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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Gwaflwpevdxomo-uhfffaoysa- 264908-59-0 C20H11F6NO3S
    Gwaflwpevdxomo-uhfffaoysa-
    —— Vgmwkhiedkxrid-uhfffaoysa- 264908-62-5 C19H8ClF6NO2S
    Vgmwkhiedkxrid-uhfffaoysa-
    —— Xujqylxmijeuba-uhfffaoysa- 264908-61-4 C19H9F6NO2S
    Xujqylxmijeuba-uhfffaoysa-
    —— 2-(4-methoxyphenylthio)thiazole 1335609-17-0 C10H9NOS2
    2-(4-methoxyphenylthio)thiazole
    —— 5-(2-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 237401-51-3 C10H7NS5
    5-(2-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— Ethyl-dimethyl-thionocarbamat 41185-28-8 C6H13NOS
    Ethyl-dimethyl-thionocarbamat
    —— 2,4-Dichloro-N-{4-chloro-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide 882500-02-9 C21H19Cl3N4O4S3
    2,4-Dichloro-N-{4-chloro-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide
    —— N-butan-2-yl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-44-7 C11H13N3O4S2
    N-butan-2-yl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— 2-({[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfanyl)-1,3-oxazole 1191104-19-4 C10H8F5N3O2S
    2-({[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfanyl)-1,3-oxazole
    —— 4,4-bis(ethylthio)-2,6-dimethyl-1,3-cyclohexanedione 112473-10-6 C12H20O2S2
    4,4-bis(ethylthio)-2,6-dimethyl-1,3-cyclohexanedione
    —— N-benzyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-48-1 C14H11N3O4S2
    N-benzyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— 2-(4-benzyloxy-phenylsulfanyl)-5-nitro-phenylamine 944503-16-6 C19H16N2O3S
    2-(4-benzyloxy-phenylsulfanyl)-5-nitro-phenylamine
    —— 4-(4-benzyloxy-phenylsulfanyl)-N3-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-benzene-1,3-diamine 944503-18-8 C27H23N5OS
    4-(4-benzyloxy-phenylsulfanyl)-N3-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-benzene-1,3-diamine
    —— [2-(4-benzyloxy-phenylsulfanyl)-5-nitro-phenyl]-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine 944503-17-7 C27H21N5O3S
    [2-(4-benzyloxy-phenylsulfanyl)-5-nitro-phenyl]-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine
    —— 7-nitro-1,1-dioxo-N-(1-phenylethyl)-1lambda6,4,2-benzodithiazin-3-imine 1429321-49-2 C15H13N3O4S2
    7-nitro-1,1-dioxo-N-(1-phenylethyl)-1lambda6,4,2-benzodithiazin-3-imine
    —— N-cyclopropyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-43-6 C10H9N3O4S2
    N-cyclopropyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— N-(cyclopropylmethyl)-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-46-9 C11H11N3O4S2
    N-(cyclopropylmethyl)-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— N-ethyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-42-5 C9H9N3O4S2
    N-ethyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— N-cyclopentyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-47-0 C12H13N3O4S2
    N-cyclopentyl-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— N-(2-methylpropyl)-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine 1429321-45-8 C11H13N3O4S2
    N-(2-methylpropyl)-7-nitro-1,1-dioxo-1lambda6,4,2-benzodithiazin-3-imine
    —— N-(2-phenylethyl)-N-[(E)-phenylsulfanylmethyldiazenyl]acetamide 84304-09-6 C17H19N3OS
    N-(2-phenylethyl)-N-[(E)-phenylsulfanylmethyldiazenyl]acetamide
    —— 2-(4-chlorophenylthio)-5-nitrobenzenesulfonamide 95175-11-4 C12H9ClN2O4S2
    2-(4-chlorophenylthio)-5-nitrobenzenesulfonamide
    —— 2-ethyl-2-(phenylthio)butanenitrile 93338-72-8 C12H15NS
    2-ethyl-2-(phenylthio)butanenitrile
    —— (5-chloromethyl-2-methylsulfanyl-pyrimidin-4-yl)-methyl-amine hydrochloride 878738-91-1 C7H10ClN3S*ClH
    (5-chloromethyl-2-methylsulfanyl-pyrimidin-4-yl)-methyl-amine hydrochloride
    —— 1-(1-(benzo[b]thiophen-2-yl)cyclohexyl)-4-((1-(2,6-bis(phenylthio)phenyl)-1H-1,2,3-triazol-4-yl)methyl)piperazine 1271825-62-7 C39H39N5S3
    1-(1-(benzo[b]thiophen-2-yl)cyclohexyl)-4-((1-(2,6-bis(phenylthio)phenyl)-1H-1,2,3-triazol-4-yl)methyl)piperazine
    —— 3-(phenylthio)-2-pentene 71253-57-1 C11H14S
    3-(phenylthio)-2-pentene
    —— 2-<2-(Phenylthio)ethyl>cyclohexanone 151830-52-3 C14H18OS
    2-<2-(Phenylthio)ethyl>cyclohexanone
    —— Imino-[(2-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)imino]azanium 51108-42-0 C4H7N6S+
    Imino-[(2-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)imino]azanium
    —— methyl (3S)-3-hydroxy-3-methyl-4-phenylsulfanylbutanoate 350604-71-6 C12H16O3S
    methyl (3S)-3-hydroxy-3-methyl-4-phenylsulfanylbutanoate
    —— methyl 2-methyl-2-[(pyridin-2-yl)sulfanyl]propionate 1152091-93-4 C10H13NO2S
    methyl 2-methyl-2-[(pyridin-2-yl)sulfanyl]propionate
    —— 2,2-Dimethyl-13-methylsulfon-tridecannitril 93153-24-3 C16H31NO2S
    2,2-Dimethyl-13-methylsulfon-tridecannitril
    —— 3-Phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl 3-(trifluoromethyl)phenyl sulfide 4708-91-2 C17H9F6N3S
    3-Phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl 3-(trifluoromethyl)phenyl sulfide
    —— 13,13,13-trifluorotridecanethiol 200501-45-7 C13H25F3S
    13,13,13-trifluorotridecanethiol
    —— Methyl 3,3-Dimethyl-4-(phenylthio)-5-hexenoate 143706-93-8 C15H20O2S
    Methyl 3,3-Dimethyl-4-(phenylthio)-5-hexenoate
    —— 3-Amino-4-(benzylthio)-6-methylpyridazine 82608-19-3 C12H13N3S
    3-Amino-4-(benzylthio)-6-methylpyridazine
    —— 2-[[5-[[(2-fluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol 333743-74-1 C16H17FN4O2S2
    2-[[5-[[(2-fluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol
    —— 2-[[2-bromo-5-[[(2-fluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol 333743-73-0 C15H14BrFN4OS2
    2-[[2-bromo-5-[[(2-fluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol
    —— 2-[[2-amino-5-[[(2-fluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol 333743-72-9 C15H16FN5OS2
    2-[[2-amino-5-[[(2-fluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol
    —— Methyl 3-methyl-3-(phenylsulfanyl)butanoate 64793-82-4 C12H16O2S
    Methyl 3-methyl-3-(phenylsulfanyl)butanoate
    —— di(1-adamantyl) thioketone 73509-04-3 C21H30S
    di(1-adamantyl) thioketone
    —— 2-phenylthio-5-methylpyridine 19541-52-7 C12H11NS
    2-phenylthio-5-methylpyridine
    —— 1,1-dichloro-3-phenylthio-2-propanone 155106-07-3 C9H8Cl2OS
    1,1-dichloro-3-phenylthio-2-propanone
    —— 5-methyl-2-(propylthio)pyridine 5613-18-3 C9H13NS
    5-methyl-2-(propylthio)pyridine
    —— 2-methoxy-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide 1380333-89-0 C24H23N5O3S
    2-methoxy-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide
    —— 4-Oxo-5,6-dihydrothieno[2,3-b]thiopyran-2-sulfonyl chloride 106319-48-6 C7H5ClO3S3
    4-Oxo-5,6-dihydrothieno[2,3-b]thiopyran-2-sulfonyl chloride
    —— 5,6-dihydro-4H-4-hydroxythieno[2,3-b]thiopyran-2-sulfonamide 105951-34-6 C7H9NO3S3
    5,6-dihydro-4H-4-hydroxythieno[2,3-b]thiopyran-2-sulfonamide
    —— 2H-thieno<2,3-b>thiopyran 21339-38-8 C7H6S2
    2H-thieno<2,3-b>thiopyran
    —— tert-butyl-diphenyl-[(2R,3S)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]-2,3-bis(trimethylsilyloxy)butoxy]silane 360580-61-6 C35H52O4SSi3
    tert-butyl-diphenyl-[(2R,3S)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]-2,3-bis(trimethylsilyloxy)butoxy]silane
    —— dimethyl-1,2-propadien-1-yl sulfonium bromide 25308-81-0 Br*C5H9S
    dimethyl-1,2-propadien-1-yl sulfonium bromide
    —— 4,5-bis(phenylthio)-1,3-dithiole-2-thione 120397-77-5 C15H10S5
    4,5-bis(phenylthio)-1,3-dithiole-2-thione