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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(4-((4-((((Amino(imino)methyl)amino)(imino)methyl)amino)phenyl)thio)phenyl)dicarbonimidoic diamide/imido 5440-96-0 C16H20N10S
    N-(4-((4-((((Amino(imino)methyl)amino)(imino)methyl)amino)phenyl)thio)phenyl)dicarbonimidoic diamide/imido
    —— (R)-2-tert-butoxycarbonylamino-N-ethyl-thiopropionimidic acid 944705-55-9 C10H20N2O2S
    (R)-2-tert-butoxycarbonylamino-N-ethyl-thiopropionimidic acid
    —— 4-[4-Hydroxy-3-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-2-(2,4,4-trimethylpentan-2-yl)phenol 951403-93-3 C28H42O2S
    4-[4-Hydroxy-3-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-2-(2,4,4-trimethylpentan-2-yl)phenol
    —— 3-morpholino-1-(4-phenylsulfanyl-phenyl)-propan-1-ol 6317-79-9 C19H23NO2S
    3-morpholino-1-(4-phenylsulfanyl-phenyl)-propan-1-ol
    —— 6,6-dimethyl-1-(4-methylsulfanyl-phenyl)-1,6-dihydro-[1,3,5]triazine-2,4-diamine 90-07-3 C12H17N5S
    6,6-dimethyl-1-(4-methylsulfanyl-phenyl)-1,6-dihydro-[1,3,5]triazine-2,4-diamine
    —— S-sec.-Butyl-thiuronium 44648-64-8 C5H12N2S
    S-sec.-Butyl-thiuronium
    —— <(oxo-2 cyclopentyl)-1 ethyl>-2 pentene-4 dithioate de methyle 119755-99-6 C13H20OS2
    <(oxo-2 cyclopentyl)-1 ethyl>-2 pentene-4 dithioate de methyle
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-pyridylthio)ethyl>oxazolidine 143122-20-7 C24H38N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-pyridylthio)ethyl>oxazolidine
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-<(1-methyl-1H-tetrazol-5-yl)thio>ethyl>oxazolidine 143122-26-3 C21H37N5O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-<(1-methyl-1H-tetrazol-5-yl)thio>ethyl>oxazolidine
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<3-(2-pyridylthio)propyl>oxazolidine 143122-16-1 C25H40N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<3-(2-pyridylthio)propyl>oxazolidine
    —— 2-Amino-5-phenyl-4,6-di-(benzylmercapto)-pyrimidin 6299-80-5 C24H21N3S2
    2-Amino-5-phenyl-4,6-di-(benzylmercapto)-pyrimidin
    —— l-5-(hydroxymethyl)-3-[4-(methylthio)phenyl]-2-oxazolidinone 64589-90-8 C11H13NO3S
    l-5-(hydroxymethyl)-3-[4-(methylthio)phenyl]-2-oxazolidinone
    —— 2-Amino-5-phenyl-4,6-di-(o-chlorbenzylmercapto)-pyrimidin 6299-79-2 C24H19Cl2N3S2
    2-Amino-5-phenyl-4,6-di-(o-chlorbenzylmercapto)-pyrimidin
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(4-pyridylthio)ethyl>oxazolidine 143122-22-9 C24H38N2O3S
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(4-pyridylthio)ethyl>oxazolidine
    —— Benzyl-dimethyl-(phenylsulfanylmethyl)azanium 7154-02-1 C16H20NS+
    Benzyl-dimethyl-(phenylsulfanylmethyl)azanium
    —— 4.5-Bis-(3-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5376-24-9 C24H18F2N2OS2
    4.5-Bis-(3-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— 1,4-bis(vinylthio)benzene 86199-22-6 C10H10S2
    1,4-bis(vinylthio)benzene
    —— 4.5-Bis-(2-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-34-7 C24H18Cl2N2OS2
    4.5-Bis-(2-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— Isopropan-α-thiosulfonsaeure-S-aethylester 2043-80-3 C5H12O2S2
    Isopropan-α-thiosulfonsaeure-S-aethylester
    —— 4.5-Bis-(2-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-36-9 C24H18F2N2OS2
    4.5-Bis-(2-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— t-butyl 3-methyl-4-phenylthiohept-2(E)-enoate 208582-32-5 C18H26O2S
    t-butyl 3-methyl-4-phenylthiohept-2(E)-enoate
    —— methyl (2RS,3RS)-2,3-dimethyl-4,4-bis(phenylthio)heptanoate 128098-99-7 C22H28O2S2
    methyl (2RS,3RS)-2,3-dimethyl-4,4-bis(phenylthio)heptanoate
    —— 4.5-Bis-(4-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-37-0 C24H18F2N2OS2
    4.5-Bis-(4-fluor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— Dicyclopropylcarbinyl-phenylsulfid 59277-51-9 C13H16S
    Dicyclopropylcarbinyl-phenylsulfid
    —— S-(2-Aminooxy-propyl)-isothioharnstoff 90642-24-3 C4H11N3OS
    S-(2-Aminooxy-propyl)-isothioharnstoff
    —— 4.5-Bis-(4-brom-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-33-6 C24H18Br2N2OS2
    4.5-Bis-(4-brom-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— 4,5-Bis-(benzylthio)-2-phenyl-3-pyridazinon 5273-32-5 C24H20N2OS2
    4,5-Bis-(benzylthio)-2-phenyl-3-pyridazinon
    —— 4-hydrazino-6-<(phenylmethyl)thio>-2,5-pyrimidinediamine 31736-47-7 C11H14N6S
    4-hydrazino-6-<(phenylmethyl)thio>-2,5-pyrimidinediamine
    —— 4-((2-chlorophenyl)thio)-5-hydroxy-1,6-dihydro-[1,1'-biphenyl]-3(2H)-one 1639046-45-9 C18H15ClO2S
    4-((2-chlorophenyl)thio)-5-hydroxy-1,6-dihydro-[1,1'-biphenyl]-3(2H)-one
    —— 3-Hydroxy-5-phenyl-2-phenylsulfanylcyclohex-2-en-1-one 883947-40-8 C18H16O2S
    3-Hydroxy-5-phenyl-2-phenylsulfanylcyclohex-2-en-1-one
    —— 3-Phenyl-7-p-tolyl-1H-[1,2,4]triazino[5,6-e][1,3,4]thiadiazine 120588-54-7 C17H13N5S
    3-Phenyl-7-p-tolyl-1H-[1,2,4]triazino[5,6-e][1,3,4]thiadiazine
    —— butylxanthate anion 53452-11-2 C5H9OS2
    butylxanthate anion
    —— Propanethiohydrazide 89946-93-0 C3H8N2S
    Propanethiohydrazide
    —— 4-phenylthiocyclohexanol 34209-61-5 C12H16OS
    4-phenylthiocyclohexanol
    —— Tetrathiocyanatocobaltate —— C4CoN4S4-4
    Tetrathiocyanatocobaltate
    —— 2-ethyl-2-(p-tolylthio)cyclopentanone 84612-99-7 C14H18OS
    2-ethyl-2-(p-tolylthio)cyclopentanone
    —— 1-(4-phenylsulfanyl-phenyl)-3<i>t</i>-[2]thienyl-propenone 76542-46-6 C19H14OS2
    1-(4-phenylsulfanyl-phenyl)-3<i>t</i>-[2]thienyl-propenone
    —— 1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-(4-fluorophenyl)urea 1263499-69-9 C19H17FN4OS
    1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-(4-fluorophenyl)urea
    —— 1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-m-tolylurea 1263499-65-5 C20H20N4OS
    1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-m-tolylurea
    —— 2-Azanidylethylazanide;chromium(3+);thiocyanic acid —— C7H19CrN7S-3
    2-Azanidylethylazanide;chromium(3+);thiocyanic acid
    —— (β-trifluoromethyl)vinyl tolyl sulfide 1226575-31-0 C10H9F3S
    (β-trifluoromethyl)vinyl tolyl sulfide
    —— 1-Isothiocyanato-propan-2-one 89914-76-1 C4H5NOS
    1-Isothiocyanato-propan-2-one
    —— N,N-Dihexylthioacatamid 68506-58-1 C14H29NS
    N,N-Dihexylthioacatamid
    —— 2-[4-(methylsulfanyl)benzyl]-1,2,5-thiadiazolidine 1,1-dioxide 1341126-72-4 C10H14N2O2S2
    2-[4-(methylsulfanyl)benzyl]-1,2,5-thiadiazolidine 1,1-dioxide
    —— 3-(p-tolylthio)-1-propanamine 67215-17-2 C10H15NS
    3-(p-tolylthio)-1-propanamine
    —— 2-(6-aminohexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile 1245907-05-4 C17H24N6S
    2-(6-aminohexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile
    —— O-tert-butyl S-4-methylphenyl carbonothioate 1146734-36-2 C12H16O2S
    O-tert-butyl S-4-methylphenyl carbonothioate
    —— 2,2,5,5-Tetramethyl-[1,3]dithian 60311-43-5 C8H16S2
    2,2,5,5-Tetramethyl-[1,3]dithian
    —— (2S)-2-[[2-[[(2S)-1,4-dioxan-2-yl]methyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane 934346-66-4 C14H24O4S2
    (2S)-2-[[2-[[(2S)-1,4-dioxan-2-yl]methyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane
    —— 1,2-O:5,6-O,S-diisopropylidene-6-thio-α-D-glucofuranose 288850-20-4 C12H20O5S
    1,2-O:5,6-O,S-diisopropylidene-6-thio-α-D-glucofuranose