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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <2-<(2,3,5,6-tetrachlorophenyl)thio>phenyl>acetic acid 86335-31-1 C14H8Cl4O2S
    <2-<(2,3,5,6-tetrachlorophenyl)thio>phenyl>acetic acid
    —— 2-(2-chloro-4-nitrophenylsulfanyl)-1-ethyl-4,5-dimethyl-1H-imidazole 1125455-50-6 C13H14ClN3O2S
    2-(2-chloro-4-nitrophenylsulfanyl)-1-ethyl-4,5-dimethyl-1H-imidazole
    —— 1-ethoxy-1-methylsulfanyl-ethane 117583-94-5 C5H12OS
    1-ethoxy-1-methylsulfanyl-ethane
    —— methyl 4-phenylthiopent-2-enoate 88087-84-7 C12H14O2S
    methyl 4-phenylthiopent-2-enoate
    —— 2-Imidazol-1-yl-1-(4-propylsulfanyl-phenyl)-ethanol 73973-70-3 C14H18N2OS
    2-Imidazol-1-yl-1-(4-propylsulfanyl-phenyl)-ethanol
    —— 2-Imidazol-1-yl-1-(2-phenylsulfanyl-phenyl)-ethanol 73932-27-1 C17H16N2OS
    2-Imidazol-1-yl-1-(2-phenylsulfanyl-phenyl)-ethanol
    —— methyl 5-(phenylthio)tetronate 108932-52-1 C11H10O3S
    methyl 5-(phenylthio)tetronate
    —— 4-(2-nitro phenylthio)benzyl alcohol 126585-10-2 C13H11NO3S
    4-(2-nitro phenylthio)benzyl alcohol
    —— 4-(2-nitro phenylthio)benzaldehyde 126585-08-8 C13H9NO3S
    4-(2-nitro phenylthio)benzaldehyde
    —— Pent-1-ene-1-thione 131136-77-1 C5H8S
    Pent-1-ene-1-thione
    —— 1-(4-Butylsulfanyl-phenyl)-2-imidazol-1-yl-ethanol 73973-72-5 C15H20N2OS
    1-(4-Butylsulfanyl-phenyl)-2-imidazol-1-yl-ethanol
    —— 4,6-Diamino-2-methylmercapto-thioformamido-pyrimidin 98197-66-1 C6H9N5S2
    4,6-Diamino-2-methylmercapto-thioformamido-pyrimidin
    —— 1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-lyxo-furanosyl>uracil 134357-13-4 C15H14N2O4S
    1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-lyxo-furanosyl>uracil
    —— 7-amino-5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidine 6306-87-2 C5H5N5S2
    7-amino-5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidine
    —— 3-(3-(3-(thien-2-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)pyridine 165116-44-9 C14H13N3S3
    3-(3-(3-(thien-2-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)pyridine
    —— 2-hydroxy-2-methyl-4-(phenylthio)octan-3-one 131864-16-9 C15H22O2S
    2-hydroxy-2-methyl-4-(phenylthio)octan-3-one
    —— 2-Aethylmercapto-4-hydrazino-6-methyl-pyrimidin 89852-74-4 C7H12N4S
    2-Aethylmercapto-4-hydrazino-6-methyl-pyrimidin
    —— 6-[(4'-chlorophenyl)-thio]-3-methylphenyl acetic acid 54506-87-5 C15H13ClO2S
    6-[(4'-chlorophenyl)-thio]-3-methylphenyl acetic acid
    —— 1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-arabino-furanosyl>uracil 134304-05-5 C15H14N2O4S
    1-<3'-deoxy-3'-phenylthio-2,2'-O-anhydro-β-D-arabino-furanosyl>uracil
    —— 4-hydroxyphenyl 2-(tetrahydropyran-2-yloxy)ethyl sulfide 114568-47-7 C13H18O3S
    4-hydroxyphenyl 2-(tetrahydropyran-2-yloxy)ethyl sulfide
    —— 2-ethoxyethyl 4-hydroxyphenyl sulfide 17178-13-1 C10H14O2S
    2-ethoxyethyl 4-hydroxyphenyl sulfide
    —— tert-butyl 5-amino-2-(ethylthio)benzyl(methyl)carbamate 943740-52-1 C15H24N2O2S
    tert-butyl 5-amino-2-(ethylthio)benzyl(methyl)carbamate
    —— 2-(2-(methylthio)phenyl)pyrimidine 1219699-60-1 C11H10N2S
    2-(2-(methylthio)phenyl)pyrimidine
    —— (1S,3R,8R,10S,12R,14R,15S,17R,19R)-15-[tert-butyl(dimethyl)silyl]oxy-17-[3-[tert-butyl(diphenyl)silyl]oxypropyl]-7,7-bis(ethylsulfanyl)-10-methyl-2,9,13,18-tetraoxatetracyclo[10.8.0.03,10.014,19]icosane-8-carbaldehyde 205864-92-2 C47H74O7S2Si2
    (1S,3R,8R,10S,12R,14R,15S,17R,19R)-15-[tert-butyl(dimethyl)silyl]oxy-17-[3-[tert-butyl(diphenyl)silyl]oxypropyl]-7,7-bis(ethylsulfanyl)-10-methyl-2,9,13,18-tetraoxatetracyclo[10.8.0.03,10.014,19]icosane-8-carbaldehyde
    —— 2-(2,6-bis(phenylthio)phenyl)pyrimidine 1584673-53-9 C22H16N2S2
    2-(2,6-bis(phenylthio)phenyl)pyrimidine
    —— 2-(phenyl(p-tolylthio)methyl)cyclohex-2-enone 1198078-58-8 C20H20OS
    2-(phenyl(p-tolylthio)methyl)cyclohex-2-enone
    —— 2-((4-chlorophenylthio)(phenyl)methyl)cyclohex-2-enone 1198078-57-7 C19H17ClOS
    2-((4-chlorophenylthio)(phenyl)methyl)cyclohex-2-enone
    —— 2-Imidazol-1-yl-1-(4-methylsulfanyl-phenyl)-ethanol 73973-68-9 C12H14N2OS
    2-Imidazol-1-yl-1-(4-methylsulfanyl-phenyl)-ethanol
    —— 3-<(3-methoxypropyl)thio>pyrrole 89597-75-1 C8H13NOS
    3-<(3-methoxypropyl)thio>pyrrole
    —— 3-chloro-5-(4-methylpiperazino)-6,7-dihydro-5H-dibenzo<b,g>thiocin 74801-55-1 C20H23ClN2S
    3-chloro-5-(4-methylpiperazino)-6,7-dihydro-5H-dibenzo<b,g>thiocin
    —— N-[2-[6-methyl-5-(2-pyrrolidin-1-ylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide 1431866-15-7 C17H25N3OS2
    N-[2-[6-methyl-5-(2-pyrrolidin-1-ylethyl)thieno[2,3-c]pyrrol-4-yl]sulfanylethyl]acetamide
    —— 4-bromo-7-methyl-benzo[b]thiophen-3-one 845746-16-9 C9H7BrOS
    4-bromo-7-methyl-benzo[b]thiophen-3-one
    —— 2-Phenylsulfanyl-hexanoyl chloride 76785-58-5 C12H15ClOS
    2-Phenylsulfanyl-hexanoyl chloride
    —— 2-(methylsulfanyl)-4-(propan-2-ylamino)pyrimidine-5-carbaldehyde 321690-73-7 C9H13N3OS
    2-(methylsulfanyl)-4-(propan-2-ylamino)pyrimidine-5-carbaldehyde
    —— 4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde 851885-65-9 C9H13N3O2S
    4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde
    —— <i>N</i>',<i>N</i>'''-dimethyl-<i>N</i>,<i>N</i>''-hexanediyl-bis-thiourea 109868-83-9 C10H22N4S2
    <i>N</i>',<i>N</i>'''-dimethyl-<i>N</i>,<i>N</i>''-hexanediyl-bis-thiourea
    —— 2-methoxy-5-methylthio-3-mercaptothiophene 88234-97-3 C6H8OS3
    2-methoxy-5-methylthio-3-mercaptothiophene
    —— trimethylsulfoxonium iodide 75465-09-7 C3H9OS*I
    trimethylsulfoxonium iodide
    —— 1,4-Difluoro-2-(4-methoxyphenyl)sulfanylbenzene 1376608-67-1 C13H10F2OS
    1,4-Difluoro-2-(4-methoxyphenyl)sulfanylbenzene
    —— 1,4-Difluoro-2-(4-fluorophenyl)sulfanylbenzene 1376608-75-1 C12H7F3S
    1,4-Difluoro-2-(4-fluorophenyl)sulfanylbenzene
    —— 2-(2,5-Difluorophenyl)sulfanylnaphthalene 1376608-71-7 C16H10F2S
    2-(2,5-Difluorophenyl)sulfanylnaphthalene
    —— vinyl tridecafluorohexyl sulfide 680187-84-2 C8H3F13S
    vinyl tridecafluorohexyl sulfide
    —— (3S,4R)-4-acetoxymethyl-3-<(3ξ)-3-hydroxybutyl>cyclopentanone ethylene dithioacetal 106026-61-3 C14H24O3S2
    (3S,4R)-4-acetoxymethyl-3-<(3ξ)-3-hydroxybutyl>cyclopentanone ethylene dithioacetal
    —— 2-Imidazol-1-yl-1-(4-phenylsulfanyl-phenyl)-ethanol 73941-94-3 C17H16N2OS
    2-Imidazol-1-yl-1-(4-phenylsulfanyl-phenyl)-ethanol
    —— 1-(3-Ethoxy-propyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-58-8 C18H21N3O4S
    1-(3-Ethoxy-propyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— (2S)-hydroxy-3-(phenylthio)propanoic acid 83023-80-7 C9H10O3S
    (2S)-hydroxy-3-(phenylthio)propanoic acid
    —— 2-(tert-butyl-dimethylsilanyloxy)-3-phenylsulfanyl-propionic acid methyl ester 901265-30-3 C16H26O3SSi
    2-(tert-butyl-dimethylsilanyloxy)-3-phenylsulfanyl-propionic acid methyl ester
    —— 1-(3-Methoxy-propyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-57-7 C17H19N3O4S
    1-(3-Methoxy-propyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— (E)-1-chloro-2-(4-chlorobenzenesulfenyl)-3-methyl-butene-1 58866-58-3 C11H12Cl2S
    (E)-1-chloro-2-(4-chlorobenzenesulfenyl)-3-methyl-butene-1
    —— ((E)-2-Chloro-1-phenylsulfanyl-but-2-enyl)-phosphonic acid diethyl ester 87926-16-7 C14H20ClO3PS
    ((E)-2-Chloro-1-phenylsulfanyl-but-2-enyl)-phosphonic acid diethyl ester