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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-methoxymethyl-2-phenylthioindole-3-carbaldehyde 145235-94-5 C17H15NO2S
    1-methoxymethyl-2-phenylthioindole-3-carbaldehyde
    —— 5-hydroxy-4-(4'-methoxyphenylthio)-6-(2-propenyl)-1,3-benzodioxole 316800-32-5 C17H16O4S
    5-hydroxy-4-(4'-methoxyphenylthio)-6-(2-propenyl)-1,3-benzodioxole
    —— 5-methoxy-4-phenylthio-6-(2-propenyl)-1,3-benzodioxole 316800-34-7 C17H16O3S
    5-methoxy-4-phenylthio-6-(2-propenyl)-1,3-benzodioxole
    —— 5-methoxy-4-(4'-methoxyphenylthio)-6-(2-propenyl)-1,3-benzodioxole 316800-35-8 C18H18O4S
    5-methoxy-4-(4'-methoxyphenylthio)-6-(2-propenyl)-1,3-benzodioxole
    —— 5-allyloxy-4-(4'-methoxyphenylthio)-1,3-benzodioxole 316800-26-7 C17H16O4S
    5-allyloxy-4-(4'-methoxyphenylthio)-1,3-benzodioxole
    —— 5-hydroxy-4-(4'-methoxyphenylthio)-1,3-benzodioxole 316800-22-3 C14H12O4S
    5-hydroxy-4-(4'-methoxyphenylthio)-1,3-benzodioxole
    —— 5-hydroxy-4-phenylthio-1,3-benzodioxole 316800-21-2 C13H10O3S
    5-hydroxy-4-phenylthio-1,3-benzodioxole
    —— 4-[(2-bromo-N,4-dimethylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one 1205745-52-3 C18H18BrNO2S
    4-[(2-bromo-N,4-dimethylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one
    —— Bis-(N,N-dimethyl-methylamin)-sulfid 5695-39-6 C6H16N2S
    Bis-(N,N-dimethyl-methylamin)-sulfid
    —— 4-(phenylthio)-3,4-dihydro-2H-pyran 959682-63-4 C11H12OS
    4-(phenylthio)-3,4-dihydro-2H-pyran
    —— 6-amino-2-(benzylthio)-3-isobutylpyrimidin-4(3H)-one 1620909-79-6 C15H19N3OS
    6-amino-2-(benzylthio)-3-isobutylpyrimidin-4(3H)-one
    —— 4-[(2,6-difluorophenyl)methyl]-2-isobutylsulfanyl-1H-pyrimidin-6-one 221122-04-9 C15H16F2N2OS
    4-[(2,6-difluorophenyl)methyl]-2-isobutylsulfanyl-1H-pyrimidin-6-one
    —— 2-(benzylthio)-6-isobutoxypyrimidin-4-amine 1620909-67-2 C15H19N3OS
    2-(benzylthio)-6-isobutoxypyrimidin-4-amine
    —— methyl (E)-2-methyl-3-(phenylthio)-2-propenoate 71847-74-0 C11H12O2S
    methyl (E)-2-methyl-3-(phenylthio)-2-propenoate
    —— 2-Ethoxymethyl-4-(4-fluorophenyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-2H-isoxazol-5-one 476313-99-2 C17H16FN3O3S
    2-Ethoxymethyl-4-(4-fluorophenyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-2H-isoxazol-5-one
    —— 4-(4-fluorophenyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-2H-isoxazol-5-one 476313-98-1 C14H10FN3O2S
    4-(4-fluorophenyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-2H-isoxazol-5-one
    —— 1-hydroxy-3-methylthiourea 25684-18-8 C2H6N2OS
    1-hydroxy-3-methylthiourea
    —— dimethyl-dithiocarbamic acid butoxymethyl ester 66229-40-1 C8H17NOS2
    dimethyl-dithiocarbamic acid butoxymethyl ester
    —— bis(2-nitro-4,5-dicyanophenyl)sulfide 357617-32-4 C16H4N6O4S
    bis(2-nitro-4,5-dicyanophenyl)sulfide
    —— 2,2'-di(methylsulfonyl)diethyl ether 16523-03-8 C6H14O5S2
    2,2'-di(methylsulfonyl)diethyl ether
    —— methyl-(1,2,2,2-tetrachloro-ethyl)-sulfide 741258-61-7 C3H4Cl4S
    methyl-(1,2,2,2-tetrachloro-ethyl)-sulfide
    —— N-methyl-N-({3-[4-(methylsulfanyl)benzyl]-4-pyridinyl}methyl)amine 662150-40-5 C15H18N2S
    N-methyl-N-({3-[4-(methylsulfanyl)benzyl]-4-pyridinyl}methyl)amine
    —— 1-imino-3-methoxy-λ<sup>6</sup>-thietane 1-oxide 1609964-34-2 C4H9NO2S
    1-imino-3-methoxy-λ<sup>6</sup>-thietane 1-oxide
    —— 4-Hydroxy-2-(1-phenylsulfanylpropan-2-yl)-5-(2,4,6-trimethylphenyl)-2,3-dihydropyran-6-one 1612830-39-3 C23H26O3S
    4-Hydroxy-2-(1-phenylsulfanylpropan-2-yl)-5-(2,4,6-trimethylphenyl)-2,3-dihydropyran-6-one
    —— 4,6-dichloro-5-(piperidin-1-yl)-2-(methylthio)pyrimidine 1137576-72-7 C10H13Cl2N3S
    4,6-dichloro-5-(piperidin-1-yl)-2-(methylthio)pyrimidine
    —— 1-(2,2-Difluoro-2-methylsulfanylethyl)adamantane 1028315-33-4 C13H20F2S
    1-(2,2-Difluoro-2-methylsulfanylethyl)adamantane
    —— (4S)-4-Benzyl-3-{(2R)-2-[2-(2-methyl-1,3-dithian-2-YL)ethyl]-3-oxopentanoyl}-1,3-oxazolidin-2-one 287717-25-3 C22H29NO4S2
    (4S)-4-Benzyl-3-{(2R)-2-[2-(2-methyl-1,3-dithian-2-YL)ethyl]-3-oxopentanoyl}-1,3-oxazolidin-2-one
    —— (4S)-4-benzyl-3-[4-(2-methyl-1,3-dithian-2-yl)butanoyl]-1,3-oxazolidin-2-one 287717-24-2 C19H25NO3S2
    (4S)-4-benzyl-3-[4-(2-methyl-1,3-dithian-2-yl)butanoyl]-1,3-oxazolidin-2-one
    —— Methyl 2-(1-adamantyl)ethanedithioate 178100-67-9 C13H20S2
    Methyl 2-(1-adamantyl)ethanedithioate
    —— [2,2-bis(phenylthio)ethyl]dimethyl(1-phenylbut-3-enyloxy)silane 332188-09-7 C26H30OS2Si
    [2,2-bis(phenylthio)ethyl]dimethyl(1-phenylbut-3-enyloxy)silane
    —— 2-ethylthio-2-hexen-4-yne-1,6-diol 77922-14-6 C8H12O2S
    2-ethylthio-2-hexen-4-yne-1,6-diol
    —— 2-<<(p-bromophenyl)thio>methyl>-3-methylpyridine 83782-46-1 C13H12BrNS
    2-<<(p-bromophenyl)thio>methyl>-3-methylpyridine
    —— 2-ethylthioimidazole 7565-39-1 C5H8N2S
    2-ethylthioimidazole
    —— 4-(2-fluoropyridin-3-yl)-5-[(2-methylfuran-3-yl)thio]thiophene-2-carbaldehyde 1138034-28-2 C15H10FNO2S2
    4-(2-fluoropyridin-3-yl)-5-[(2-methylfuran-3-yl)thio]thiophene-2-carbaldehyde
    —— 3-nitro-6-phenylsulfanyl-pyridin-2-ylamine 73896-35-2 C11H9N3O2S
    3-nitro-6-phenylsulfanyl-pyridin-2-ylamine
    —— Sulfonyl butane 79458-34-7 C4H8O2S
    Sulfonyl butane
    —— 4-Hydroxy-5-methyl-5-phenylsulfanylhexanamide 852806-87-2 C13H19NO2S
    4-Hydroxy-5-methyl-5-phenylsulfanylhexanamide
    —— Δ<sup>1(6)</sup>-2,5-dithiabicyclo<4.3.0>nonene 35756-14-0 C7H10S2
    Δ<sup>1(6)</sup>-2,5-dithiabicyclo<4.3.0>nonene
    —— 6,6-Dimethyl-5-phenylsulfanylpiperidin-2-one 852806-89-4 C13H17NOS
    6,6-Dimethyl-5-phenylsulfanylpiperidin-2-one
    —— 1-allyl-2-(o-bromophenylsulfenyl)-4-pentenenitrile 280557-84-8 C14H14BrNS
    1-allyl-2-(o-bromophenylsulfenyl)-4-pentenenitrile
    —— 2,2-Dimethyl-3-phenylsulfanylpiperidine 852898-82-9 C13H19NS
    2,2-Dimethyl-3-phenylsulfanylpiperidine
    —— 2-chloro-6-methylphenyl 1-neopentyl-2-tert-butyl-4-nitro-5-imidazolyl sulfide 135217-03-7 C19H26ClN3O2S
    2-chloro-6-methylphenyl 1-neopentyl-2-tert-butyl-4-nitro-5-imidazolyl sulfide
    —— 1-(methylsulfonyl)propan-2-ol 1977-38-4 C4H10O3S
    1-(methylsulfonyl)propan-2-ol
    —— 1-Methyl-4-nitro-5-imidazolyl 2-acetamidophenyl sulfide 53900-33-7 C12H12N4O3S
    1-Methyl-4-nitro-5-imidazolyl 2-acetamidophenyl sulfide
    —— 1-Methyl-4-nitro-5-imidazolyl 3-Succinamidophenyl Sulfide 108655-39-6 C14H14N4O5S
    1-Methyl-4-nitro-5-imidazolyl 3-Succinamidophenyl Sulfide
    —— 1-Methyl-4-nitro-5-imidazolyl 2-Succinamidophenyl Sulfide 108655-38-5 C14H14N4O5S
    1-Methyl-4-nitro-5-imidazolyl 2-Succinamidophenyl Sulfide
    —— 2-propionylamino-5-(4-nitrophenylthio)thiazole 133691-56-2 C12H11N3O3S2
    2-propionylamino-5-(4-nitrophenylthio)thiazole
    —— 2-(o-bromophenylsulfenyl)-5-methyl-2-(methyl-2-butenyl)-4-hexenenitrile 280557-86-0 C18H22BrNS
    2-(o-bromophenylsulfenyl)-5-methyl-2-(methyl-2-butenyl)-4-hexenenitrile
    —— 7-butyl-2,7-diazaphenothiazine 1261268-70-5 C14H15N3S
    7-butyl-2,7-diazaphenothiazine
    —— 2-(o-bromophenylsulfenyl)-5-methylhexenenitrile 280557-78-0 C13H14BrNS
    2-(o-bromophenylsulfenyl)-5-methylhexenenitrile