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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[1-(5-bromo-3-methylpyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline 1026922-67-7 C18H19BrN4S
    2-[[1-(5-bromo-3-methylpyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline
    —— 1-(pyridin-4-yl)-2-(2-dimethylaminobenzylthio)imidazole 117348-02-4 C17H18N4S
    1-(pyridin-4-yl)-2-(2-dimethylaminobenzylthio)imidazole
    —— N,N-dimethyl-2-[(1-pyridin-2-yl-4,5,6,7-tetrahydrobenzimidazol-2-yl)sulfanylmethyl]aniline 117323-73-6 C21H24N4S
    N,N-dimethyl-2-[(1-pyridin-2-yl-4,5,6,7-tetrahydrobenzimidazol-2-yl)sulfanylmethyl]aniline
    —— 2-[(2-dimethylamino)benzylthio]-1-methylimidazole 123823-51-8 C13H17N3S
    2-[(2-dimethylamino)benzylthio]-1-methylimidazole
    —— 2-[[1-(5-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline 117392-85-5 C18H20N4OS
    2-[[1-(5-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline
    —— N,N-dimethyl-2-[(1-pyrimidin-2-ylimidazol-2-yl)sulfanylmethyl]aniline 1026493-25-3 C16H17N5S
    N,N-dimethyl-2-[(1-pyrimidin-2-ylimidazol-2-yl)sulfanylmethyl]aniline
    —— 2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline 117348-08-0 C18H20N4OS
    2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline
    —— 2-[(2-dimethylamino)benzylthio]imidazole 128936-06-1 C12H15N3S
    2-[(2-dimethylamino)benzylthio]imidazole
    —— 2-[[1-(4-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline 117348-06-8 C18H20N4OS
    2-[[1-(4-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]-N,N-dimethylaniline
    —— 2-[(1-benzylimidazol-2-yl)sulfanylmethyl]-N,N-dimethylaniline 1026882-42-7 C19H21N3S
    2-[(1-benzylimidazol-2-yl)sulfanylmethyl]-N,N-dimethylaniline
    —— N,N-dimethyl-2-[[1-(6-methylpyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline 117348-07-9 C18H20N4S
    N,N-dimethyl-2-[[1-(6-methylpyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline
    —— N,N-dimethyl-2-[[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylmethyl]aniline 117347-98-5 C18H20N4S
    N,N-dimethyl-2-[[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylmethyl]aniline
    —— 3-phenylthio-3-trimethylsilylpropane-1-ol 78375-76-5 C12H20OSSi
    3-phenylthio-3-trimethylsilylpropane-1-ol
    —— (E,Z,3RS,5S)-3-(9-iodonon-8-enyl)-5-methyl-3-(phenylsulfenyl)-tetrahydrofuran-2-one 288585-40-0 C20H27IO2S
    (E,Z,3RS,5S)-3-(9-iodonon-8-enyl)-5-methyl-3-(phenylsulfenyl)-tetrahydrofuran-2-one
    —— 2,5-bis<2-(chloroethyl)thio>-1,3,4-thiadiazole 105784-96-1 C6H8Cl2N2S3
    2,5-bis<2-(chloroethyl)thio>-1,3,4-thiadiazole
    —— 3-chloromethyl-5-methylthio-4-propyl-4H-1,2,4-triazole hydrochloride 497851-83-9 C7H12ClN3S*ClH
    3-chloromethyl-5-methylthio-4-propyl-4H-1,2,4-triazole hydrochloride
    —— 3-chloromethyl-5-ethylthio-4-isobutyl-4H-1,2,4-triazole hydrochloride 497851-82-8 C9H16ClN3S*ClH
    3-chloromethyl-5-ethylthio-4-isobutyl-4H-1,2,4-triazole hydrochloride
    —— 1-phenylthio-2-phenyl-2-trimethylsilylethane 122760-30-9 C17H22SSi
    1-phenylthio-2-phenyl-2-trimethylsilylethane
    —— (E)-3-(phenylthio)-1,3-pentadiene 84132-33-2 C11H12S
    (E)-3-(phenylthio)-1,3-pentadiene
    —— (Z)-3-(phenylthio)-1,3-pentadiene 84132-32-1 C11H12S
    (Z)-3-(phenylthio)-1,3-pentadiene
    —— 2-(4-Bromo-2-nitrophenyl)sulfanyl-3-chloro-6-methylaniline 147054-42-0 C13H10BrClN2O2S
    2-(4-Bromo-2-nitrophenyl)sulfanyl-3-chloro-6-methylaniline
    —— 2-[2-(Phenylsulfanyl)furan-3-yl]ethan-1-ol 89861-16-5 C12H12O2S
    2-[2-(Phenylsulfanyl)furan-3-yl]ethan-1-ol
    —— Trimethyl{2-[2-(phenylsulfanyl)-5-(trimethylsilyl)furan-3-yl]ethoxy}silane 89861-17-6 C18H28O2SSi2
    Trimethyl{2-[2-(phenylsulfanyl)-5-(trimethylsilyl)furan-3-yl]ethoxy}silane
    —— 3-phenyl-4-[(4-phenylthien-3-yl)thio]thiophene 500772-24-7 C20H14S3
    3-phenyl-4-[(4-phenylthien-3-yl)thio]thiophene
    —— N-[2-(4-bromo-2-nitrophenyl)sulfanyl-3-chloro-6-methylphenyl]formamide 147054-48-6 C14H10BrClN2O3S
    N-[2-(4-bromo-2-nitrophenyl)sulfanyl-3-chloro-6-methylphenyl]formamide
    —— (E)-3-(2-Amino-4-furan-2-yl-6-methylsulfanyl-pyrimidin-5-yl)-acrylonitrile 357286-05-6 C12H10N4OS
    (E)-3-(2-Amino-4-furan-2-yl-6-methylsulfanyl-pyrimidin-5-yl)-acrylonitrile
    —— 3-iodo-1,1-bis(phenylthio)propane 83711-18-6 C15H15IS2
    3-iodo-1,1-bis(phenylthio)propane
    —— 1,2-bis(phenylthio)cyclobutene 70871-28-2 C16H14S2
    1,2-bis(phenylthio)cyclobutene
    —— S-[3,3-bis(phenylsulfanyl)propyl] cyclohexanecarbothioate 242483-24-5 C22H26OS3
    S-[3,3-bis(phenylsulfanyl)propyl] cyclohexanecarbothioate
    —— ethyl 2-ethylenedioxy-t-5-<2-(Z)-(5-hydroxypent-3-enyl)-1,3-dithian-2-yl>cyclopentan-r-1-ylacetate 93832-17-8 C20H32O5S2
    ethyl 2-ethylenedioxy-t-5-<2-(Z)-(5-hydroxypent-3-enyl)-1,3-dithian-2-yl>cyclopentan-r-1-ylacetate
    —— 1-methyl-4-(phenylthio)-1H-imidazole-5-methanol 141524-76-7 C11H12N2OS
    1-methyl-4-(phenylthio)-1H-imidazole-5-methanol
    —— 5-bromo-pentane-1-thiol 114764-15-7 C5H11BrS
    5-bromo-pentane-1-thiol
    —— 1-((1H-tetrazol-5-yl)methyl)-2-(4-fluorobenzylthio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-4(5H)-one 1417527-01-5 C16H15FN6OS
    1-((1H-tetrazol-5-yl)methyl)-2-(4-fluorobenzylthio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-4(5H)-one
    —— 4-(Methylthio)phenylcarbothioic acid hydrazide 109684-10-8 C8H10N2S2
    4-(Methylthio)phenylcarbothioic acid hydrazide
    —— 2-cyclobutyl-2-hydroxymethyl propan-1,3-dithiol 131506-03-1 C8H16OS2
    2-cyclobutyl-2-hydroxymethyl propan-1,3-dithiol
    —— tert-butyl N-[5-(6-chloro-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-yl]-N-propan-2-ylcarbamate 905300-52-9 C16H21ClN4O2S2
    tert-butyl N-[5-(6-chloro-2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-yl]-N-propan-2-ylcarbamate
    —— 2-[(phenylsulfanyl)methyl]dodecanal 808137-56-6 C19H30OS
    2-[(phenylsulfanyl)methyl]dodecanal
    —— 3,7-dimethyl-6-phenylthio-1,7-octadien-3-ol 259210-13-4 C16H22OS
    3,7-dimethyl-6-phenylthio-1,7-octadien-3-ol
    —— allyl-hexadecyl-sulfide 137138-70-6 C19H38S
    allyl-hexadecyl-sulfide
    —— (4S)-4-benzyl-3-[(2S)-2-phenylsulfanylbutanoyl]-1,3-oxazolidin-2-one 156546-60-0 C20H21NO3S
    (4S)-4-benzyl-3-[(2S)-2-phenylsulfanylbutanoyl]-1,3-oxazolidin-2-one
    —— (4-(but-3-enyl)phenyl)(methyl)sulfane 59209-69-7 C11H14S
    (4-(but-3-enyl)phenyl)(methyl)sulfane
    —— 2-benzylthio-3-(5,6-dihydro-[1,4,2]-dioxazin-3-yl)-pyridine 163349-67-5 C15H14N2O2S
    2-benzylthio-3-(5,6-dihydro-[1,4,2]-dioxazin-3-yl)-pyridine
    —— 2-acetylamino-5-(pyridin-2-ylthio)thiazole 133691-58-4 C10H9N3OS2
    2-acetylamino-5-(pyridin-2-ylthio)thiazole
    —— 3-cyano-5-phenylthio[2,1]benzisoxazole 194873-13-7 C14H8N2OS
    3-cyano-5-phenylthio[2,1]benzisoxazole
    —— (1-methylpyrrolidin-2-ylidene)[2-nitro-5-(phenylthio)phenyl]acetonitrile 1259405-88-3 C19H17N3O2S
    (1-methylpyrrolidin-2-ylidene)[2-nitro-5-(phenylthio)phenyl]acetonitrile
    —— 5-nitro-4-(phenylthio)spiro<2H-benzimidazole-2,1'-cyclohexane> 130256-93-8 C18H17N3O2S
    5-nitro-4-(phenylthio)spiro<2H-benzimidazole-2,1'-cyclohexane>
    —— (2-Nitro-5-(phenylthio)phenyl)acetonitrile 72301-69-0 C14H10N2O2S
    (2-Nitro-5-(phenylthio)phenyl)acetonitrile
    —— 2,3-dihydro-5-nitro-4-(phenylthio)spiro<1H-benzimidazole-2,1'-cyclohexane> 130256-92-7 C18H19N3O2S
    2,3-dihydro-5-nitro-4-(phenylthio)spiro<1H-benzimidazole-2,1'-cyclohexane>
    —— p-tolyl(phenylthio)sulfine 64874-44-8 C14H12OS2
    p-tolyl(phenylthio)sulfine
    —— 2,2-Bis(ethylsulfanyl)pentanedinitrile 89450-22-6 C9H14N2S2
    2,2-Bis(ethylsulfanyl)pentanedinitrile