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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(benzylideneamino)-3-(methylthio)-6-phenyl-1,2,4-triazin-5(4H)-one 22279-38-5 C17H14N4OS
    4-(benzylideneamino)-3-(methylthio)-6-phenyl-1,2,4-triazin-5(4H)-one
    —— (R)-2-Hydroxy-3-(phenylthio)propanoic acid 83023-81-8 C9H10O3S
    (R)-2-Hydroxy-3-(phenylthio)propanoic acid
    —— 5-chloro-6-methyl-3-(phenylmethylthio)-2H-1,4-oxazin-2-one 142330-89-0 C12H10ClNO2S
    5-chloro-6-methyl-3-(phenylmethylthio)-2H-1,4-oxazin-2-one
    —— Ethyl 2-amino-5-hydroxy-4-(4-methoxyphenyl)sulfanyl-furo[2,3-f]quinazoline-3-carboxylate 1355613-21-6 C20H17N3O5S
    Ethyl 2-amino-5-hydroxy-4-(4-methoxyphenyl)sulfanyl-furo[2,3-f]quinazoline-3-carboxylate
    —— Ethyl 2-amino-4-(4-chlorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate 1355613-22-7 C19H14ClN3O4S
    Ethyl 2-amino-4-(4-chlorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate
    —— Ethyl 2-amino-4-(4-bromophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate 1355613-23-8 C19H14BrN3O4S
    Ethyl 2-amino-4-(4-bromophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate
    —— ethyl 2-amino-5-hydroxy-4-(p-tolylthio)furo[2,3-f]quinazoline-3-carboxylate 1355613-20-5 C20H17N3O4S
    ethyl 2-amino-5-hydroxy-4-(p-tolylthio)furo[2,3-f]quinazoline-3-carboxylate
    —— Ethyl 2-amino-4-(3,4-difluorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate 1355613-24-9 C19H13F2N3O4S
    Ethyl 2-amino-4-(3,4-difluorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate
    —— Ethyl 2-amino-4-(4-fluorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate 1355613-25-0 C19H14FN3O4S
    Ethyl 2-amino-4-(4-fluorophenyl)sulfanyl-5-hydroxy-furo[2,3-f]quinazoline-3-carboxylate
    —— methyl-(1-methyl-1-methylsulfanyl-propyl)-disulfane 69078-85-9 C6H14S3
    methyl-(1-methyl-1-methylsulfanyl-propyl)-disulfane
    —— 4-(3,5-dichloro-phenylsulfanyl)-3-isopropyl-1-methyl-5-[1-hydroxy-1-pyridin-4-ylmethyl]-1,3-dihydro-imidazol-2-one 431880-87-4 C19H19Cl2N3O2S
    4-(3,5-dichloro-phenylsulfanyl)-3-isopropyl-1-methyl-5-[1-hydroxy-1-pyridin-4-ylmethyl]-1,3-dihydro-imidazol-2-one
    —— 2-amino-5-benzylthiopyrazine 136743-00-5 C11H11N3S
    2-amino-5-benzylthiopyrazine
    —— bis-(2-aminopyrazine) 5-sulfide 136743-03-8 C8H8N6S
    bis-(2-aminopyrazine) 5-sulfide
    —— 5-[2-methyl-4-(methylthio)phenyl]-2-pyrazinamine 1032825-89-0 C12H13N3S
    5-[2-methyl-4-(methylthio)phenyl]-2-pyrazinamine
    —— 5-[2-fluoro-4-(methylthio)phenyl]-2-pyrazinamine 1032825-58-3 C11H10FN3S
    5-[2-fluoro-4-(methylthio)phenyl]-2-pyrazinamine
    —— S-methanesulfinylmethyl-isothiourea 760115-58-0 C3H8N2OS2
    S-methanesulfinylmethyl-isothiourea
    —— 2,6-Dichloro-3,5-bis(benzylthio)pyridine 129836-60-8 C19H15Cl2NS2
    2,6-Dichloro-3,5-bis(benzylthio)pyridine
    —— 2,6-Dichloro-3,5-bis(methylthio)pyridine 76942-26-2 C7H7Cl2NS2
    2,6-Dichloro-3,5-bis(methylthio)pyridine
    —— 2-(phenylsulfanyl)-3-chloropyrazine 54127-76-3 C10H7ClN2S
    2-(phenylsulfanyl)-3-chloropyrazine
    —— 1-isopropylamino-3-(3-phenylsulfanyl-pyrazin-2-yloxy)-propan-2-ol 54127-77-4 C16H21N3O2S
    1-isopropylamino-3-(3-phenylsulfanyl-pyrazin-2-yloxy)-propan-2-ol
    —— N-Methylmercapto-thionylimid 20706-09-6 CH3NOS2
    N-Methylmercapto-thionylimid
    —— (1-ethyl-allyl)-thiourea 854653-31-9 C6H12N2S
    (1-ethyl-allyl)-thiourea
    —— (S)-1-Amino-4-methyl-pentane-2-thiol 765256-87-9 C6H15NS
    (S)-1-Amino-4-methyl-pentane-2-thiol
    —— S-methyl-N,N-dipropylisothiourea 75191-77-4 C8H18N2S*HI
    S-methyl-N,N-dipropylisothiourea
    —— 2-(phenylthio)prop-2-en-1-ol 52072-15-8 C9H10OS
    2-(phenylthio)prop-2-en-1-ol
    —— (1S,2R)-2-Methyl-2-phenyl-[1,3]dithiolane 1-oxide —— C10H12OS2
    (1S,2R)-2-Methyl-2-phenyl-[1,3]dithiolane 1-oxide
    —— (E)-2-methyl-2-phenyl-1,3-dithiolane S-oxide 89614-16-4 C10H12OS2
    (E)-2-methyl-2-phenyl-1,3-dithiolane S-oxide
    —— 2-methyl-2-phenyl-1,3-dithiolane 1-oxide 110379-08-3 C10H12OS2
    2-methyl-2-phenyl-1,3-dithiolane 1-oxide
    —— <2-Brom-4-methyl-phenylmercapto>-essigsaeure 17067-13-9 C9H9BrO2S
    <2-Brom-4-methyl-phenylmercapto>-essigsaeure
    —— 5-amino-6-methylamino-3-methylthio-as-triazine 87591-97-7 C5H9N5S
    5-amino-6-methylamino-3-methylthio-as-triazine
    —— Bis[2-(ethylsulfinyl)ethyl]disulfide 74857-97-9 C8H18O2S4
    Bis[2-(ethylsulfinyl)ethyl]disulfide
    —— 7-methyl-3-methylthioimidazo<4,5-e>-as-triazine 105782-41-0 C6H7N5S
    7-methyl-3-methylthioimidazo<4,5-e>-as-triazine
    —— ethyl 2-[2-(ethylsulfinyl)ethyl]sulfanylethyl sulfoxide 74857-98-0 C8H18O2S3
    ethyl 2-[2-(ethylsulfinyl)ethyl]sulfanylethyl sulfoxide
    —— 8-Methyl-3-methylsulfanyl-5,6,7,8-tetrahydro-pyrazino[2,3-e][1,2,4]triazine-6,7-diol 87611-90-3 C7H11N5O2S
    8-Methyl-3-methylsulfanyl-5,6,7,8-tetrahydro-pyrazino[2,3-e][1,2,4]triazine-6,7-diol
    —— 6-methylamino-3,5-dimethylthio-as-triazine 87591-99-9 C6H10N4S2
    6-methylamino-3,5-dimethylthio-as-triazine
    —— Thioessigsaeure-S-acetoxymethylester 51930-27-9 C5H8O3S
    Thioessigsaeure-S-acetoxymethylester
    —— 4-Chloro-1-chloromethyl-2-(4-fluoro-phenylsulfanyl)-benzene 54435-30-2 C13H9Cl2FS
    4-Chloro-1-chloromethyl-2-(4-fluoro-phenylsulfanyl)-benzene
    —— 4-(4-bromobutylsulfanyl)-2-chloromethyl-3-methylpyridine hydrochloride 251345-09-2 C11H15BrClNS*ClH
    4-(4-bromobutylsulfanyl)-2-chloromethyl-3-methylpyridine hydrochloride
    —— 4-(4-Hydroxybutylthio)-2-hydroxymethyl-3-methylpyridine 162280-08-2 C11H17NO2S
    4-(4-Hydroxybutylthio)-2-hydroxymethyl-3-methylpyridine
    —— [4-Chloro-2-(4-fluoro-phenylsulfanyl)-phenyl]-acetic acid 54435-47-1 C14H10ClFO2S
    [4-Chloro-2-(4-fluoro-phenylsulfanyl)-phenyl]-acetic acid
    —— methyloctyl sulfone 7560-60-3 C9H20O2S
    methyloctyl sulfone
    —— [4-(4-bromobutylsulfanyl)-3-methylpyridin-2-yl]methanol 251345-08-1 C11H16BrNOS
    [4-(4-bromobutylsulfanyl)-3-methylpyridin-2-yl]methanol
    —— (3-Methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)ethoxy]-ethylsulfanyl}-pyridin-2-yl)-methanol 198200-24-7 C13H18F3NO3S
    (3-Methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)ethoxy]-ethylsulfanyl}-pyridin-2-yl)-methanol
    —— 5-hydroxy-4,6-dimethyl-2-pyridyl n-octyl sulfide 1062541-66-5 C15H25NOS
    5-hydroxy-4,6-dimethyl-2-pyridyl n-octyl sulfide
    —— Trifluoro-methanethiosulfonic acid S-octyl ester 181820-61-1 C9H17F3O2S2
    Trifluoro-methanethiosulfonic acid S-octyl ester
    —— 3-hydroxy-4,6-dimethyl-2-pyridyl n-octyl sulfide 1062541-57-4 C15H25NOS
    3-hydroxy-4,6-dimethyl-2-pyridyl n-octyl sulfide
    —— 5-hydroxy-2-pyridyl n-octyl sulfide 1062541-42-7 C13H21NOS
    5-hydroxy-2-pyridyl n-octyl sulfide
    —— 2-methoxyethyl octyl disulfide 1020261-25-9 C11H24OS2
    2-methoxyethyl octyl disulfide
    —— 3-hydroxy-6-methyl-2-pyridyl n-octyl sulfide 1062541-52-9 C14H23NOS
    3-hydroxy-6-methyl-2-pyridyl n-octyl sulfide
    —— 1-Pentylsulfanyl-octane 62103-68-8 C13H28S
    1-Pentylsulfanyl-octane