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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Methyl-4-(methylthio)-6-(tributylstannyl)pyrimidine 1253568-64-7 C18H34N2SSn
    2-Methyl-4-(methylthio)-6-(tributylstannyl)pyrimidine
    —— 4-(3,5-dichlorophenylthio)-3-aminobenzonitrile 1253499-73-8 C13H8Cl2N2S
    4-(3,5-dichlorophenylthio)-3-aminobenzonitrile
    —— 3-Methyl-2-(methylsulfanyl)furan 143454-54-0 C6H8OS
    3-Methyl-2-(methylsulfanyl)furan
    —— N-[6-methoxy-2-[(2-phenylethyl)thio]pyrimidin-4-yl]azetidine-1-sulfonamide 878387-62-3 C16H20N4O3S2
    N-[6-methoxy-2-[(2-phenylethyl)thio]pyrimidin-4-yl]azetidine-1-sulfonamide
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-(4-methylpiperazin-1-yl)piperidine-1-sulfonamide 878388-25-1 C22H30F2N6O3S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-(4-methylpiperazin-1-yl)piperidine-1-sulfonamide
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-(ethylamino)piperidine-1-sulfonamide 878388-28-4 C19H25F2N5O3S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-(ethylamino)piperidine-1-sulfonamide
    —— 3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-azetidine-1-sulfonamide 878387-78-1 C15H17F2N5O3S2
    3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-azetidine-1-sulfonamide
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-hydroxypiperidine-1-sulfonamide 878388-26-2 C17H20F2N4O4S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-4-hydroxypiperidine-1-sulfonamide
    —— (3R)-3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}pyrrolidine-1-sulfonamide 878387-54-3 C16H19F2N5O3S2
    (3R)-3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}pyrrolidine-1-sulfonamide
    —— N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-1,4-diazepane-1-sulfonamide 878387-75-8 C17H21F2N5O3S2
    N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}-1,4-diazepane-1-sulfonamide
    —— (3S)-3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}pyrrolidine-1-sulfonamide 878387-51-0 C16H19F2N5O3S2
    (3S)-3-amino-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}pyrrolidine-1-sulfonamide
    —— 4-azetidin-1-yl-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}piperidine-1-sulfonamide 878388-27-3 C20H25F2N5O3S2
    4-azetidin-1-yl-N-{2-[(2,3-difluorobenzyl)thio]-6-methoxypyrimidin-4-yl}piperidine-1-sulfonamide
    —— (Z)-N-methoxy-N-methyl-2-phenylsulfanylnon-6-enamide 1235328-49-0 C17H25NO2S
    (Z)-N-methoxy-N-methyl-2-phenylsulfanylnon-6-enamide
    —— (2S)-1-(4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidin-1-yl)-1-oxopropan-2-ol 1156467-73-0 C20H21BrN6O4S
    (2S)-1-(4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidin-1-yl)-1-oxopropan-2-ol
    —— methyl-[[4-[[[(1S)-1-pyridin-3-ylethoxy]carbonylamino]methyl]pyridin-2-yl]sulfanylmethyl]phosphinic acid 1108150-85-1 C16H20N3O4PS
    methyl-[[4-[[[(1S)-1-pyridin-3-ylethoxy]carbonylamino]methyl]pyridin-2-yl]sulfanylmethyl]phosphinic acid
    —— 2-{[(3,5-dichloropyridin-4-yl)methyl]sulfanyI}-6-methylpyrimidin-4-amine 1256558-75-4 C11H10Cl2N4S
    2-{[(3,5-dichloropyridin-4-yl)methyl]sulfanyI}-6-methylpyrimidin-4-amine
    —— N,N-dihexyl-3,5-dihydroxy-6-{2-[2-(4-hydroxyphenyl)-ethyl]-[1,3]-dithian-2-yl}hexanamide 1051966-67-6 C30H51NO4S2
    N,N-dihexyl-3,5-dihydroxy-6-{2-[2-(4-hydroxyphenyl)-ethyl]-[1,3]-dithian-2-yl}hexanamide
    —— [4-(2,5-dimethyl-2H-pyrazol-3-ylamino)-2-methylsulfanyl-pyrimidin-5-yl]-methanol 1001129-04-9 C11H15N5OS
    [4-(2,5-dimethyl-2H-pyrazol-3-ylamino)-2-methylsulfanyl-pyrimidin-5-yl]-methanol
    —— tert-butyl N-[cyclohexyl-(5-formyl-2-methylsulfanylpyrimidin-4-yl)amino]carbamate 900502-64-9 C17H26N4O3S
    tert-butyl N-[cyclohexyl-(5-formyl-2-methylsulfanylpyrimidin-4-yl)amino]carbamate
    —— tert-butyl N-[cyclohexyl-[5-(hydroxymethyl)-2-methylsulfanylpyrimidin-4-yl]amino]carbamate 900502-63-8 C17H28N4O3S
    tert-butyl N-[cyclohexyl-[5-(hydroxymethyl)-2-methylsulfanylpyrimidin-4-yl]amino]carbamate
    —— 5-methyl-2-phenylsulfanyl-1H-imidazole 788150-02-7 C10H10N2S
    5-methyl-2-phenylsulfanyl-1H-imidazole
    —— 4-((R)-2-hydroxy-propylamino)-2-methylsulfanyl pyrimidine-5-methanol 851885-64-8 C9H15N3O2S
    4-((R)-2-hydroxy-propylamino)-2-methylsulfanyl pyrimidine-5-methanol
    —— 4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl pyrimidine-5-methanol 851885-69-3 C9H15N3O2S
    4-((S)-2-hydroxy-propylamino)-2-methylsulfanyl pyrimidine-5-methanol
    —— 1,3-Diaminopropane-2-thiol 97231-26-0 C3H10N2S
    1,3-Diaminopropane-2-thiol
    —— 1H,1H,2H,2H-3-trifluoromethylperfluoro-1-butanethiol 1006627-78-6 C5H5F7S
    1H,1H,2H,2H-3-trifluoromethylperfluoro-1-butanethiol
    —— Tributyl-(3-methylsulfanyl-1,2,4-triazin-6-yl)stannane 446287-47-4 C16H31N3SSn
    Tributyl-(3-methylsulfanyl-1,2,4-triazin-6-yl)stannane
    —— Cyclohexanemethanamine, 4-ethyl-1-[2-(ethylsulfonyl)ethyl]- 1480538-27-9 C13H27NO2S
    Cyclohexanemethanamine, 4-ethyl-1-[2-(ethylsulfonyl)ethyl]-
    —— (4S,5R)-4-(fluoromethyl)-5-{4-[(fluoromethyl)thio]phenyl}-2-phenyl-4,5-dihydro-1,3-oxazole 859520-23-3 C17H15F2NOS
    (4S,5R)-4-(fluoromethyl)-5-{4-[(fluoromethyl)thio]phenyl}-2-phenyl-4,5-dihydro-1,3-oxazole
    —— 2-methyl-2-(propane-2-sulfonyl)-propionic acid 1017539-77-3 C7H14O4S
    2-methyl-2-(propane-2-sulfonyl)-propionic acid
    —— 2-Methylbutane-1,3-dithiol 54812-83-8 C5H12S2
    2-Methylbutane-1,3-dithiol
    —— methyl 2-(m-tolylthio)acetate 190005-34-6 C10H12O2S
    methyl 2-(m-tolylthio)acetate
    —— 8-methyl-5-methylsulfanyl-1,3-diphenyl-1H,8H-pyrimido[4,5-d]pyrimidine-2,4,7-trione 871699-92-2 C20H16N4O3S
    8-methyl-5-methylsulfanyl-1,3-diphenyl-1H,8H-pyrimido[4,5-d]pyrimidine-2,4,7-trione
    —— <i>S</i>-deuterio-ethynethiol 76596-41-3 C2H2S
    <i>S</i>-deuterio-ethynethiol
    —— 1-(2,4-difluoro-benzyl)-6-[5-(6-methylsulfanyl-pyridin-3-yl)-thiophen-2-yl]-2-oxo-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile 849934-68-5 C24H14F5N3OS2
    1-(2,4-difluoro-benzyl)-6-[5-(6-methylsulfanyl-pyridin-3-yl)-thiophen-2-yl]-2-oxo-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile
    —— (2S)-2-[(S)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine 668470-64-2 C19H23NOS
    (2S)-2-[(S)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine
    —— (2S)-2-((S)-phenyl{[2-(trifluoromethyl)phenyl]thio}methyl)morpholine 668470-57-3 C18H21NOS2
    (2S)-2-((S)-phenyl{[2-(trifluoromethyl)phenyl]thio}methyl)morpholine
    —— (2S)-2-[(S)-[(2-fluorophenyl)thio](phenyl)methyl]morpholine 668470-63-1 C17H18FNOS
    (2S)-2-[(S)-[(2-fluorophenyl)thio](phenyl)methyl]morpholine
    —— 2-{4-[2-bromo-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol 869854-06-8 C13H8BrF6NOS2
    2-{4-[2-bromo-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol
    —— 4-bromomethyl-5-isopropylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole 878204-79-6 C9H12BrF3N2S
    4-bromomethyl-5-isopropylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole
    —— 2-{4-[2-amino-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol 869854-05-7 C13H10F6N2OS2
    2-{4-[2-amino-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol
    —— 2-(4-(2,4-dichlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-20-6 C12H8Cl2F3NOS2
    2-(4-(2,4-dichlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— S-4-(1,1,1-trifluoro-2-hydroxypropan-2-yl)phenyl dimethylcarbamothioate 869854-54-6 C12H14F3NO2S
    S-4-(1,1,1-trifluoro-2-hydroxypropan-2-yl)phenyl dimethylcarbamothioate
    —— 2-(4-(2-chlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-19-3 C12H9ClF3NOS2
    2-(4-(2-chlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— 3-chloro-4-[4-[(2S)-1,1,1-trifluoro-2-hydroxypropan-2-yl]phenyl]sulfanylbenzonitrile 869854-57-9 C16H11ClF3NOS
    3-chloro-4-[4-[(2S)-1,1,1-trifluoro-2-hydroxypropan-2-yl]phenyl]sulfanylbenzonitrile
    —— 2-{[4-(3-aminopropyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-36-2 C14H24N2O2S2
    2-{[4-(3-aminopropyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— 2-{[4-(2-aminoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-10-2 C13H22N2O2S2
    2-{[4-(2-aminoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— 5-[2-(2-benzyloxy-ethyl)-5-ethyl-3H-imidazol-4-ylsulfanyl]-3-chloro-benzonitrile 897626-27-6 C21H20ClN3OS
    5-[2-(2-benzyloxy-ethyl)-5-ethyl-3H-imidazol-4-ylsulfanyl]-3-chloro-benzonitrile
    —— (4S,5R)-4-methyl-5-[4-(methylthio)phenyl]-1,3-oxazolidin-2-one 1028459-38-2 C11H13NO2S
    (4S,5R)-4-methyl-5-[4-(methylthio)phenyl]-1,3-oxazolidin-2-one
    —— Cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanone 864301-12-2 C11H12Cl2N2OS
    Cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanone
    —— (2-chlorophenyl)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)-methanol 864300-82-3 C12H9Cl3N2OS
    (2-chlorophenyl)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)-methanol