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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Methyl-3-cyano-2-allylthiopyridine 112629-70-6 C10H10N2S
    6-Methyl-3-cyano-2-allylthiopyridine
    —— N'-cyano-2-(3-cyano-6-methylpyridin-2-yl)sulfanylethanimidamide 159717-90-5 C10H9N5S
    N'-cyano-2-(3-cyano-6-methylpyridin-2-yl)sulfanylethanimidamide
    —— 1-Phenyl-2-<(phenylthio)methyl>-1-propen 79597-56-1 C16H16S
    1-Phenyl-2-<(phenylthio)methyl>-1-propen
    —— ethyl 5-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-hexenoate 134427-77-3 C16H19F3O2S
    ethyl 5-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-hexenoate
    —— <4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane 103559-10-0 C17H21ClSSi
    <4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane
    —— 3,4-Bis(trifluormethylthio)pyrazol 114861-77-7 C5H2F6N2S2
    3,4-Bis(trifluormethylthio)pyrazol
    —— (1Z,3R)-3-tert-butyldimethylsilyloxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene 228716-85-6 C22H29NO3SSi
    (1Z,3R)-3-tert-butyldimethylsilyloxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene
    —— (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-91-4 C22H29NO4SSi
    (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— 7-chloro-2,3-dihydro-5H-thiazolo[3,2-a]pyrimidin-5-one 72211-60-0 C6H5ClN2OS
    7-chloro-2,3-dihydro-5H-thiazolo[3,2-a]pyrimidin-5-one
    —— 7-morpholin-4-yl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 32090-53-2 C10H13N3O2S
    7-morpholin-4-yl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— 5,7-dioxo-3,5,6,7-tetrahydro-2H-thiazolo<3,2-c>pyrimidine-8-carbaldehyde 161094-28-6 C7H6N2O3S
    5,7-dioxo-3,5,6,7-tetrahydro-2H-thiazolo<3,2-c>pyrimidine-8-carbaldehyde
    —— 7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 72211-62-2 C7H8N2O4S2
    7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— 6-(2-Methylpropyl)-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidine-5,7-dione 149221-47-6 C10H14N2O2S
    6-(2-Methylpropyl)-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidine-5,7-dione
    —— 2<(4-chlorophenylthio)methyl>furan 5380-97-2 C11H9ClOS
    2<(4-chlorophenylthio)methyl>furan
    —— 1-Methyl-3,4-bis(trifluormethylthio)pyrazol 114861-78-8 C6H4F6N2S2
    1-Methyl-3,4-bis(trifluormethylthio)pyrazol
    —— 3-[Dimethyl-(1-phenylsulfanylcyclopropyl)silyl]-3-phenylpropan-1-ol 166672-30-6 C20H26OSSi
    3-[Dimethyl-(1-phenylsulfanylcyclopropyl)silyl]-3-phenylpropan-1-ol
    —— Ethyl 2-[4-cyano-5,6-bis(furan-2-yl)pyridazin-3-yl]sulfanylacetate 158014-42-7 C17H13N3O4S
    Ethyl 2-[4-cyano-5,6-bis(furan-2-yl)pyridazin-3-yl]sulfanylacetate
    —— methyl 3-(2-hydroxyphenylsulfanyl)propanoate 938435-58-6 C10H12O3S
    methyl 3-(2-hydroxyphenylsulfanyl)propanoate
    —— 2-Ethoxycarbonylmethylthio-6-methyl-4-(2-thienyl)-pyridin-3-carbonitril 127144-11-0 C15H14N2O2S2
    2-Ethoxycarbonylmethylthio-6-methyl-4-(2-thienyl)-pyridin-3-carbonitril
    —— 1-Methyl-4,5-bis(trifluormethylthio)pyrazol 114861-79-9 C6H4F6N2S2
    1-Methyl-4,5-bis(trifluormethylthio)pyrazol
    —— 2-Phenyl-5-pyrrolidino-3,4-bis(trifluormethylthio)furan 114861-81-3 C16H13F6NOS2
    2-Phenyl-5-pyrrolidino-3,4-bis(trifluormethylthio)furan
    —— 2-(pentafluorosulfanyl)acetaldehyde 762-57-2 C2H3F5OS
    2-(pentafluorosulfanyl)acetaldehyde
    —— 1,3-Dioxolane-2-thione, 4-(2-hydroxyethyl)- 189280-29-3 C5H8O3S
    1,3-Dioxolane-2-thione, 4-(2-hydroxyethyl)-
    —— 3,4,4-tris-methylsulfanyl-butan-2-one 7714-01-4 C7H14OS3
    3,4,4-tris-methylsulfanyl-butan-2-one
    —— (2S)-1-[2-[[2-(hydroxymethyl)-1,3-dithian-2-yl]methyl]-1,3-dithian-2-yl]propan-2-ol 175030-54-3 C13H24O2S4
    (2S)-1-[2-[[2-(hydroxymethyl)-1,3-dithian-2-yl]methyl]-1,3-dithian-2-yl]propan-2-ol
    —— 4-thioxo-3,4,7,8-tetrahydro-6<i>H</i>-[1,3]thiazino[3,2-<i>a</i>][1,3,5]triazin-2-one 51270-95-2 C6H7N3OS2
    4-thioxo-3,4,7,8-tetrahydro-6<i>H</i>-[1,3]thiazino[3,2-<i>a</i>][1,3,5]triazin-2-one
    —— methylene-2-(1,3-dithianyl)-2'-(1,3-dithianyl-2-hydroxymethyl) 62888-30-6 C10H18OS4
    methylene-2-(1,3-dithianyl)-2'-(1,3-dithianyl-2-hydroxymethyl)
    —— 2,2'-methylenebis(1,3-dithianyl-2-hydroxymethyl) 62888-22-6 C11H20O2S4
    2,2'-methylenebis(1,3-dithianyl-2-hydroxymethyl)
    —— 3-methylthiothiophene-2-carboxaldehyde 16237-84-6 C6H6OS2
    3-methylthiothiophene-2-carboxaldehyde
    —— (4-bromo-but-2-ynylsulfanyl)-benzene 1257307-95-1 C10H9BrS
    (4-bromo-but-2-ynylsulfanyl)-benzene
    —— thiacyclododeca-3,10-diyne-1,1-dioxide 514853-57-7 C11H14O2S
    thiacyclododeca-3,10-diyne-1,1-dioxide
    —— 2,2-bis(methylthio)heptane 75920-72-8 C9H20S2
    2,2-bis(methylthio)heptane
    —— 4-chloro-6-(3,4-dimethoxy-phenylsulfanyl)-2-methyl-pyrimidin-5-ylamine 870257-97-9 C13H14ClN3O2S
    4-chloro-6-(3,4-dimethoxy-phenylsulfanyl)-2-methyl-pyrimidin-5-ylamine
    —— cyclooctenyl-3-phenyl thioether 108533-50-2 C14H18S
    cyclooctenyl-3-phenyl thioether
    —— 4-Tert-butyl-2-[5-tert-butyl-3-(chloromethyl)-2-hydroxyphenyl]sulfanyl-6-(chloromethyl)phenol 404578-46-7 C22H28Cl2O2S
    4-Tert-butyl-2-[5-tert-butyl-3-(chloromethyl)-2-hydroxyphenyl]sulfanyl-6-(chloromethyl)phenol
    —— (3-Methyl-2-phenylsulfanylimidazol-4-yl)methanol 497059-31-1 C11H12N2OS
    (3-Methyl-2-phenylsulfanylimidazol-4-yl)methanol
    —— [(1R,3R)-2,2-dichloro-3-methylcyclopropyl]sulfanylbenzene 35347-63-8 C10H10Cl2S
    [(1R,3R)-2,2-dichloro-3-methylcyclopropyl]sulfanylbenzene
    —— 2-methyl-1-prop-2-enylsulphinylprop-1-ene 99097-21-9 C7H12OS
    2-methyl-1-prop-2-enylsulphinylprop-1-ene
    —— 2-methyl-1-(prop-2-enylthio)prop-1-ene 63196-69-0 C7H12S
    2-methyl-1-(prop-2-enylthio)prop-1-ene
    —— 1-ethylsulfanyl-5,5-dimethyl-hex-2-ene 32997-11-8 C10H20S
    1-ethylsulfanyl-5,5-dimethyl-hex-2-ene
    —— 1,3-thiaselenetane 1-oxide 918905-40-5 C2H4OSSe
    1,3-thiaselenetane 1-oxide
    —— Cyclopropyl-t-butyl-sulfon 89794-74-1 C7H14O2S
    Cyclopropyl-t-butyl-sulfon
    —— (4RS,6SR)-4-(tert-butyldimethylsilyloxy)-6-methyl-6-phenylthiocyclohex-2-enone —— C19H28O2SSi
    (4RS,6SR)-4-(tert-butyldimethylsilyloxy)-6-methyl-6-phenylthiocyclohex-2-enone
    —— (+)-(1R,3S,5S,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one 1289117-07-2 C19H28O3SSi
    (+)-(1R,3S,5S,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one
    —— (+)-(1R,3R,5S,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one 1289117-14-1 C19H28O3SSi
    (+)-(1R,3R,5S,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one
    —— (1S,3S,5S,6R)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one 1289117-08-3 C19H28O3SSi
    (1S,3S,5S,6R)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one
    —— thiacyclooctodeca-3,16-1,1-dioxide 514853-70-4 C17H26O2S
    thiacyclooctodeca-3,16-1,1-dioxide
    —— 2-(benzylthio)-4-chloropyridine 769163-29-3 C12H10ClNS
    2-(benzylthio)-4-chloropyridine
    —— 5-[((2,3-difluorophenyl)methyl)thio]-7-{[(1S,2S)-2-hydroxy-1-(hydroxymethyl)propyl]amino}thiazolo[4,5-d]pyrimidin-2(3H)-one 676345-69-0 C16H16F2N4O3S2
    5-[((2,3-difluorophenyl)methyl)thio]-7-{[(1S,2S)-2-hydroxy-1-(hydroxymethyl)propyl]amino}thiazolo[4,5-d]pyrimidin-2(3H)-one
    —— 4-Phenylmercapto-2,6-di-tert.-butyl-phenol 32551-12-5 C20H26OS
    4-Phenylmercapto-2,6-di-tert.-butyl-phenol