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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(Diethylamino)thiete 1,1-dioxide 59514-12-4 C7H13NO2S
    3-(Diethylamino)thiete 1,1-dioxide
    —— methyl 2-cyano-3-(5-phenylthio-2-furyl)acrylate 56656-71-4 C15H11NO3S
    methyl 2-cyano-3-(5-phenylthio-2-furyl)acrylate
    —— 2-phenyl-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile 209412-02-2 C18H13N3S
    2-phenyl-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile
    —— 3,4-dihydro-2H-pyrimido[1,2-c]pyrido[4,3-e][1,3]thiazine-6-thione 1202519-01-4 C10H9N3S2
    3,4-dihydro-2H-pyrimido[1,2-c]pyrido[4,3-e][1,3]thiazine-6-thione
    —— N-benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide 1426959-64-9 C22H22N2O2S
    N-benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carboxamide
    —— 2-[6-(ethylthio)pyridazin-3-yl]-2-phenylacetonitrile 1159497-77-4 C14H13N3S
    2-[6-(ethylthio)pyridazin-3-yl]-2-phenylacetonitrile
    —— 2-(ω-morpholinohexylthio)-4,6-dimethylpyrimidine 90094-36-3 C16H27N3OS
    2-(ω-morpholinohexylthio)-4,6-dimethylpyrimidine
    —— 2-(ω-anilinohexylthio)-4,6-dimethylpyrimidine 90094-34-1 C18H25N3S
    2-(ω-anilinohexylthio)-4,6-dimethylpyrimidine
    —— <(4,6-dimethylpyrimidin-2-ylthio)hexyl>pyridinium bromide 90094-32-9 Br*C17H24N3S
    <(4,6-dimethylpyrimidin-2-ylthio)hexyl>pyridinium bromide
    —— 2-(ω-piperidinohexylthio)-4,6-dimethylpyrimidine 90094-35-2 C17H29N3S
    2-(ω-piperidinohexylthio)-4,6-dimethylpyrimidine
    —— 1-Acetoxy-1-phenylthio-2-butanon 67175-44-4 C12H14O3S
    1-Acetoxy-1-phenylthio-2-butanon
    —— 1,1-Bis(phenylsulfanyl)-2-butanone 77331-08-9 C16H16OS2
    1,1-Bis(phenylsulfanyl)-2-butanone
    —— (Z)-N,N-diethyl-1-methoxy-2-(trifluoromethanesulfonyl)ethenamine 1315550-04-9 C8H14F3NO3S
    (Z)-N,N-diethyl-1-methoxy-2-(trifluoromethanesulfonyl)ethenamine
    —— dimethyl meso-2,3-di(pyrimidin-2-ylthio)butane-1,4-dioate 77586-19-7 C14H14N4O4S2
    dimethyl meso-2,3-di(pyrimidin-2-ylthio)butane-1,4-dioate
    —— 5-ethylsulfanyl-6-methyl-pyrazine-2,3-dicarbonitrile 72112-31-3 C9H8N4S
    5-ethylsulfanyl-6-methyl-pyrazine-2,3-dicarbonitrile
    —— N-<2-(p-tolylthio)ethyl>acetamide 98225-03-7 C11H15NOS
    N-<2-(p-tolylthio)ethyl>acetamide
    —— (4S,4aR)-4,4a-dimethylspiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane] 150930-70-4 C14H22S2
    (4S,4aR)-4,4a-dimethylspiro[1,2,3,4,5,6-hexahydronaphthalene-7,2'-1,3-dithiolane]
    —— N,N'-dimethyl-N,N'-bis(phenylsulfanylmethyl)ethane-1,2-diamine 214148-69-3 C18H24N2S2
    N,N'-dimethyl-N,N'-bis(phenylsulfanylmethyl)ethane-1,2-diamine
    —— 4-Methylsulfanyl-2-phenyl-[1,3]oxazin-6-one 135714-53-3 C11H9NO2S
    4-Methylsulfanyl-2-phenyl-[1,3]oxazin-6-one
    —— 4-(benzo-1,4-dithiafulven-6-yl)-1,2,3-thiadiazole 1028256-72-5 C10H6N2S3
    4-(benzo-1,4-dithiafulven-6-yl)-1,2,3-thiadiazole
    —— N<sup>1</sup>,N<sup>3</sup>-diphenyl-N<sup>2</sup>,N<sup>4</sup>-bis(6-methyl-3-(methylthio)-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)-N<sup>5</sup>-methylbiguanide 118458-63-2 C25H27N11O2S2
    N<sup>1</sup>,N<sup>3</sup>-diphenyl-N<sup>2</sup>,N<sup>4</sup>-bis(6-methyl-3-(methylthio)-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)-N<sup>5</sup>-methylbiguanide
    —— 2-Azathianthrene 2-oxide 106835-12-5 C11H7NOS2
    2-Azathianthrene 2-oxide
    —— 1-morpholino-2-(phenylthio)ethanone 425608-06-6 C12H15NO2S
    1-morpholino-2-(phenylthio)ethanone
    —— 1,7-diazathianthrene 113372-47-7 C10H6N2S2
    1,7-diazathianthrene
    —— 1,8-diazathianthrene 113372-48-8 C10H6N2S2
    1,8-diazathianthrene
    —— 2-Azathianthrene 106835-13-6 C11H7NS2
    2-Azathianthrene
    —— 4-(4-methylphenyl)-4-(phenylsulfanyl)nona-1,8-dien-5-one 878480-49-0 C22H24OS
    4-(4-methylphenyl)-4-(phenylsulfanyl)nona-1,8-dien-5-one
    —— 1-(4-methylphenyl)-1-(phenylsulfanyl)hex-5-en-2-one 878480-42-3 C19H20OS
    1-(4-methylphenyl)-1-(phenylsulfanyl)hex-5-en-2-one
    —— diethyl 1,7,7-trimethyl-3-(phenylthio)bicyclo[2.2.1]hept-2-en-2-yl phosphate 1233941-43-9 C20H29O4PS
    diethyl 1,7,7-trimethyl-3-(phenylthio)bicyclo[2.2.1]hept-2-en-2-yl phosphate
    —— 4,6-dichloro-2,8-bis(dimethylamino)-5-(4-nitrophenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine 259654-09-6 C19H17Cl2N7O2S
    4,6-dichloro-2,8-bis(dimethylamino)-5-(4-nitrophenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
    —— S-(2-{[2'-(N-methylthiocarbamoyl)ethyl]amino}ethyl) lithium hydrogen phosphorothioate 127914-25-4 C6H14N2O3PS2*Li
    S-(2-{[2'-(N-methylthiocarbamoyl)ethyl]amino}ethyl) lithium hydrogen phosphorothioate
    —— S-{2-[(2'-thiocarbamoylethyl)amino]ethyl} lithium hydrogen phosphorothioate 127914-09-4 C5H12N2O3PS2*Li
    S-{2-[(2'-thiocarbamoylethyl)amino]ethyl} lithium hydrogen phosphorothioate
    —— 2-[4-[(2-Methylsulfanylpyrimidin-4-yl)amino]phenyl]acetic acid 83528-53-4 C13H13N3O2S
    2-[4-[(2-Methylsulfanylpyrimidin-4-yl)amino]phenyl]acetic acid
    —— 4-chloro-3-fluoro-9-methyl-1-phenylsulfanyl-dipyrido[1,2-a;3',4'-d]imidazole 1207286-81-4 C17H11ClFN3S
    4-chloro-3-fluoro-9-methyl-1-phenylsulfanyl-dipyrido[1,2-a;3',4'-d]imidazole
    —— 2-Fluoro-1-methoxyethyl phenyl sulfide 136764-65-3 C9H11FOS
    2-Fluoro-1-methoxyethyl phenyl sulfide
    —— N'-[4-cyano-2-[diethoxyphosphoryl(phenyl)methyl]-5-methylsulfanylpyrazol-3-yl]-N,N-diethylmethanimidamide 1174766-39-2 C21H30N5O3PS
    N'-[4-cyano-2-[diethoxyphosphoryl(phenyl)methyl]-5-methylsulfanylpyrazol-3-yl]-N,N-diethylmethanimidamide
    —— diethyl [(5-amino-4-cyano-3-methylsulfanyl-pyrazol-1-yl)-benzyl]phosphonate 1173091-27-4 C16H21N4O3PS
    diethyl [(5-amino-4-cyano-3-methylsulfanyl-pyrazol-1-yl)-benzyl]phosphonate
    —— 1-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-3-methylsulfanyl-5-[(E)-morpholin-4-ylmethylideneamino]pyrazole-4-carbonitrile 1174766-45-0 C21H27FN5O4PS
    1-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-3-methylsulfanyl-5-[(E)-morpholin-4-ylmethylideneamino]pyrazole-4-carbonitrile
    —— N,N-dibutyl-N'-[4-cyano-2-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-5-methylsulfanylpyrazol-3-yl]methanimidamide 1174766-43-8 C25H37FN5O3PS
    N,N-dibutyl-N'-[4-cyano-2-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-5-methylsulfanylpyrazol-3-yl]methanimidamide
    —— N'-[4-cyano-2-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-5-methylsulfanylpyrazol-3-yl]-N,N-diethylmethanimidamide 1174766-41-6 C21H29FN5O3PS
    N'-[4-cyano-2-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-5-methylsulfanylpyrazol-3-yl]-N,N-diethylmethanimidamide
    —— ethyl (1E)-N-[4-cyano-2-[diethoxyphosphoryl(phenyl)methyl]-5-methylsulfanylpyrazol-3-yl]methanimidate 1174766-37-0 C19H25N4O4PS
    ethyl (1E)-N-[4-cyano-2-[diethoxyphosphoryl(phenyl)methyl]-5-methylsulfanylpyrazol-3-yl]methanimidate
    —— 1-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-3-methylsulfanyl-5-[(E)-piperidin-1-ylmethylideneamino]pyrazole-4-carbonitrile 1174766-44-9 C22H29FN5O3PS
    1-[diethoxyphosphoryl-(4-fluorophenyl)methyl]-3-methylsulfanyl-5-[(E)-piperidin-1-ylmethylideneamino]pyrazole-4-carbonitrile
    —— 1-[diethoxyphosphoryl(phenyl)methyl]-3-methylsulfanyl-5-[(E)-piperidin-1-ylmethylideneamino]pyrazole-4-carbonitrile 1174766-40-5 C22H30N5O3PS
    1-[diethoxyphosphoryl(phenyl)methyl]-3-methylsulfanyl-5-[(E)-piperidin-1-ylmethylideneamino]pyrazole-4-carbonitrile
    —— (2S)-2-(2-methylphenyl)sulfanyloxane —— C12H16OS
    (2S)-2-(2-methylphenyl)sulfanyloxane
    —— 2-(6-methyl-5-nitro-pyridin-2-ylsulfanyl)-ethanol 851446-85-0 C8H10N2O3S
    2-(6-methyl-5-nitro-pyridin-2-ylsulfanyl)-ethanol
    —— 6,7-dihydroxy-3-methylthio-5,6,7,8-tetrahydropyrazino<2,3-e>-as-triazine 87611-88-9 C6H9N5O2S
    6,7-dihydroxy-3-methylthio-5,6,7,8-tetrahydropyrazino<2,3-e>-as-triazine
    —— 6-amino-5-methylamino-3-methylthio-as-triazine 84582-95-6 C5H9N5S
    6-amino-5-methylamino-3-methylthio-as-triazine
    —— (Z)-1,1'-[oct-4-ene-2,6-diyne-1,8-diylbis(thio)]dibenzene 1445996-71-3 C20H16S2
    (Z)-1,1'-[oct-4-ene-2,6-diyne-1,8-diylbis(thio)]dibenzene
    —— 3-Methyl-4-((5-nitro-2-(2-pyridylthio)phenylmethylene)-1-phenyl-2-pyrazolin-5-one 1024724-31-9 C22H16N4O3S
    3-Methyl-4-((5-nitro-2-(2-pyridylthio)phenylmethylene)-1-phenyl-2-pyrazolin-5-one
    —— Methyl tert-butyltrisulfane-1-carboxylate 95502-90-2 C6H12O2S3
    Methyl tert-butyltrisulfane-1-carboxylate