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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Benzyl-3-methylsulfanyl-5-thiophen-3-yl-1,2,4-triazole 1012073-76-5 C14H13N3S2
    4-Benzyl-3-methylsulfanyl-5-thiophen-3-yl-1,2,4-triazole
    —— 6-[2-(1,3-dioxan-2-yl)ethyl]-2-phenylthio-2-cyclohexen-1-one 258514-10-2 C18H22O3S
    6-[2-(1,3-dioxan-2-yl)ethyl]-2-phenylthio-2-cyclohexen-1-one
    —— 4-Benzyl-3-methylsulfanyl-5-thiophen-2-yl-1,2,4-triazole 1012073-49-2 C14H13N3S2
    4-Benzyl-3-methylsulfanyl-5-thiophen-2-yl-1,2,4-triazole
    —— 3-Methylthio-5-n-propylthio-4-cyano-isothiazol 37572-29-5 C8H10N2S3
    3-Methylthio-5-n-propylthio-4-cyano-isothiazol
    —— 6-[2-(1,3-dioxan-2-yl)ethyl]-2,2-bisphenylthiocyclohexanone 258514-08-8 C24H28O3S2
    6-[2-(1,3-dioxan-2-yl)ethyl]-2,2-bisphenylthiocyclohexanone
    —— 2-Phenylthio-5-hydroxy-p-benzochinon 19346-86-2 C12H8O3S
    2-Phenylthio-5-hydroxy-p-benzochinon
    —— 1,5-Dimethyl-2,4,6,8-tetrathiaadamantane 17749-57-4 C8H12S4
    1,5-Dimethyl-2,4,6,8-tetrathiaadamantane
    —— 2,4,6,8-Tetrathiatricyclo[3.3.1.1(3,7)]decane, 1,10-dimethyl- 57289-11-9 C8H12S4
    2,4,6,8-Tetrathiatricyclo[3.3.1.1(3,7)]decane, 1,10-dimethyl-
    —— 5-methyl-2-oxo-3,5-dihydro-2H-thiopyrano[2,3-d][1,3]thiazole-6-carbaldehyde 1018038-51-1 C8H7NO2S2
    5-methyl-2-oxo-3,5-dihydro-2H-thiopyrano[2,3-d][1,3]thiazole-6-carbaldehyde
    —— 3,5-Bis-(methylthio)-4-bromisothiazol 37572-44-4 C5H6BrNS3
    3,5-Bis-(methylthio)-4-bromisothiazol
    —— 4-(4-chlorophenyl)-2-(isopropylthio)thiophene-3-carbonitrile 882280-89-9 C14H12ClNS2
    4-(4-chlorophenyl)-2-(isopropylthio)thiophene-3-carbonitrile
    —— 5-Brom-2-dimethylamino-4-methylthio-pyrimidin 60186-82-5 C7H10BrN3S
    5-Brom-2-dimethylamino-4-methylthio-pyrimidin
    —— 2-(4-Bromo-phenylsulfanylmethyl)-pyridine 1-oxide 83782-67-6 C12H10BrNOS
    2-(4-Bromo-phenylsulfanylmethyl)-pyridine 1-oxide
    —— 4,5-bis-ethylsulfanyl-2-phenyl-2<i>H</i>-pyridazin-3-one 10005-35-3 C14H16N2OS2
    4,5-bis-ethylsulfanyl-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— <i>S</i>-hexyl-isothiourea; <i>S</i>-hexyl-isothiuronium-chloride 61988-51-0 C7H16N2S*ClH
    <i>S</i>-hexyl-isothiourea; <i>S</i>-hexyl-isothiuronium-chloride
    —— (2-pyrimidinylthio)phenylacetic acid 87125-92-6 C12H10N2O2S
    (2-pyrimidinylthio)phenylacetic acid
    —— 3-trifluoromethyl-6-tert-butylbenzo-1,4-oxathian 136603-65-1 C13H15F3OS
    3-trifluoromethyl-6-tert-butylbenzo-1,4-oxathian
    —— 4-acetyl-2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one 90330-76-0 C13H10N4O2S
    4-acetyl-2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one
    —— (Z)-hex-3-ene-1,6-dithiol 901772-75-6 C6H12S2
    (Z)-hex-3-ene-1,6-dithiol
    —— 2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one 90330-80-6 C11H8N4OS
    2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one
    —— 1-(4-(phenylthio)-3-(trifluoromethyl)cyclohex-3-enyl)ethanone 1192362-52-9 C15H15F3OS
    1-(4-(phenylthio)-3-(trifluoromethyl)cyclohex-3-enyl)ethanone
    —— 1-(3-(phenylthio)-4-(trifluoromethyl)cyclohex-3-enyl)ethanone 1192362-53-0 C15H15F3OS
    1-(3-(phenylthio)-4-(trifluoromethyl)cyclohex-3-enyl)ethanone
    —— 2-Ethyl-2,4-dimethyl-1,3-dithiolan 118633-23-1 C7H14S2
    2-Ethyl-2,4-dimethyl-1,3-dithiolan
    —— 2,4-dimethyl-2-phenyl-[1,3]dithiolane 100059-87-8 C11H14S2
    2,4-dimethyl-2-phenyl-[1,3]dithiolane
    —— 2-ethyl-5,6-dihydro-3,5-dimethyl-1,4-dithiin 61947-18-0 C8H14S2
    2-ethyl-5,6-dihydro-3,5-dimethyl-1,4-dithiin
    —— 2,4-dimethyl-2-propyl-[1,3]dithiolane 98561-12-7 C8H16S2
    2,4-dimethyl-2-propyl-[1,3]dithiolane
    —— 2,3-dihydro-2,5-dimethyl-1,4-dithiin 61947-19-1 C6H10S2
    2,3-dihydro-2,5-dimethyl-1,4-dithiin
    —— 1,2-bis(methylthio)propane 67560-48-9 C5H12S2
    1,2-bis(methylthio)propane
    —— 2,3-dihydro-2,6-dimethyl-1,4-dithiin 61947-20-4 C6H10S2
    2,3-dihydro-2,6-dimethyl-1,4-dithiin
    —— 2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin 61947-22-6 C7H12S2
    2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin
    —— 2-ethyl-5,6-dihydro-5-methyl-1,4-dithiin 61947-21-5 C7H12S2
    2-ethyl-5,6-dihydro-5-methyl-1,4-dithiin
    —— 2,9-dimercapto-3,5,8-trimethyl-4,7-dithia-decane 78010-95-4 C11H24S4
    2,9-dimercapto-3,5,8-trimethyl-4,7-dithia-decane
    —— 2,2'-dimethoxy-6,4'-bis-methylsulfanyl-[4,5']bipyrimidinyl 59549-55-2 C12H14N4O2S2
    2,2'-dimethoxy-6,4'-bis-methylsulfanyl-[4,5']bipyrimidinyl
    —— 6-phenylsulfanyl-[1,2,4]triazolo[4,3-<i>b</i>]pyridazine 99974-48-8 C11H8N4S
    6-phenylsulfanyl-[1,2,4]triazolo[4,3-<i>b</i>]pyridazine
    —— 4-Nitro-3',4',5'-trimethoxydiphenylsulfide 24891-42-7 C15H15NO5S
    4-Nitro-3',4',5'-trimethoxydiphenylsulfide
    —— 1-{[4-(Bromomethyl)phenyl]thio}-2-nitro-4-(trifluoromethyl)benzene 650615-78-4 C14H9BrF3NO2S
    1-{[4-(Bromomethyl)phenyl]thio}-2-nitro-4-(trifluoromethyl)benzene
    —— 2-acetoxymethyl-2,3-dihydrobenzothiophene 99338-94-0 C11H12O2S
    2-acetoxymethyl-2,3-dihydrobenzothiophene
    —— methylenedithiotetrathiafulvalene 118148-29-1 C7H4S6
    methylenedithiotetrathiafulvalene
    —— 3,4,5-tris(methylsulfanyl)-1,2-dithiolium iodide 82504-66-3 C6H9S5*I
    3,4,5-tris(methylsulfanyl)-1,2-dithiolium iodide
    —— (R)-(-)-2-methylbutyl phenyl sulfide 87106-26-1 C11H16S
    (R)-(-)-2-methylbutyl phenyl sulfide
    —— 1-(pentafluorophenylsulfanyl)hex-5-en-2-one 165531-79-3 C12H9F5OS
    1-(pentafluorophenylsulfanyl)hex-5-en-2-one
    —— 2,4-Dihydroxy-6-(2-naphthylthio)chinazolin 52979-05-2 C18H12N2O2S
    2,4-Dihydroxy-6-(2-naphthylthio)chinazolin
    —— Ethyl 2-amino-5-[2-naphthylthio]benzoate 52979-20-1 C19H17NO2S
    Ethyl 2-amino-5-[2-naphthylthio]benzoate
    —— 1-Chloro-3-(pyridin-4-ylthio)propane 134186-64-4 C8H10ClNS
    1-Chloro-3-(pyridin-4-ylthio)propane
    —— 4,5,6,4',5',6'-Hexamethyl-5H,5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene] 183479-89-2 C16H18N2S4
    4,5,6,4',5',6'-Hexamethyl-5H,5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]
    —— S-Ethyl-N,N'-dimethylisothioharnstoff —— C5H12N2S
    S-Ethyl-N,N'-dimethylisothioharnstoff
    —— 2,4-Dioxo-3-phenyl-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-66-6 C18H14N2O3S
    2,4-Dioxo-3-phenyl-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 4-(2-chloropyridin-4-ylthio)naphthalen-1-amine 1338815-51-2 C15H11ClN2S
    4-(2-chloropyridin-4-ylthio)naphthalen-1-amine
    —— 2,4-Dioxo-3-phenyl-6-phenylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-64-4 C17H12N2O3S
    2,4-Dioxo-3-phenyl-6-phenylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 6-(4-Chloro-phenylsulfanyl)-2,4-dioxo-3-phenyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-65-5 C17H11ClN2O3S
    6-(4-Chloro-phenylsulfanyl)-2,4-dioxo-3-phenyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde