-5-cyclopentyl-1,2,4-thiadiazole
    —— 1-methyl-3-phenylsulfanyl-2-piperidinone 59953-51-4 C12H15NOS
    1-methyl-3-phenylsulfanyl-2-piperidinone
    —— 3-methylthio-5-(cyclohexyl)methyl-1,2,4-thiadiazole 699003-74-2 C10H16N2S2
    3-methylthio-5-(cyclohexyl)methyl-1,2,4-thiadiazole
    —— (2-cyclohexyl-3,3,3-trifluoro-1-phenylsulfanylpropyl)sulfanylbenzene 144765-03-7 C21H23F3S2
    (2-cyclohexyl-3,3,3-trifluoro-1-phenylsulfanylpropyl)sulfanylbenzene
    —— 3-<bis(phenylthio)(trimethylsilyl)methyl>cyclohexanone 104115-24-4 C22H28OS2Si
    3-<bis(phenylthio)(trimethylsilyl)methyl>cyclohexanone
    —— 3-<bis(phenylthio)methylene>-1-methyl-1-cyclohexene 104115-34-6 C20H20S2
    3-<bis(phenylthio)methylene>-1-methyl-1-cyclohexene
    —— 5-phenylthiodec-5-ene 107014-79-9 C16H24S
    5-phenylthiodec-5-ene
    —— 1,1-bis(phenylthio)-2-methyl-1-(trimethylsilyl)-4-pentanone 104115-36-8 C21H28OS2Si
    1,1-bis(phenylthio)-2-methyl-1-(trimethylsilyl)-4-pentanone
    —— Bis(phenylthio)bis(trimethylsilyl)methane 87729-86-0 C19H28S2Si2
    Bis(phenylthio)bis(trimethylsilyl)methane
    —— 7-(phenylthio)-7-(trimethylsilyl)bicyclo[4.1.0]heptane 115025-76-8 C16H24SSi
    7-(phenylthio)-7-(trimethylsilyl)bicyclo[4.1.0]heptane
    —— [3,3,3-Trifluoro-1,1-bis(phenylsulfanyl)prop-1-en-2-yl]benzene 144764-92-1 C21H15F3S2
    [3,3,3-Trifluoro-1,1-bis(phenylsulfanyl)prop-1-en-2-yl]benzene
    —— 3,6-dihydro-4,5-dimethyl-2,2-bis(phenylthio)-2H-thiapyran 1-oxide 88534-34-3 C19H20OS3
    3,6-dihydro-4,5-dimethyl-2,2-bis(phenylthio)-2H-thiapyran 1-oxide
    —— (1-phenylthiopentylidene)cyclohexane 87729-85-9 C17H24S
    (1-phenylthiopentylidene)cyclohexane
    —— 2-phenylthio-1-phenylhex-1-ene 87729-83-7 C18H20S
    2-phenylthio-1-phenylhex-1-ene
    —— 4-phenyl-1,1-bis(phenylthio)but-1-ene 111171-95-0 C22H20S2
    4-phenyl-1,1-bis(phenylthio)but-1-ene
    —— 7-(phenylthio)-7-(trimethylsilyl)bicyclo<4.1.0>heptan-2-one 112022-44-3 C16H22OSSi
    7-(phenylthio)-7-(trimethylsilyl)bicyclo<4.1.0>heptan-2-one
    —— 1,1-bis(phenylthio)-3-methyl-1-(trimethylsilyl)butane 105494-77-7 C20H28S2Si
    1,1-bis(phenylthio)-3-methyl-1-(trimethylsilyl)butane
    —— 7-amino-5-(methylthio)<1,2,5>oxadiazolo<3,4-d>pyrimidine 30708-68-0 C5H5N5OS
    7-amino-5-(methylthio)<1,2,5>oxadiazolo<3,4-d>pyrimidine
    —— cis-N-(2-phenylthio-1-methylvinyl)methylurethane 85212-37-9 C11H13NO2S
    cis-N-(2-phenylthio-1-methylvinyl)methylurethane
    —— 1-t-Butoxycarbonyl-4-((2-bromophenyl)thio)methyl-1,2,5,6-tetrahydropyridine 159635-24-2 C17H22BrNO2S
    1-t-Butoxycarbonyl-4-((2-bromophenyl)thio)methyl-1,2,5,6-tetrahydropyridine
    —— trans-N-(2-phenylthio-1-methylvinyl)methylurethane 85212-38-0 C11H13NO2S
    trans-N-(2-phenylthio-1-methylvinyl)methylurethane
    —— N-n-Butyl-N'-(2-mercaptoethyl)-thioharnstoff 89851-15-0 C7H16N2S2
    N-n-Butyl-N'-(2-mercaptoethyl)-thioharnstoff
    —— 2-Amino-2-methylethanthiol-hydrochlorid 4145-98-6 C3H9NS*ClH
    2-Amino-2-methylethanthiol-hydrochlorid
    —— N,N-diisopropyl-6-(phenylthio)-1-cyclohexenecarboxamide 80997-44-0 C19H27NOS
    N,N-diisopropyl-6-(phenylthio)-1-cyclohexenecarboxamide
    —— 2-[4-methyl-3-(methylsulfanyl)phenyl]-1,3-dioxolane 315188-39-7 C11H14O2S
    2-[4-methyl-3-(methylsulfanyl)phenyl]-1,3-dioxolane
    —— Bis-(2-amino-propyl)-disulfid 4390-09-4 C6H16N2S2
    Bis-(2-amino-propyl)-disulfid
    —— [1-benzyl-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester 868673-20-5 C27H27N3O4S
    [1-benzyl-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester
    —— [1-(2-fluoro-benzyl)-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester 868673-21-6 C27H26FN3O4S
    [1-(2-fluoro-benzyl)-3-(2-nitro-phenylsulfanyl)-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester
    —— 1-[5-(methylthio)thiophen-2-yl]ethanone 22102-48-3 C7H8OS2
    1-[5-(methylthio)thiophen-2-yl]ethanone
    —— 2-(ethylthio)-5-methylthiophene 6522-11-8 C7H10S2
    2-(ethylthio)-5-methylthiophene
    —— (5-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester 731017-53-1 C9H10O3S2
    (5-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester
    —— 5-(methylthio)-2-thiophenesulfonamide 142294-53-9 C5H7NO2S3
    5-(methylthio)-2-thiophenesulfonamide
    —— (3-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester 731017-54-2 C9H10O3S2
    (3-methylsulfanyl-thiophen-2-yl)-oxo-acetic acid ethyl ester
    —— thiocarbamic acid <i>S</i>-thiophen-2-yl ester 60830-65-1 C5H5NOS2
    thiocarbamic acid <i>S</i>-thiophen-2-yl ester
    —— 4-(4-aminophenyl)sulfanyl-N-[(1S)-1-cyclohexylethyl]-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide 943779-36-0 C31H36N6OS
    4-(4-aminophenyl)sulfanyl-N-[(1S)-1-cyclohexylethyl]-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(4-pyridyl)ethyl]benzamide 943779-32-6 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(4-pyridyl)ethyl]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-pyridyl)ethyl]benzamide 943779-28-0 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-pyridyl)ethyl]benzamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(3-pyridyl)ethyl]benzamide 943779-30-4 C30H29N7OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(3-pyridyl)ethyl]benzamide
    —— (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-bromoacetate 1268473-48-8 C17H16BrClO2S
    (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-bromoacetate
    —— 2-[4,5-bis(pentylthio)-1,3-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole 300766-21-6 C18H25NS6
    2-[4,5-bis(pentylthio)-1,3-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole
    —— 2-Amino-4-(3-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357289-36-2 C16H15N7S
    2-Amino-4-(3-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 2-Amino-4-(4-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile 357289-33-9 C16H15N7S
    2-Amino-4-(4-methyl-pyrazol-1-yl)-6-(2-pyridin-2-yl-ethylsulfanyl)-pyrimidine-5-carbonitrile