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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [3-amino-4-[4-fluoro-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol 1005413-00-2 C16H19FN2OS
    [3-amino-4-[4-fluoro-2-[[methyl((111C)methyl)amino]methyl]phenyl]sulfanylphenyl]methanol
    —— N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-fluorobenzylamine 1005412-79-2 C15H17FN2OS
    N-methyl-2-(2'-amino-4'-hydroxymethylphenylthio)-5-fluorobenzylamine
    —— Hexakis(p-aminophenylthiomethyl)benzol 72031-82-4 C48H48N6S6
    Hexakis(p-aminophenylthiomethyl)benzol
    —— hexakis[(2-pyridylsulfanyl)methyl]benzene 53403-86-4 C42H36N6S6
    hexakis[(2-pyridylsulfanyl)methyl]benzene
    —— 6-methoxy-3-(phenylthio)-1H-indole 92552-56-2 C15H13NOS
    6-methoxy-3-(phenylthio)-1H-indole
    —— 5,6-dihydropyrido[2,3-b][1,4]benzothiazepine 169878-94-8 C12H10N2S
    5,6-dihydropyrido[2,3-b][1,4]benzothiazepine
    —— 1,6-dithio-2,5-dithia-adipic acid <i>O</i>,<i>O</i>'-bis-dimethylaminomethyl ester 119210-25-2 C10H20N2O2S4
    1,6-dithio-2,5-dithia-adipic acid <i>O</i>,<i>O</i>'-bis-dimethylaminomethyl ester
    —— Hexakis(phenylthiomethyl)benzol 53370-13-1 C48H42S6
    Hexakis(phenylthiomethyl)benzol
    —— 1-(phenylthio)cyclopropanecarboxylic acid 36638-57-0 C10H10O2S
    1-(phenylthio)cyclopropanecarboxylic acid
    —— 4-Aza-phenothiazin-10-carbonsaeure-1-dimethylamino-propylester-3 98344-49-1 C17H19N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-1-dimethylamino-propylester-3
    —— 2-(4-phenyl-butylsulfanyl)-pyrimidin-4-ylamine 60722-72-7 C14H17N3S
    2-(4-phenyl-butylsulfanyl)-pyrimidin-4-ylamine
    —— 2-{3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}-N-(2,5-difluorobenzyl)acetamide 745837-72-3 C32H37F2N3O2S
    2-{3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}-N-(2,5-difluorobenzyl)acetamide
    —— {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetic acid 735274-10-9 C25H32N2O3S
    {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetic acid
    —— 1-ethylsulfanyl(113C)propane 140155-09-5 C5H12S
    1-ethylsulfanyl(113C)propane
    —— 4-[3-(N-dodecyl-N-trifluoroacetylamino)propylthio]pyridine 155966-35-1 C22H35F3N2OS
    4-[3-(N-dodecyl-N-trifluoroacetylamino)propylthio]pyridine
    —— 2-Methyl-4-phenylthio-benzofuro<3,2-d>pyrimidin 68217-87-8 C17H12N2OS
    2-Methyl-4-phenylthio-benzofuro<3,2-d>pyrimidin
    —— butyl trans-2-butenyl sulfone 73687-62-4 C8H16O2S
    butyl trans-2-butenyl sulfone
    —— <2-(6-Ethoxy-5,6-dihydro-6-methylthiazolo<3,2-b><1,2,4>triazol-5-yliden)ethyl>phosphonsaeure-diethylester 113250-13-8 C13H22N3O4PS
    <2-(6-Ethoxy-5,6-dihydro-6-methylthiazolo<3,2-b><1,2,4>triazol-5-yliden)ethyl>phosphonsaeure-diethylester
    —— p-Bromphenyl-2-pentylsulfid 29182-85-2 C11H15BrS
    p-Bromphenyl-2-pentylsulfid
    —— 2-methyl-5-phenylsulfanyl-oxazole-4-carbonitrile 60957-16-6 C11H8N2OS
    2-methyl-5-phenylsulfanyl-oxazole-4-carbonitrile
    —— 2-ethyl-5-phenylsulfanyl-oxazole-4-carbonitrile 60957-19-9 C12H10N2OS
    2-ethyl-5-phenylsulfanyl-oxazole-4-carbonitrile
    —— <<2,3-Dihydro-2-(2-methyl-1-oxopropyl)imidazo<2,1-b>thiazol-3-yl>methyl>phosphonsaeure-diethylester 113250-37-6 C14H23N2O4PS
    <<2,3-Dihydro-2-(2-methyl-1-oxopropyl)imidazo<2,1-b>thiazol-3-yl>methyl>phosphonsaeure-diethylester
    —— 5-Phenylthiooxazol-4-carbonitril 60957-13-3 C10H6N2OS
    5-Phenylthiooxazol-4-carbonitril
    —— 5-cyclopropyl-3-(methylthio)-1,2,4-triazine 69466-76-8 C7H9N3S
    5-cyclopropyl-3-(methylthio)-1,2,4-triazine
    —— 4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-5-phenylsulfanylmethyl-isoxazole 132611-27-9 C16H18N2O2S
    4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-5-phenylsulfanylmethyl-isoxazole
    —— (2R)-2-[{2-amino-5-[(4-bromo-2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}(methyl)amino]-4-methylpentan-1-ol 849942-85-4 C19H23BrFN5OS2
    (2R)-2-[{2-amino-5-[(4-bromo-2-fluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}(methyl)amino]-4-methylpentan-1-ol
    —— 3-Methyl-2-thiomethoxypyridin 51933-73-4 C7H9NS
    3-Methyl-2-thiomethoxypyridin
    —— 2-(4-methylamino-5-amino-6-pyrimidinylmercapto)-3-hydroxy-5,5-dimethylcyclohexen-2-one 75398-62-8 C13H18N4O2S
    2-(4-methylamino-5-amino-6-pyrimidinylmercapto)-3-hydroxy-5,5-dimethylcyclohexen-2-one
    —— 2-(4-methylamino-5-amino-6-pyrimidinylmercapto)-3-methoxy-5,5-dimethylcyclohexen-2-one 75398-63-9 C14H20N4O2S
    2-(4-methylamino-5-amino-6-pyrimidinylmercapto)-3-methoxy-5,5-dimethylcyclohexen-2-one
    —— 4-Chloro-7,7-dimethyl-9-oxo-6,7,8,9-tetrahydropyrimido<4,5-b>(1,4)benzothiazine 72031-29-9 C12H12ClN3OS
    4-Chloro-7,7-dimethyl-9-oxo-6,7,8,9-tetrahydropyrimido<4,5-b>(1,4)benzothiazine
    —— 7,7-dimethyl-3,5,7,8-tetrahydro-6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazine-4,9-dione 72031-38-0 C12H13N3O2S
    7,7-dimethyl-3,5,7,8-tetrahydro-6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazine-4,9-dione
    —— 2-[4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-isoxazol-5-ylmethylsulfanyl]-pyridine 132611-26-8 C15H17N3O2S
    2-[4-(4,4-Dimethyl-4,5-dihydro-oxazol-2-yl)-3-methyl-isoxazol-5-ylmethylsulfanyl]-pyridine
    —— 4-dimethylamino-7,7-dimethyl-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one 72031-27-7 C14H18N4OS
    4-dimethylamino-7,7-dimethyl-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one
    —— Heptan-2-yl thiocyanate 906725-48-2 C8H15NS
    Heptan-2-yl thiocyanate
    —— 2-(2-Methyl-1,3-dithian-2-yl)-3-buten-2-ol 62163-03-5 C9H16OS2
    2-(2-Methyl-1,3-dithian-2-yl)-3-buten-2-ol
    —— (E)-2-acetyl-3-methylthiothiophen oxime 74598-26-8 C7H9NOS2
    (E)-2-acetyl-3-methylthiothiophen oxime
    —— 4-(4-(3-(3,5-bis(trifluoromethyl)phenyl)thioureido)phenylthio)-N-methylpicolinamide 1417344-64-9 C22H16F6N4OS2
    4-(4-(3-(3,5-bis(trifluoromethyl)phenyl)thioureido)phenylthio)-N-methylpicolinamide
    —— 2-(phenylthio)-3-(trimethylsilyl)-1,3-butadiene 91312-41-3 C13H18SSi
    2-(phenylthio)-3-(trimethylsilyl)-1,3-butadiene
    —— Ethyl 2-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylacetate 13551-66-1 C9H13N3O4S
    Ethyl 2-(2,5-dimethyl-4-nitropyrazol-3-yl)sulfanylacetate
    —— 2-phenylthio-3-trimethylstannyl-1,3-butadiene 91312-30-0 C13H18SSn
    2-phenylthio-3-trimethylstannyl-1,3-butadiene
    —— 1-Methyl-5-[4,4-ethylenedioxy-4-(4-ethylphenyl)butyl]thio-1,2,3,4-tetrazole 80087-34-9 C16H22N4O2S
    1-Methyl-5-[4,4-ethylenedioxy-4-(4-ethylphenyl)butyl]thio-1,2,3,4-tetrazole
    —— 9-(3-(isopropylamino)propyl)-8-(6-(thiazol-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine 1289544-83-7 C21H23N7O2S2
    9-(3-(isopropylamino)propyl)-8-(6-(thiazol-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine
    —— 1-Methyl-5-[4,4-ethylenedioxy-4-(2-pyridyl)butyl]thio-1,2,3,4-tetrazole 80087-44-1 C13H17N5O2S
    1-Methyl-5-[4,4-ethylenedioxy-4-(2-pyridyl)butyl]thio-1,2,3,4-tetrazole
    —— [(RS)-1-amino-3-(phenylsulfanyl)propyl]phosphonic acid 1367824-41-6 C9H14NO3PS
    [(RS)-1-amino-3-(phenylsulfanyl)propyl]phosphonic acid
    —— (1S,2S,3S,4S,5S,6S)-2-Hydroxymethyl-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane 121388-51-0 C15H19NO4S
    (1S,2S,3S,4S,5S,6S)-2-Hydroxymethyl-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane
    —— diethyl N-<5-(2-methylthio)thiazolyl>aminomethylenemalonate 91478-69-2 C12H16N2O4S2
    diethyl N-<5-(2-methylthio)thiazolyl>aminomethylenemalonate
    —— 2,4-Bis(butylsulfanyl)-6-methylpyrimidine 55749-49-0 C13H22N2S2
    2,4-Bis(butylsulfanyl)-6-methylpyrimidine
    —— diethyl ({[4-(methylthio)phenyl]amino}methylidene) propanedioate 16553-17-6 C15H19NO4S
    diethyl ({[4-(methylthio)phenyl]amino}methylidene) propanedioate
    —— (2S,5S)-methyl 2-{(3aS,4S,6R,6aS)-6-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl}-5-methoxy-3-[2-(phenylthio)ethyl]isoxazolidine-5-carboxylate 1171098-26-2 C26H37NO9S
    (2S,5S)-methyl 2-{(3aS,4S,6R,6aS)-6-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl}-5-methoxy-3-[2-(phenylthio)ethyl]isoxazolidine-5-carboxylate
    —— 7-[(4-Methylphenyl)sulfanyl]-4-nitro-1-oxo-2,1lambda~5~,3-benzoxadiazole 53619-47-9 C13H9N3O4S
    7-[(4-Methylphenyl)sulfanyl]-4-nitro-1-oxo-2,1lambda~5~,3-benzoxadiazole