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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepin-9-one 214270-64-1 C12H9NOS
    9,10-dihydropyrrolo[2,1-b][1,3]benzothiazepin-9-one
    —— 5-(2-chlorobenzylthio)-3-(benzyloxy)-N-(4-methylthiazol-2-yl)pyridin-2-amine hydrochloride 936245-47-5 C23H20ClN3OS2*ClH
    5-(2-chlorobenzylthio)-3-(benzyloxy)-N-(4-methylthiazol-2-yl)pyridin-2-amine hydrochloride
    —— S-(3-chlorobut-2-en-1-yl)isothiuronium chloride 52265-81-3 C5H9ClN2S*ClH
    S-(3-chlorobut-2-en-1-yl)isothiuronium chloride
    —— (n-octylthio)ethanal 1334321-71-9 C10H20OS
    (n-octylthio)ethanal
    —— N4-(4-aminomethyl-cyclohexylmethyl)-N2-(2-methylsulfanyl-benzyl)-5-nitro-pyrimidine-2,4-diamine 736050-81-0 C20H28N6O2S
    N4-(4-aminomethyl-cyclohexylmethyl)-N2-(2-methylsulfanyl-benzyl)-5-nitro-pyrimidine-2,4-diamine
    —— 4-Phenyl-2-(phenylthio)butanal 121033-27-0 C16H16OS
    4-Phenyl-2-(phenylthio)butanal
    —— N4-(4-dimethylaminomethyl-cyclohexylmethyl)-N2-(2-methylsulfanyl-benzyl)-5-nitro-pyrimidine-2,4-diamine 736047-48-6 C22H32N6O2S
    N4-(4-dimethylaminomethyl-cyclohexylmethyl)-N2-(2-methylsulfanyl-benzyl)-5-nitro-pyrimidine-2,4-diamine
    —— 5-Chlor-2,4,2'-trinitrophenylsulfid 62486-59-3 C12H6ClN3O6S
    5-Chlor-2,4,2'-trinitrophenylsulfid
    —— 6-Methylsulfanyl-1-propoxy-5-propylpyrimidine-2,4-dione 191472-54-5 C11H18N2O3S
    6-Methylsulfanyl-1-propoxy-5-propylpyrimidine-2,4-dione
    —— 1,5-Bis(2-nitrophenylthio)-2,4-dinitrobenzol 62486-60-6 C18H10N4O8S2
    1,5-Bis(2-nitrophenylthio)-2,4-dinitrobenzol
    —— 3-(2,4-diamino-5-carboxymethylsulfanyl-phenylsulfanyl)-propionic acid 13399-39-8 C11H14N2O4S2
    3-(2,4-diamino-5-carboxymethylsulfanyl-phenylsulfanyl)-propionic acid
    —— 2,4-Dinitro-1-(2-carboxy-aethylmercapto)-5-(2-carboxy-phenylmercapto)-benzol 13399-40-1 C16H12N2O8S2
    2,4-Dinitro-1-(2-carboxy-aethylmercapto)-5-(2-carboxy-phenylmercapto)-benzol
    —— 3-(2-methylsulfanyl-pyrimidin-4-yl)-3-oxo-propionic acid tert-butyl ester 852164-50-2 C12H16N2O3S
    3-(2-methylsulfanyl-pyrimidin-4-yl)-3-oxo-propionic acid tert-butyl ester
    —— 2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-3-oxo-propionic acid tert-butyl ester 852164-47-7 C19H21ClN2O3S
    2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-3-oxo-propionic acid tert-butyl ester
    —— 1,3-Bis<<4-(1,1-dimethylpentyl)pheny>thio>-4,6-dinitrobenzene 1027252-38-5 C32H40N2O4S2
    1,3-Bis<<4-(1,1-dimethylpentyl)pheny>thio>-4,6-dinitrobenzene
    —— 2-(Benzylsulfanyl)-6-(thiophen-2-yl)-4-(trifluoromethyl)pyridine-3-carbonitrile 293759-06-5 C18H11F3N2S2
    2-(Benzylsulfanyl)-6-(thiophen-2-yl)-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— ST 1899 395073-74-2 C17H19N3S
    ST 1899
    —— (R)-2-<1-(2-hydroxypropyl)>-2-phenyl-1,3-dithiane 167780-47-4 C13H18OS2
    (R)-2-<1-(2-hydroxypropyl)>-2-phenyl-1,3-dithiane
    —— 5-Cyclopropyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione 191472-50-1 C11H16N2O3S
    5-Cyclopropyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione
    —— 5-Cyclopropyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione 191472-52-3 C15H16N2O3S
    5-Cyclopropyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione
    —— 5-Cyclopropyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione 191472-53-4 C16H18N2O3S
    5-Cyclopropyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione
    —— 3-propylthio-1,2,4-triazine 857008-89-0 C6H9N3S
    3-propylthio-1,2,4-triazine
    —— <i>N</i>-(2-phenylsulfanyl-ethyl)-acetoacetamide 88124-16-7 C12H15NO2S
    <i>N</i>-(2-phenylsulfanyl-ethyl)-acetoacetamide
    —— anti-tricarbonyl(spiro{1,3-dithiane-2,1'-{2.2}metacyclophane})chromium 136276-56-7 C22H20CrO3S2
    anti-tricarbonyl(spiro{1,3-dithiane-2,1'-{2.2}metacyclophane})chromium
    —— 6-Methylsulfanyl-1-phenylmethoxy-5-propylpyrimidine-2,4-dione 191472-56-7 C15H18N2O3S
    6-Methylsulfanyl-1-phenylmethoxy-5-propylpyrimidine-2,4-dione
    —— 5-Ethyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione 191472-48-7 C15H18N2O3S
    5-Ethyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione
    —— 5-ethyl-6-(methylthio)-1-(3-phenylpropyl)uracil 172256-47-2 C16H20N2O2S
    5-ethyl-6-(methylthio)-1-(3-phenylpropyl)uracil
    —— 1-butyl-5-ethyl-6-(methylthio)uracil 172256-46-1 C11H18N2O2S
    1-butyl-5-ethyl-6-(methylthio)uracil
    —— 5-Ethyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione 191472-44-3 C10H16N2O3S
    5-Ethyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione
    —— 1-Butoxy-5-ethyl-6-methylsulfanylpyrimidine-2,4-dione 191472-46-5 C11H18N2O3S
    1-Butoxy-5-ethyl-6-methylsulfanylpyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione 191472-58-9 C9H14N2O3S
    5-Methyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione 191472-61-4 C14H16N2O3S
    5-Methyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione
    —— 3-(phenylthio)propanal dimethyl acetal 52072-17-0 C11H16O2S
    3-(phenylthio)propanal dimethyl acetal
    —— 1-Butyl-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 172256-48-3 C12H20N2O2S
    1-Butyl-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione 191472-60-3 C13H14N2O3S
    5-Methyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione
    —— 6-Methylsulfanyl-1-(2-phenylethoxy)-5-propan-2-ylpyrimidine-2,4-dione 191472-40-9 C16H20N2O3S
    6-Methylsulfanyl-1-(2-phenylethoxy)-5-propan-2-ylpyrimidine-2,4-dione
    —— 1-Butoxy-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 191472-38-5 C12H20N2O3S
    1-Butoxy-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 1-(2-Methoxyethoxy)-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 191472-42-1 C11H18N2O4S
    1-(2-Methoxyethoxy)-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 6-Methylsulfanyl-1-phenylmethoxy-5-propan-2-ylpyrimidine-2,4-dione 191472-39-6 C15H18N2O3S
    6-Methylsulfanyl-1-phenylmethoxy-5-propan-2-ylpyrimidine-2,4-dione
    —— 4-(benzylthio)-N'-hydroxybenzocarboximidamide 947689-76-1 C14H14N2OS
    4-(benzylthio)-N'-hydroxybenzocarboximidamide
    —— 4-Chlor-2-ethylmercapto-pyrimidin 98198-74-4 C6H7ClN2S
    4-Chlor-2-ethylmercapto-pyrimidin
    —— (1R,2S)-2-methylsulfanylthioxocarbonyloxycyclopentanecarboxylic acid ethyl ester 162084-62-0 C10H16O3S2
    (1R,2S)-2-methylsulfanylthioxocarbonyloxycyclopentanecarboxylic acid ethyl ester
    —— 2,2-difluoroethanethioamide 180002-32-8 C2H3F2NS
    2,2-difluoroethanethioamide
    —— 3-Methylmercapto-6-(4-aminobenzyl)-2,5-dihydro-1,2,4-triazin-5-on 77441-96-4 C11H12N4OS
    3-Methylmercapto-6-(4-aminobenzyl)-2,5-dihydro-1,2,4-triazin-5-on
    —— N-benzal-5-(methylthio)pyridine-2-amine 1374129-87-9 C13H12N2S
    N-benzal-5-(methylthio)pyridine-2-amine
    —— 2-(2-amino-4-chloro-phenylsulfanyl)-benzoic acid methyl ester 93535-13-8 C14H12ClNO2S
    2-(2-amino-4-chloro-phenylsulfanyl)-benzoic acid methyl ester
    —— 2,3-Bis-butylsulfanyl-6,7,9,10,12,13,15,16,18,19-decahydro-5,8,11,14,17,20-hexaoxa-benzocyclooctadecene 150921-07-6 C24H40O6S2
    2,3-Bis-butylsulfanyl-6,7,9,10,12,13,15,16,18,19-decahydro-5,8,11,14,17,20-hexaoxa-benzocyclooctadecene
    —— (3S)-3-methyl-4-phenylsulfanylbutanenitrile 157733-10-3 C11H13NS
    (3S)-3-methyl-4-phenylsulfanylbutanenitrile
    —— 1,1-bis(3-phenylpropoxymethyl)-3-(p-tolylsulfanyl)cyclobutane 1221171-40-9 C31H38O2S
    1,1-bis(3-phenylpropoxymethyl)-3-(p-tolylsulfanyl)cyclobutane
    —— S,S'-bis-p-chlorophenyl dithiocarbonate 24455-27-4 C13H8Cl2OS2
    S,S'-bis-p-chlorophenyl dithiocarbonate