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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(2-Butenylthio)-1-(1-methylethyl)-1H-1,2,4-triazol-3-yl ethanesulfonate 61800-05-3 C11H19N3O3S2
    5-(2-Butenylthio)-1-(1-methylethyl)-1H-1,2,4-triazol-3-yl ethanesulfonate
    —— 1-<(Methylsulfinyl)methylen>cyclopentan 55059-03-5 C7H12OS
    1-<(Methylsulfinyl)methylen>cyclopentan
    —— 1-({[5-(methylthio)-1H-pyrazol-3-yl]methyl}amino)butan-2-ol 844872-54-4 C9H17N3OS
    1-({[5-(methylthio)-1H-pyrazol-3-yl]methyl}amino)butan-2-ol
    —— 5-(2-Butenylthio)-1-methyl-1H-1,2,4-triazol-3-ol methanesulfonate (ester) 55375-40-1 C8H13N3O3S2
    5-(2-Butenylthio)-1-methyl-1H-1,2,4-triazol-3-ol methanesulfonate (ester)
    —— methyl-5,5-(dimethylenedithio)-12(S)-hydroxy-6(E),8(E),10(E),14(Z)-eicosatetraenoate 218162-96-0 C23H36O3S2
    methyl-5,5-(dimethylenedithio)-12(S)-hydroxy-6(E),8(E),10(E),14(Z)-eicosatetraenoate
    —— methyl-5,5-(dimethylenedithio)-12(S)-hydroxy-6(E),8(Z),10(E),14(Z)-eicosatetraenoate 218162-95-9 C23H36O3S2
    methyl-5,5-(dimethylenedithio)-12(S)-hydroxy-6(E),8(Z),10(E),14(Z)-eicosatetraenoate
    —— 2-((3,4-Dimethoxyphenyl)thio)-N-methylbenzenemethanamine (Z)-2-butenedioate (1:1) 127905-91-3 C20H23NO6S
    2-((3,4-Dimethoxyphenyl)thio)-N-methylbenzenemethanamine (Z)-2-butenedioate (1:1)
    —— 3-(2-(Dimethylaminomethyl)phenylthio)benzonitrile hydrogen maleate 139009-47-5 C20H20N2O4S
    3-(2-(Dimethylaminomethyl)phenylthio)benzonitrile hydrogen maleate
    —— N,N-Dimethyl-2-(3-fluorophenylthio)benzylamine hydrogen maleate 139009-29-3 C19H20FNO4S
    N,N-Dimethyl-2-(3-fluorophenylthio)benzylamine hydrogen maleate
    —— (E)-2-amino-N'-((6-methyl-2-(p-tolylthio)quinolin-3-yl)methylene)benzohydrazide 1443242-63-4 C25H22N4OS
    (E)-2-amino-N'-((6-methyl-2-(p-tolylthio)quinolin-3-yl)methylene)benzohydrazide
    —— Decanoic acid, 2-(4-(2-chloro-7-fluoro-11H-dibenz(b,e)(1,4)oxathiepin-11-yl)-1-piperidinyl)ethyl ester, (Z)-2-butenedioate (1:1) 83975-89-7 C34H43ClFNO7S
    Decanoic acid, 2-(4-(2-chloro-7-fluoro-11H-dibenz(b,e)(1,4)oxathiepin-11-yl)-1-piperidinyl)ethyl ester, (Z)-2-butenedioate (1:1)
    —— Spiro(11H-dibenz(b,e)(1,4)oxathiepin-11,4'-piperidine), (Z)-2-butenedioate (1:1) 98796-34-0 C21H21NO5S
    Spiro(11H-dibenz(b,e)(1,4)oxathiepin-11,4'-piperidine), (Z)-2-butenedioate (1:1)
    —— 4-[6-Chloro-2-(4-cyanoanilino)pyrimidin-4-yl]sulfanyl-3,5-dimethylbenzonitrile 903593-80-6 C20H14ClN5S
    4-[6-Chloro-2-(4-cyanoanilino)pyrimidin-4-yl]sulfanyl-3,5-dimethylbenzonitrile
    —— 2-(β-Cyanoethyl)thio-3-amino-6-chloropyridine 78909-78-1 C8H8ClN3S
    2-(β-Cyanoethyl)thio-3-amino-6-chloropyridine
    —— 2-(2-(Phenylthio)phenyl)ethylamine maleate 127876-78-2 C18H19NO4S
    2-(2-(Phenylthio)phenyl)ethylamine maleate
    —— 1-benzyl-3-(ethylthio)-N<sup>5</sup>,N<sup>5</sup>-dimethyl-1H-pyrazole-4,5-diamine 1196685-97-8 C14H20N4S
    1-benzyl-3-(ethylthio)-N<sup>5</sup>,N<sup>5</sup>-dimethyl-1H-pyrazole-4,5-diamine
    —— (2R,4Z)-1,1-Bis(ethylthio)-2-hydroxy-4-decen 136810-38-3 C14H28OS2
    (2R,4Z)-1,1-Bis(ethylthio)-2-hydroxy-4-decen
    —— 6-methyl-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde 1134633-65-0 C19H14N4OS
    6-methyl-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde
    —— 4-((2-((Dimethylamino)methyl)phenyl)thio)-1,3-benzenediol (Z)-2-butenedioate (1:1) (salt) 127906-28-9 C19H21NO6S
    4-((2-((Dimethylamino)methyl)phenyl)thio)-1,3-benzenediol (Z)-2-butenedioate (1:1) (salt)
    —— 3-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-24-5 C19H21NO5S
    3-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 3-Furancarbothioamide, N-(3-(2-butenylthio)-4-chlorophenyl)-2-methyl- 191984-43-7 C16H16ClNOS2
    3-Furancarbothioamide, N-(3-(2-butenylthio)-4-chlorophenyl)-2-methyl-
    —— S<sup>6</sup>,2'-cyclo-2-O-methyluridine 74610-61-0 C10H12N2O5S
    S<sup>6</sup>,2'-cyclo-2-O-methyluridine
    —— S<sup>6</sup>,2'-cyclo-2-thiouridine 74666-17-4 C9H10N2O4S2
    S<sup>6</sup>,2'-cyclo-2-thiouridine
    —— S<sup>6</sup>,2'-cyclouridine 74610-62-1 C9H10N2O5S
    S<sup>6</sup>,2'-cyclouridine
    —— 3-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-51-8 C17H17NO5S
    3-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 1-methylsulfonyldodecane 7560-61-4 C13H28O2S
    1-methylsulfonyldodecane
    —— S<sup>6</sup>,2'-cyclo-isocytidine 74652-99-6 C9H11N3O4S
    S<sup>6</sup>,2'-cyclo-isocytidine
    —— S<sup>2</sup>,2'-cyclo-5-bromo-2-thiouridine 74610-60-9 C9H9BrN2O4S
    S<sup>2</sup>,2'-cyclo-5-bromo-2-thiouridine
    —— 1,12-diisothiocyanatododecane 105214-58-2 C14H24N2S2
    1,12-diisothiocyanatododecane
    —— 2-Methylthio-1-allyl-pyrimidon-(4) 6204-00-8 C8H10N2OS
    2-Methylthio-1-allyl-pyrimidon-(4)
    —— Cyclohexyldithiocarbamate 51300-97-1 C10H17NO2S2
    Cyclohexyldithiocarbamate
    —— S-cyclopropyl cyclopropanethiosulfonate 139631-63-3 C6H10O2S2
    S-cyclopropyl cyclopropanethiosulfonate
    —— S-1-chlorocyclopropyl cyclopropanethiosulfonate 139631-64-4 C6H9ClO2S2
    S-1-chlorocyclopropyl cyclopropanethiosulfonate
    —— 2H-Hexafluor-propan-1-thiol 684-14-0 C3H2F6S
    2H-Hexafluor-propan-1-thiol
    —— 6-methoxy-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde 1134633-67-2 C19H14N4O2S
    6-methoxy-2-[(5-phenyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinoline-3-carbaldehyde
    —— 3,5-dimethoxy-2-(5-nitro-1H-indol-3-ylthio)phenol 1448175-29-8 C16H14N2O5S
    3,5-dimethoxy-2-(5-nitro-1H-indol-3-ylthio)phenol
    —— 3-chloro-4-[(4-chlorophenyl)thio]-5-hydroxy-2(5H)-furanone 52180-41-3 C10H6Cl2O3S
    3-chloro-4-[(4-chlorophenyl)thio]-5-hydroxy-2(5H)-furanone
    —— (disulfido)carbonic acid <i>SS</i>-isopropyl ester <i>O</i>-methyl ester 61775-32-4 C5H10O2S2
    (disulfido)carbonic acid <i>SS</i>-isopropyl ester <i>O</i>-methyl ester
    —— Cyclopropanecarbonitrile, 1-[(phenylthio)methyl]- 1387565-86-7 C11H11NS
    Cyclopropanecarbonitrile, 1-[(phenylthio)methyl]-
    —— N-(1-phenylmethyl-1-propyl)-N-(2-phenylsulfanylethyl)formamide 886759-20-2 C19H23NOS
    N-(1-phenylmethyl-1-propyl)-N-(2-phenylsulfanylethyl)formamide
    —— 2-(diethylamino)ethyl octyl sulfoxide 69002-75-1 C14H31NOS
    2-(diethylamino)ethyl octyl sulfoxide
    —— Chlorthiosulfonsaeure-methylester 91571-60-7 CH3ClO2S2
    Chlorthiosulfonsaeure-methylester
    —— 8-Chloro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin 83986-02-1 C19H20ClNOS
    8-Chloro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin
    —— Acetonitrile, isothiocyanato- 32772-75-1 C3H2N2S
    Acetonitrile, isothiocyanato-
    —— N-Vinylthiopropionamid 37109-53-8 C5H9NS
    N-Vinylthiopropionamid
    —— 1-(4-fluorophenyl)ethyl-(2-phenylsulfanyl)ethylamine 886759-18-8 C16H18FNS
    1-(4-fluorophenyl)ethyl-(2-phenylsulfanyl)ethylamine
    —— [2-Phenylsulfanylethyl(trimethylsilyl)amino] thiohypochlorite 157736-02-2 C11H18ClNS2Si
    [2-Phenylsulfanylethyl(trimethylsilyl)amino] thiohypochlorite
    —— 2-{[4-(2-ethoxy-2-oxoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-05-5 C15H23NO4S2
    2-{[4-(2-ethoxy-2-oxoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— N-(2-Phenylmercapto-aethyl)-biguanid 91011-18-6 C10H15N5S
    N-(2-Phenylmercapto-aethyl)-biguanid
    —— benzyl(4-ethylphenyl)sulfane 100976-97-4 C15H16S
    benzyl(4-ethylphenyl)sulfane