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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1Z)-2-[[4-amino-6-[(4-chlorophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate 1105064-89-8 C20H15ClN6O4S
    (1Z)-2-[[4-amino-6-[(4-chlorophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate
    —— (1E)-2-[[4-amino-6-[(4-chlorophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate 1105064-94-5 C21H17ClN6O4S
    (1E)-2-[[4-amino-6-[(4-chlorophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate
    —— (1E)-2-[(4-amino-6-benzyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate 1105064-87-6 C20H16N6O4S
    (1E)-2-[(4-amino-6-benzyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate
    —— (1Z)-2-[[4-amino-6-[(4-bromophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate 1105064-88-7 C20H15BrN6O4S
    (1Z)-2-[[4-amino-6-[(4-bromophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-(5-oxo-3-phenyloxadiazol-3-ium-4-ylidene)ethanolate
    —— (1Z)-2-[(4-amino-6-benzyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate 1105064-92-3 C21H18N6O4S
    (1Z)-2-[(4-amino-6-benzyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate
    —— (1E)-2-[[4-amino-6-[(4-bromophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate 1105064-93-4 C21H17BrN6O4S
    (1E)-2-[[4-amino-6-[(4-bromophenyl)methyl]-5-oxo-1,2,4-triazin-3-yl]sulfanyl]-1-[3-(4-methylphenyl)-5-oxooxadiazol-3-ium-4-ylidene]ethanolate
    —— (S)-5-(2-(3-bromophenyl)-2-(phenylthio)ethyl)-3-methyl-4-nitroisoxazole 1334145-71-9 C18H15BrN2O3S
    (S)-5-(2-(3-bromophenyl)-2-(phenylthio)ethyl)-3-methyl-4-nitroisoxazole
    —— 5-Bromo-2-(cyclopentylsulfanyl)pyrimidine 1330750-21-4 C9H11BrN2S
    5-Bromo-2-(cyclopentylsulfanyl)pyrimidine
    —— 2-(Propan-2-ylsulfanyl)ethan-1-amine hydrochloride 927-69-5 C5H14ClNS
    2-(Propan-2-ylsulfanyl)ethan-1-amine hydrochloride
    —— 2,4-Dibromo-5-fluorothioanisole 1314987-31-9 C7H5Br2FS
    2,4-Dibromo-5-fluorothioanisole
    —— 1H-Tetrazole, 5-[[(2-chloro-6-fluorophenyl)methyl]thio]-1-(2-propen-1-yl)- 1389070-00-1 C11H10ClFN4S
    1H-Tetrazole, 5-[[(2-chloro-6-fluorophenyl)methyl]thio]-1-(2-propen-1-yl)-
    —— 13,30,45-Trimethyl-16,42-dithia-2,10,14,27,31,44,47,49-octazatetracyclo[41.3.1.111,15.127,31]nonatetraconta-1(47),11(49),12,14,29,43,45-heptaene-28,48-dione 1336915-74-2 C42H68N8O2S2
    13,30,45-Trimethyl-16,42-dithia-2,10,14,27,31,44,47,49-octazatetracyclo[41.3.1.111,15.127,31]nonatetraconta-1(47),11(49),12,14,29,43,45-heptaene-28,48-dione
    —— 2-[[(4,6-Diamino-2-pyrimidinyl)thio]methyl]-5-hydroxy-4H-pyran-4-one 138426-87-6 C10H10N4O3S
    2-[[(4,6-Diamino-2-pyrimidinyl)thio]methyl]-5-hydroxy-4H-pyran-4-one
    —— 1-Bromo-3-[(4-chlorophenyl)sulfanylmethyl]benzene 1443304-53-7 C13H10BrClS
    1-Bromo-3-[(4-chlorophenyl)sulfanylmethyl]benzene
    —— 3,3-Dimethyl-1-[(trimethylpyrimidin-2-yl)sulfanyl]butan-2-one 1469164-08-6 C13H20N2OS
    3,3-Dimethyl-1-[(trimethylpyrimidin-2-yl)sulfanyl]butan-2-one
    —— 2-(1,3,4-Thiadiazol-2-ylthio)propanamide 893746-13-9 C5H7N3OS2
    2-(1,3,4-Thiadiazol-2-ylthio)propanamide
    —— 2-Chloro-6-[(4-methoxyphenyl)sulfanyl]benzoic acid 62326-40-3 C14H11ClO3S
    2-Chloro-6-[(4-methoxyphenyl)sulfanyl]benzoic acid
    —— N-[2-(Phenylthio)ethyl]-2-pyrazinamine 1179020-40-6 C12H13N3S
    N-[2-(Phenylthio)ethyl]-2-pyrazinamine
    —— 2,4-Dimethyl-5-cyano-6-phenylthiopyridin 92149-92-3 C14H12N2S
    2,4-Dimethyl-5-cyano-6-phenylthiopyridin
    —— Propanamide, 2-methyl-N-[2-(phenylthio)ethyl]- 1378306-71-8 C12H17NOS
    Propanamide, 2-methyl-N-[2-(phenylthio)ethyl]-
    —— 2-[(4-Bromophenyl)thio]-N-(2-ethoxyethyl)ethanamine 1249068-67-4 C12H18BrNOS
    2-[(4-Bromophenyl)thio]-N-(2-ethoxyethyl)ethanamine
    —— Ethyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate 919799-85-2 C7H11N3O2S2
    Ethyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate
    —— 3-[(4,6-Diamino-2-pyrimidinyl)thio]-2-methylpropanenitrile 1247690-45-4 C8H11N5S
    3-[(4,6-Diamino-2-pyrimidinyl)thio]-2-methylpropanenitrile
    —— N-[2-[(4-Methylphenyl)thio]ethyl]-1-propanamine 67747-27-7 C12H19NS
    N-[2-[(4-Methylphenyl)thio]ethyl]-1-propanamine
    —— N1,N1,2,2-Tetramethyl-N3-[2-(methylsulfonyl)ethyl]-1,3-propanediamine 1179738-25-0 C10H24N2O2S
    N1,N1,2,2-Tetramethyl-N3-[2-(methylsulfonyl)ethyl]-1,3-propanediamine
    —— 3-[[2-[Ethyl(2-hydroxyethyl)amino]ethyl]sulfonyl]propanamide 1248751-81-6 C9H20N2O4S
    3-[[2-[Ethyl(2-hydroxyethyl)amino]ethyl]sulfonyl]propanamide
    —— 5-nitro-2-(p-tolylthio)aniline 91955-35-0 C13H12N2O2S
    5-nitro-2-(p-tolylthio)aniline
    —— 2-{[(6-Chloropyridin-3-yl)methyl]sulfanyl}-4,6-dimethylpyrimidine 821782-42-7 C12H12ClN3S
    2-{[(6-Chloropyridin-3-yl)methyl]sulfanyl}-4,6-dimethylpyrimidine
    —— Methyl 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate 646534-24-9 C7H11N3O2S
    Methyl 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— 2-[(5-Amino-4-methyl-4H-1,2,4-triazol-3-yl)thio]-N-(2-cyanoethyl)acetamide 1247164-67-5 C8H12N6OS
    2-[(5-Amino-4-methyl-4H-1,2,4-triazol-3-yl)thio]-N-(2-cyanoethyl)acetamide
    —— 2-[(2,3-Dihydro-1H-inden-5-yl)thio]-6-fluorobenzenamine 1183210-57-2 C15H14FNS
    2-[(2,3-Dihydro-1H-inden-5-yl)thio]-6-fluorobenzenamine
    —— N-[2-[(4-Fluorophenyl)thio]ethyl]-N-propyl-4-piperidinamine 1178384-66-1 C16H25FN2S
    N-[2-[(4-Fluorophenyl)thio]ethyl]-N-propyl-4-piperidinamine
    —— 2-((4-(tert-butyl)phenyl)thio)benzaldehyde 643763-18-2 C17H18OS
    2-((4-(tert-butyl)phenyl)thio)benzaldehyde
    —— 3-Fluoro-4-(2-methylphenyl)sulfanylbenzaldehyde 1275209-65-8 C14H11FOS
    3-Fluoro-4-(2-methylphenyl)sulfanylbenzaldehyde
    —— Methyl-o-(p-tolylthio)phenylcarbinol 52252-64-9 C15H16OS
    Methyl-o-(p-tolylthio)phenylcarbinol
    —— 5-Chloro-2-(methylthio)pyridin-3-amine 886373-90-6 C6H7ClN2S
    5-Chloro-2-(methylthio)pyridin-3-amine
    —— 3-Fluoro-I+/--[[[3-(methylthio)phenyl]amino]methyl]benzenemethanol 1184806-52-7 C15H16FNOS
    3-Fluoro-I+/--[[[3-(methylthio)phenyl]amino]methyl]benzenemethanol
    —— 2-(6-(Methylthio)pyrimidin-4-yl)acetic acid 1314969-30-6 C7H8N2O2S
    2-(6-(Methylthio)pyrimidin-4-yl)acetic acid
    —— 4-Ethyl-I+/--methyl-5-(methylthio)-4H-1,2,4-triazole-3-methanamine 1092279-04-3 C7H14N4S
    4-Ethyl-I+/--methyl-5-(methylthio)-4H-1,2,4-triazole-3-methanamine
    —— Carbamimidothioic acid, oxiranylmethyl ester 792858-10-7 C4H8N2OS
    Carbamimidothioic acid, oxiranylmethyl ester
    —— 3-Fluoro-5-methylphenyl methyl sulfide 1314902-71-0 C8H9FS
    3-Fluoro-5-methylphenyl methyl sulfide
    —— 2-Methyl-5-methylmercapto-4-hydroxypyrimidin 66699-20-5 C6H8N2OS
    2-Methyl-5-methylmercapto-4-hydroxypyrimidin
    —— l-Isoleucine thioamide hydrochloride 111013-76-4 C6H15ClN2S
    l-Isoleucine thioamide hydrochloride
    —— 1H-Pyrazole-4-carboxylic acid, 3-amino-5-(methylthio)-, hydrazide 1346270-10-7 C5H9N5OS
    1H-Pyrazole-4-carboxylic acid, 3-amino-5-(methylthio)-, hydrazide
    —— 3-(Phenylthio)oxetane 1207175-19-6 C9H10OS
    3-(Phenylthio)oxetane
    —— 5-Methylmercapto-1.3.4-thiadiazolyl-hydrazin 88982-34-7 C3H6N4S2
    5-Methylmercapto-1.3.4-thiadiazolyl-hydrazin
    —— (6-Methylsulfanylpyridin-3-yl)hydrazine 1314927-45-1 C6H9N3S
    (6-Methylsulfanylpyridin-3-yl)hydrazine
    —— N-Isopropyl-thioformamid-S-oxid 19841-20-4 C4H9NOS
    N-Isopropyl-thioformamid-S-oxid
    —— 6-hydroxyhexanethioamide 943994-90-9 C6H13NOS
    6-hydroxyhexanethioamide
    —— (2R)-1-methylsulfonylpropan-2-amine 1032451-77-6 C4H11NO2S
    (2R)-1-methylsulfonylpropan-2-amine