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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (S)-tert-butyl 1-amino-3-cyclopropyl-1-thioxopropan-2-ylcarbamate 1415898-82-6 C11H20N2O2S
    (S)-tert-butyl 1-amino-3-cyclopropyl-1-thioxopropan-2-ylcarbamate
    —— (3R,4R,5R)-4-[(1S)-1,2-dihydroxyethyl]-3-methyl-3-phenylsulfanyl-5-tridecyloxolan-2-one 180267-06-5 C26H42O4S
    (3R,4R,5R)-4-[(1S)-1,2-dihydroxyethyl]-3-methyl-3-phenylsulfanyl-5-tridecyloxolan-2-one
    —— 1,3-dimethyl-6-(2-aminophenylthio)uracil 62925-51-3 C12H13N3O2S
    1,3-dimethyl-6-(2-aminophenylthio)uracil
    —— Aldicarb-aldicarb sulfone mixt. 106541-75-7 C14H28N4O6S2
    Aldicarb-aldicarb sulfone mixt.
    —— trans-8-Methylmercapto-trideca-1,7-dien-3,5,9,11-tetrain 5142-14-3 C14H10S
    trans-8-Methylmercapto-trideca-1,7-dien-3,5,9,11-tetrain
    —— (E)-8-methylsulfanyl-trideca-1,7-diene-3,5,9,11-tetrayne 4803-51-4 C14H10S
    (E)-8-methylsulfanyl-trideca-1,7-diene-3,5,9,11-tetrayne
    —— 3-(Phenylthio)bicyclobutanecarbonitrile 91003-31-5 C11H9NS
    3-(Phenylthio)bicyclobutanecarbonitrile
    —— 5-methyl-7-methylmercapto-3-phenylthiazolo<4,5-d>pyrimidin-2(3H)-thione 141622-19-7 C13H11N3S3
    5-methyl-7-methylmercapto-3-phenylthiazolo<4,5-d>pyrimidin-2(3H)-thione
    —— Phosphonothioic acid, methyl-, O-ethyl S-(2-(pentylsulfinyl)ethyl) ester 53151-71-6 C10H23O3PS2
    Phosphonothioic acid, methyl-, O-ethyl S-(2-(pentylsulfinyl)ethyl) ester
    —— cis-Propenyl-propyl-disulfid 23838-20-2 C6H12S2
    cis-Propenyl-propyl-disulfid
    —— (Z)‐1‐(prop‐2‐enyldisulfanyl)prop‐1‐en 122156-02-9 C6H10S2
    (Z)‐1‐(prop‐2‐enyldisulfanyl)prop‐1‐en
    —— S-2-(2-aminoethylamino)ethyl 4-tolyl sulfide 115335-17-6 C11H18N2S
    S-2-(2-aminoethylamino)ethyl 4-tolyl sulfide
    —— S-methyl (Z)-2,2,2-trifluoro-N-(methylcarbamoyloxy)thioacetimidate 82985-96-4 C5H7F3N2O2S
    S-methyl (Z)-2,2,2-trifluoro-N-(methylcarbamoyloxy)thioacetimidate
    —— [3-(1,2-dimethyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid 1359979-72-8 C18H17NO2S
    [3-(1,2-dimethyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid
    —— (E)-1-[2-(4-methylsulfanylphenyl)cyclopenten-1-yl]-N-phenylmethoxyethanimine 488759-35-9 C21H23NOS
    (E)-1-[2-(4-methylsulfanylphenyl)cyclopenten-1-yl]-N-phenylmethoxyethanimine
    —— 2-(2,4-difluorophenylthio)-5-(pyrazin-2-yl)1,3,4-thiadiazole 1404052-59-0 C13H8F2N4S2
    2-(2,4-difluorophenylthio)-5-(pyrazin-2-yl)1,3,4-thiadiazole
    —— 6-[(2,4-difluorophenyl)methoxy]-3-cyclopropyl-2-methylthio-3-hydropyrimidin-4-one 883996-39-2 C15H14F2N2O2S
    6-[(2,4-difluorophenyl)methoxy]-3-cyclopropyl-2-methylthio-3-hydropyrimidin-4-one
    —— 6-[(2,4-difluorophenyl)methoxy]-3-(2-methylpropyl)-2-methylthio-3-hydropyrimidin-4-one 883997-06-6 C16H18F2N2O2S
    6-[(2,4-difluorophenyl)methoxy]-3-(2-methylpropyl)-2-methylthio-3-hydropyrimidin-4-one
    —— (Z)-phenyl N-hydroxy-2-oxobutanimidothioate 110097-28-4 C10H11NO2S
    (Z)-phenyl N-hydroxy-2-oxobutanimidothioate
    —— [3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid ethyl ester 1359980-44-1 C19H18ClNO2S
    [3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid ethyl ester
    —— ethyl 2-(3-(ethylthio)phenyl)acetate 1363179-51-4 C12H16O2S
    ethyl 2-(3-(ethylthio)phenyl)acetate
    —— [3-(6-fluoro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid 1359979-70-6 C17H14FNO2S
    [3-(6-fluoro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid
    —— 4-methylsulfanyl-1-phenylpyrimidine-2(1H)-one 872492-86-9 C11H10N2OS
    4-methylsulfanyl-1-phenylpyrimidine-2(1H)-one
    —— [3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid 1359979-74-0 C17H14ClNO2S
    [3-(6-chloro-2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid
    —— [3-(2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid 1359979-68-2 C17H15NO2S
    [3-(2-methyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid
    —— [3-(6-chloro-1,2-dimethyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid 1359979-73-9 C18H16ClNO2S
    [3-(6-chloro-1,2-dimethyl-1H-indol-3-ylsulfanyl)-phenyl]-acetic acid
    —— 4-methylsulfanyl-1-phenylpyrimidine-2(1H)-thione 872492-84-7 C11H10N2S2
    4-methylsulfanyl-1-phenylpyrimidine-2(1H)-thione
    —— 3-(benzyloxymethyl)-1-[(Z)-2,3-di-O-(tert-butyldimethylsilyl)-4,5-dehydro-5-phenylthio-β-D-ribopentofuranosyl]uracil 1354938-99-0 C35H50N2O6SSi2
    3-(benzyloxymethyl)-1-[(Z)-2,3-di-O-(tert-butyldimethylsilyl)-4,5-dehydro-5-phenylthio-β-D-ribopentofuranosyl]uracil
    —— 2-Methyl-m-dithiane-2-carboxaldehyde O-(methylcarbamoyl)oxime 26419-72-7 C8H14N2O2S2
    2-Methyl-m-dithiane-2-carboxaldehyde O-(methylcarbamoyl)oxime
    —— [1,1,1,5,5,5-Hexafluoro-2,4-bis(trifluoromethyl)pent-2-en-3-yl]sulfanylbenzene 38091-65-5 C13H6F12S
    [1,1,1,5,5,5-Hexafluoro-2,4-bis(trifluoromethyl)pent-2-en-3-yl]sulfanylbenzene
    —— 3-ethylsulfanyl-1,1,1,5,5,5-hexafluoro-2,4-bis-trifluoromethyl-pent-2-ene 38091-64-4 C9H6F12S
    3-ethylsulfanyl-1,1,1,5,5,5-hexafluoro-2,4-bis-trifluoromethyl-pent-2-ene
    —— 2-(Morpholinoimino)-4'-(phenylthio)acetophenone 25561-45-9 C18H18N2O2S
    2-(Morpholinoimino)-4'-(phenylthio)acetophenone
    —— (2-bromoethyl)(5-(difluoromethyl)selenophen-2-yl)sulfane 1297906-71-8 C7H7BrF2SSe
    (2-bromoethyl)(5-(difluoromethyl)selenophen-2-yl)sulfane
    —— diisopropyl 2-(2-bromoethylthio)thiophen-3-ylphosphonate 1297906-74-1 C12H20BrO3PS2
    diisopropyl 2-(2-bromoethylthio)thiophen-3-ylphosphonate
    —— α-phenylsulfanyl-isobutyric acid amide 857809-74-6 C10H13NOS
    α-phenylsulfanyl-isobutyric acid amide
    —— 2-(2-bromoethylthio)furan 1297906-67-2 C6H7BrOS
    2-(2-bromoethylthio)furan
    —— 5-(2-bromoethylthio)selenophene-2-carbonitrile 1297906-72-9 C7H6BrNSSe
    5-(2-bromoethylthio)selenophene-2-carbonitrile
    —— 2-chloroethyl cycloheptyl sulfide 333782-91-5 C9H17ClS
    2-chloroethyl cycloheptyl sulfide
    —— 2-(3-fluorophenylthio)ethyl chloride 333782-56-2 C8H8ClFS
    2-(3-fluorophenylthio)ethyl chloride
    —— N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylethanesulfonamide —— C16H17NO2S2
    N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylethanesulfonamide
    —— 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane 884844-91-1 C20H12BF21O2S
    2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane
    —— 1,3-Dithiolane-2-carboxaldehyde, 2-methyl-, O-((methylamino)carbonyl)oxime 26419-69-2 C7H12N2O2S2
    1,3-Dithiolane-2-carboxaldehyde, 2-methyl-, O-((methylamino)carbonyl)oxime
    —— 2-Methyl-2-(methylthio)propanal O-((dibutylaminosulfenyl)(methyl)carbamoyl)oxime 69784-43-6 C15H31N3O2S2
    2-Methyl-2-(methylthio)propanal O-((dibutylaminosulfenyl)(methyl)carbamoyl)oxime
    —— 2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid 1-methylethyl ester 65907-51-9 C10H19N3O4S2
    2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid 1-methylethyl ester
    —— 5-chloro-1-methyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone 107363-58-6 C8H8ClN3OS
    5-chloro-1-methyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone
    —— 5-chloro-1-phenyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone 107363-59-7 C13H10ClN3OS
    5-chloro-1-phenyl-3-(2-cyanoethylthio)-2(1H)-pyrazinone
    —— allyl vinyl sulfide 41049-25-6 C5H8S
    allyl vinyl sulfide
    —— 2-Ethyl-4,8-dimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid hexyl ester 65907-53-1 C14H27N3O4S2
    2-Ethyl-4,8-dimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid hexyl ester
    —— 2,4,9,9-Tetramethyl-5-oxo-6-oxa-3,10-dithia-2,4,7-triazaundec-7-enoic acid decyl ester 65907-43-9 C19H37N3O4S2
    2,4,9,9-Tetramethyl-5-oxo-6-oxa-3,10-dithia-2,4,7-triazaundec-7-enoic acid decyl ester
    —— 2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid propyl ester 65907-50-8 C10H19N3O4S2
    2,4,8-Trimethyl-5-oxo-6-oxa-3,9-dithia-2,4,7-triazadec-7-enoic acid propyl ester