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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4''S,5''R)-methyl N-<2-(2'',2''-dimethyl-5''-vinyl-<1'',3''>dioxolan-4''-ylmethyl)-<1,3>dithian-2-ylmethyl>carbamate 139540-32-2 C15H25NO4S2
    (4''S,5''R)-methyl N-<2-(2'',2''-dimethyl-5''-vinyl-<1'',3''>dioxolan-4''-ylmethyl)-<1,3>dithian-2-ylmethyl>carbamate
    —— 2-[2-(2-isopropoxyethylamino)benzylthio]imidazole 134017-57-5 C15H21N3OS
    2-[2-(2-isopropoxyethylamino)benzylthio]imidazole
    —— N,N-di(butyl)-N'-pivaloylthiourea 446310-85-6 C14H28N2OS
    N,N-di(butyl)-N'-pivaloylthiourea
    —— 2,6-Me2C6H3NHC6H4CH=NPh-2-SPh 1382241-20-4 C27H24N2S
    2,6-Me2C6H3NHC6H4CH=NPh-2-SPh
    —— (R)-1-{2-[2-(tert-Butyl-diphenyl-silanyloxy)-1,1-dimethyl-ethyl]-[1,3]dithian-2-yl}-4-hydroxy-5-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-pentan-2-one 169899-65-4 C35H52O5S2Si
    (R)-1-{2-[2-(tert-Butyl-diphenyl-silanyloxy)-1,1-dimethyl-ethyl]-[1,3]dithian-2-yl}-4-hydroxy-5-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-pentan-2-one
    —— 2-methylsulfanyl-6-(6-morpholin-4-yl-pyridin-2-yl)-pyrimidin-4-ylamine 1061750-23-9 C14H17N5OS
    2-methylsulfanyl-6-(6-morpholin-4-yl-pyridin-2-yl)-pyrimidin-4-ylamine
    —— 2,6-i-Pr2C6H3NHC6H4CH=NPh-2-SPh 1382241-23-7 C31H32N2S
    2,6-i-Pr2C6H3NHC6H4CH=NPh-2-SPh
    —— PhNHC6H4CH=NPh-2-SPh 1382241-17-9 C25H20N2S
    PhNHC6H4CH=NPh-2-SPh
    —— 2-(4-Pyridyl)-ethyl-4-fluorphenyl-sulfid 62237-51-8 C13H12FNS
    2-(4-Pyridyl)-ethyl-4-fluorphenyl-sulfid
    —— tert-butyl 4-(2-((4-nitrophenyl)thio)benzoyl)piperazine-1-carboxylate 1391741-37-9 C22H25N3O5S
    tert-butyl 4-(2-((4-nitrophenyl)thio)benzoyl)piperazine-1-carboxylate
    —— 2-(3,4,5-trimethoxyphenylthio)benzoxazole 1569303-96-3 C16H15NO4S
    2-(3,4,5-trimethoxyphenylthio)benzoxazole
    —— [(5-Benzyl-4-ethyl-4h-1,2,4-triazol-3-yl)sulfanyl]acetic acid 305337-14-8 C13H15N3O2S
    [(5-Benzyl-4-ethyl-4h-1,2,4-triazol-3-yl)sulfanyl]acetic acid
    —— methyl 7-oxo-6-phenylthio-octanoate 98711-86-5 C15H20O3S
    methyl 7-oxo-6-phenylthio-octanoate
    —— 3,3-bis(phenylsulfenyl)bicyclo<4.3.0>-1(6)-nonen-2-one 107053-86-1 C21H20OS2
    3,3-bis(phenylsulfenyl)bicyclo<4.3.0>-1(6)-nonen-2-one
    —— 5-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)dipyrromethane 1217353-51-9 C14H12Cl2N4S
    5-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)dipyrromethane
    —— 1-methylsulfonyl-cyclohexene 59059-68-6 C7H12O2S
    1-methylsulfonyl-cyclohexene
    —— 5-acetyl-4-methylsulfanyl-6-morpholino-2-phenylpyrimidine 339584-48-4 C17H19N3O2S
    5-acetyl-4-methylsulfanyl-6-morpholino-2-phenylpyrimidine
    —— (5-p-Tolyl-[1,3,4]oxadiazol-2-ylsulfanyl)-acetic acid isopropyl ester 5807-40-9 C14H16N2O3S
    (5-p-Tolyl-[1,3,4]oxadiazol-2-ylsulfanyl)-acetic acid isopropyl ester
    —— 6-[2-(1,3-dioxolan-2-yl)ethyl]-2,2-bisphenylthiocyclohexanone 258514-09-9 C23H26O3S2
    6-[2-(1,3-dioxolan-2-yl)ethyl]-2,2-bisphenylthiocyclohexanone
    —— 6-[2-(1,3-dioxolan-2-yl)ethyl]-2-phenylthio-2-cyclohexen-1-one 258514-11-3 C17H20O3S
    6-[2-(1,3-dioxolan-2-yl)ethyl]-2-phenylthio-2-cyclohexen-1-one
    —— ((E)-3-Methyl-buta-1,3-dienylsulfanyl)-benzene 53097-26-0 C11H12S
    ((E)-3-Methyl-buta-1,3-dienylsulfanyl)-benzene
    —— 5-hydroxy-2-methyl-4,4-bisphenylthiohept-1-ene 98793-20-5 C20H24OS2
    5-hydroxy-2-methyl-4,4-bisphenylthiohept-1-ene
    —— (4H-[1,2,4]Triazol-3-ylsulfanyl)-acetic acid ethyl ester 307545-28-4 C6H9N3O2S
    (4H-[1,2,4]Triazol-3-ylsulfanyl)-acetic acid ethyl ester
    —— 3-methyl-3-(phenylsulfenyl)-bicyclo<4.3.0>-1(6)-nonen-2-one 107053-83-8 C16H18OS
    3-methyl-3-(phenylsulfenyl)-bicyclo<4.3.0>-1(6)-nonen-2-one
    —— 3-(phenylsulfenyl)-bicyclo<4.3.0>-1(6)-nonen-2-one 107053-82-7 C15H16OS
    3-(phenylsulfenyl)-bicyclo<4.3.0>-1(6)-nonen-2-one
    —— 7-(phenylsulfenyl)-1-methylbicyclo<4.3.0>-6(7)-nonen-2-one 107053-85-0 C16H18OS
    7-(phenylsulfenyl)-1-methylbicyclo<4.3.0>-6(7)-nonen-2-one
    —— [(E)-1-chloro-2-phenylethenyl]sulfanylbenzene 96336-02-6 C14H11ClS
    [(E)-1-chloro-2-phenylethenyl]sulfanylbenzene
    —— cis-7a-hydroxy-3a-(phenylsulfenyl)-3a,4,5,6,7,7a-hexahydro-4-indanone 107053-80-5 C15H18O2S
    cis-7a-hydroxy-3a-(phenylsulfenyl)-3a,4,5,6,7,7a-hexahydro-4-indanone
    —— bis(2,2-difluoro-2-nitroethyl)thionocarbonate 80456-68-4 C5H4F4N2O6S
    bis(2,2-difluoro-2-nitroethyl)thionocarbonate
    —— 6-Methoxy-2-phenylsulfanylquinoline-3-carbaldehyde 433705-71-6 C17H13NO2S
    6-Methoxy-2-phenylsulfanylquinoline-3-carbaldehyde
    —— 5,7-dihydrodibenzo<b,g>-1,4-thiazocin-6-thione 87213-28-3 C14H11NS2
    5,7-dihydrodibenzo<b,g>-1,4-thiazocin-6-thione
    —— 7-methylsulfanyl-5-oxo-5H-thiazolo[3,2-a]pyrimidine-6-carbonitrile 503423-85-6 C8H5N3OS2
    7-methylsulfanyl-5-oxo-5H-thiazolo[3,2-a]pyrimidine-6-carbonitrile
    —— 4-hydroxy-6-methyl-3-phenylthio-2(1H)-pyridone 54885-26-6 C12H11NO2S
    4-hydroxy-6-methyl-3-phenylthio-2(1H)-pyridone
    —— Penten-(4)-yl-butyl-sulfid 20217-78-1 C9H18S
    Penten-(4)-yl-butyl-sulfid
    —— (4-Chloro-6-dimethylamino-pyrimidin-2-ylsulfanyl)-acetic acid 86627-43-2 C8H10ClN3O2S
    (4-Chloro-6-dimethylamino-pyrimidin-2-ylsulfanyl)-acetic acid
    —— 2-Mercapto-6-{[(4-methylphenyl)thio]-methyl}pyrimidin-4(3H)-one 299937-81-8 C12H12N2OS2
    2-Mercapto-6-{[(4-methylphenyl)thio]-methyl}pyrimidin-4(3H)-one
    —— 2-Carboxymethylthio-5-o-tolyl-1,3,4-oxadiazol 71134-66-2 C11H10N2O3S
    2-Carboxymethylthio-5-o-tolyl-1,3,4-oxadiazol
    —— N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-1-phenylmethanimine 5483-69-2 C18H17N3S
    N-[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]phenyl]-1-phenylmethanimine
    —— 2-Methyl-5-thiocyanato-pyrrol 89418-02-0 C6H6N2S
    2-Methyl-5-thiocyanato-pyrrol
    —— 2-[2-(2-thienylsulfanyl)-1H-pyrrolyl]acetic acid 760945-80-0 C10H9NO2S2
    2-[2-(2-thienylsulfanyl)-1H-pyrrolyl]acetic acid
    —— (4,5-Dihydro-1H-imidazol-2-yl)-[2-(4-methoxy-phenylsulfanyl)-phenyl]-amine 677343-24-7 C16H17N3OS
    (4,5-Dihydro-1H-imidazol-2-yl)-[2-(4-methoxy-phenylsulfanyl)-phenyl]-amine
    —— 4,5-dihydropyrrolo[2,1-b]thieno[3,2-f][1,3]thiazepin-4-one 760945-83-3 C10H7NOS2
    4,5-dihydropyrrolo[2,1-b]thieno[3,2-f][1,3]thiazepin-4-one
    —— (2-pyrrolylsulfanyl)acetic acid 89597-78-4 C6H7NO2S
    (2-pyrrolylsulfanyl)acetic acid
    —— 5-[2-(Dimethylazaniumyl)ethylsulfanyl]-1,3,4-thiadiazole-2-thiolate —— C6H11N3S3
    5-[2-(Dimethylazaniumyl)ethylsulfanyl]-1,3,4-thiadiazole-2-thiolate
    —— 4-Amino-2-benzylthio-5-cyan-pyrimidin 100137-41-5 C12H10N4S
    4-Amino-2-benzylthio-5-cyan-pyrimidin
    —— 1-methyl-4-<2-(2-hydroxymethylphenylthio)benzoyl>piperazine 93288-95-0 C19H22N2O2S
    1-methyl-4-<2-(2-hydroxymethylphenylthio)benzoyl>piperazine
    —— 2-(2-(benzylthio)-1H-imidazol-4-yl)-6-methylpyridine 1418306-03-2 C16H15N3S
    2-(2-(benzylthio)-1H-imidazol-4-yl)-6-methylpyridine
    —— Furan-2-yl-[5-(furan-2-yl)-3-methylsulfanylfuran-2-yl]methanone 123958-30-5 C14H10O4S
    Furan-2-yl-[5-(furan-2-yl)-3-methylsulfanylfuran-2-yl]methanone
    —— N-(2-(phenylthio)benzyl)pyrrolidine 127876-53-3 C17H19NS
    N-(2-(phenylthio)benzyl)pyrrolidine
    —— 2-<2-(4-isopropylphenylthio)-5-nitrophenyl>acetic acid 91528-08-4 C17H17NO4S
    2-<2-(4-isopropylphenylthio)-5-nitrophenyl>acetic acid