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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(3-methoxyphenylthio)benzaldehyde 141358-18-1 C14H12O2S
    4-(3-methoxyphenylthio)benzaldehyde
    —— 3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole-1-carboxaldehyde 1285621-02-4 C16H13NO2S
    3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole-1-carboxaldehyde
    —— 1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole 1285621-08-0 C17H15NO2S
    1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2H-isoindole
    —— 4-(3-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline 1336930-72-3 C16H11Cl3N2OS
    4-(3-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline
    —— 1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2-methyl-2H-isoindole 1285621-16-0 C18H17NO2S
    1-acetyl-3-[(3-methoxyphenyl)sulfanyl]-2-methyl-2H-isoindole
    —— 7-chloro-7-(phenylsulfanyl)dispiro[2.0.2.1]heptane 642074-91-7 C13H13ClS
    7-chloro-7-(phenylsulfanyl)dispiro[2.0.2.1]heptane
    —— 6-(sec-butoxy)-2-((3-methoxyphenyl)thio)pyrimidin-4-amine 284681-52-3 C15H19N3O2S
    6-(sec-butoxy)-2-((3-methoxyphenyl)thio)pyrimidin-4-amine
    —— tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate 1138033-81-4 C22H24FN3O3S2
    tert-butyl ({4-(2-fluoropyridin-3-yl)-5-[(3-methoxyphenyl)thio]-1,3-thiazol-2-yl}methyl)methylcarbamate
    —— 4-(3-methoxy-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester 631909-77-8 C13H11NO5S2
    4-(3-methoxy-phenylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester
    —— (2,2-dimethyl-1,3-dithian-5-yl)methanol 1056901-08-6 C7H14OS2
    (2,2-dimethyl-1,3-dithian-5-yl)methanol
    —— 2-(4-tolylsulfanyl)-3-((phenyl)(4-tolylsulfanyl)methyl)-1H-indole 1295558-56-3 C29H25NS2
    2-(4-tolylsulfanyl)-3-((phenyl)(4-tolylsulfanyl)methyl)-1H-indole
    —— 2-phenylsulfanyl-3-((acetyl)(phenylsulfanyl)methyl)-1H-indole 1295558-75-6 C23H19NOS2
    2-phenylsulfanyl-3-((acetyl)(phenylsulfanyl)methyl)-1H-indole
    —— 2-phenylthiomethyl-2-imidazoline 65248-81-9 C10H12N2S
    2-phenylthiomethyl-2-imidazoline
    —— 5-fluoro-2-(methylthio)aniline 439291-60-8 C7H8FNS
    5-fluoro-2-(methylthio)aniline
    —— 2'-methylthio-5'-fluoro-2-(anilinomethyl)imidazoline 439291-61-9 C11H14FN3S
    2'-methylthio-5'-fluoro-2-(anilinomethyl)imidazoline
    —— 2-(3-chloro-2-methylphenyl-thiomethyl)-2-imidazoline hydrochloride 130016-17-0 C11H13ClN2S*ClH
    2-(3-chloro-2-methylphenyl-thiomethyl)-2-imidazoline hydrochloride
    —— 2-phenylsulfanyl-3-((phenyl)(phenylsulfanyl)methyl)-1H-indole 1295558-76-7 C27H21NS2
    2-phenylsulfanyl-3-((phenyl)(phenylsulfanyl)methyl)-1H-indole
    —— 3-((1H-tetrazol-5-yl)thio)-1H-indole 1569090-27-2 C9H7N5S
    3-((1H-tetrazol-5-yl)thio)-1H-indole
    —— spiro-(4H-1,3-benzodithiin-2,4'-piperidine) 136081-83-9 C12H15NS2
    spiro-(4H-1,3-benzodithiin-2,4'-piperidine)
    —— S-Methyl-N,S-diethyl-sulfoximid 35362-78-8 C5H13NOS
    S-Methyl-N,S-diethyl-sulfoximid
    —— N.S-Dimethyl-S-aethyl-sulfoximid 35362-74-4 C4H11NOS
    N.S-Dimethyl-S-aethyl-sulfoximid
    —— 4-chloro-2-(phenylthio)aniline 53692-01-6 C12H10ClNS
    4-chloro-2-(phenylthio)aniline
    —— <(1-Methylnon-2-ynyl)thio>benzene 146916-42-9 C16H22S
    <(1-Methylnon-2-ynyl)thio>benzene
    —— 2-Phenylthio-1,3-cyclohexanedione 72302-56-8 C12H12O2S
    2-Phenylthio-1,3-cyclohexanedione
    —— 4-fluoro-2-thiophenylaniline 329216-96-8 C12H10FNS
    4-fluoro-2-thiophenylaniline
    —— 4-(2-indolylthio)nicotinic acid 242491-44-7 C14H10N2O2S
    4-(2-indolylthio)nicotinic acid
    —— (-)-(7aS)-2,3,7,7a-Tetrahydro-7a-phenylthio-1H-indene-1,5(6H)-dione 127053-28-5 C15H14O2S
    (-)-(7aS)-2,3,7,7a-Tetrahydro-7a-phenylthio-1H-indene-1,5(6H)-dione
    —— (+/-)-2,3,7,7a-Tetrahydro-7a-phenylthio-1H-indene-1,5(6H)-dione 127053-28-5 C15H14O2S
    (+/-)-2,3,7,7a-Tetrahydro-7a-phenylthio-1H-indene-1,5(6H)-dione
    —— (2aS,3R,5aR,6R,8aR,8bR)-3,6-dimethyl-6-phenylsulfanylmethyl-2a-[2-(tetrahydropyran-2-yloxy)ethyl]decahydronaphtho[1,8-bc]furan-2-one 535932-79-7 C27H38O4S
    (2aS,3R,5aR,6R,8aR,8bR)-3,6-dimethyl-6-phenylsulfanylmethyl-2a-[2-(tetrahydropyran-2-yloxy)ethyl]decahydronaphtho[1,8-bc]furan-2-one
    —— (+)-(8aS)-3,4,8,8a-Tetrahydro-8a-phenylthio-1,6(2H,7H)-naphthalenedione 127053-29-6 C16H16O2S
    (+)-(8aS)-3,4,8,8a-Tetrahydro-8a-phenylthio-1,6(2H,7H)-naphthalenedione
    —— 2-(phenylthio)-1,3-cyclopentanedione 90036-83-2 C11H10O2S
    2-(phenylthio)-1,3-cyclopentanedione
    —— (2aS,3S,5aR,6R,8aR,8bR)-3,6-dimethyl-6-phenylsulfanylmethyl-2a-[2-(tetrahydropyran-2-yloxy)ethyl]decahydronaphtho[1,8-bc]furan-2-one 535932-73-1 C27H38O4S
    (2aS,3S,5aR,6R,8aR,8bR)-3,6-dimethyl-6-phenylsulfanylmethyl-2a-[2-(tetrahydropyran-2-yloxy)ethyl]decahydronaphtho[1,8-bc]furan-2-one
    —— dimethyl 2-pent-4-enyl-2-phenylsulfanylpropanedioate 196494-61-8 C16H20O4S
    dimethyl 2-pent-4-enyl-2-phenylsulfanylpropanedioate
    —— 2-isopropyl-2-phenyltio-1,3-cyclopentanedione 90036-76-3 C14H16O2S
    2-isopropyl-2-phenyltio-1,3-cyclopentanedione
    —— 5-bromo-1-(methyl-diphenyl-silyl)-2-phenyl-sulfenyl-1-hexanone 282733-21-5 C25H27BrOSSi
    5-bromo-1-(methyl-diphenyl-silyl)-2-phenyl-sulfenyl-1-hexanone
    —— 2-Phenylsulfanyl-1-trimethylsilylhexan-1-one 66132-86-3 C15H24OSSi
    2-Phenylsulfanyl-1-trimethylsilylhexan-1-one
    —— 5-bromo-4-methyl-1-(methyl-diphenyl-silyl)-2-phenyl-sulfenyl-1-pentanone 395664-13-8 C25H27BrOSSi
    5-bromo-4-methyl-1-(methyl-diphenyl-silyl)-2-phenyl-sulfenyl-1-pentanone
    —— 2-(2-phenylthio-1-naphthyl)pyridine 1609120-86-6 C21H15NS
    2-(2-phenylthio-1-naphthyl)pyridine
    —— 5-methyl-2-phenyl-5-phenylthiomethyl-4,5-dihydro-1,3-oxazole 113261-11-3 C17H17NOS
    5-methyl-2-phenyl-5-phenylthiomethyl-4,5-dihydro-1,3-oxazole
    —— ethyl 2-(ethylsulfonemethyl)acrylate 1156548-30-9 C8H14O4S
    ethyl 2-(ethylsulfonemethyl)acrylate
    —— 2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-1,3-oxazole 1337932-91-8 C20H18N2O4S
    2-[3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indol-2-yl]-1,3-oxazole
    —— 2-(furan-3-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole 1337932-86-1 C21H19NO4S
    2-(furan-3-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole
    —— 4-(2-nitro-1-phenylsulfanylethyl)phenol 110113-57-0 C14H13NO3S
    4-(2-nitro-1-phenylsulfanylethyl)phenol
    —— isopropyl S-3,6-diisopropylpyrazin-2-ylthiolcarbonate 104272-89-1 C14H22N2O2S
    isopropyl S-3,6-diisopropylpyrazin-2-ylthiolcarbonate
    —— 1H-Purin-6-amine, 2-((3-nitro-2-pyridiyl)thio)- 75477-68-8 C10H7N7O2S
    1H-Purin-6-amine, 2-((3-nitro-2-pyridiyl)thio)-
    —— N-(5-Bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyrimidin-2-yl-benzene-1,4-diamine 1034358-66-1 C15H13BrN6S
    N-(5-Bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyrimidin-2-yl-benzene-1,4-diamine
    —— methyl-thiocarbamic acid <i>S</i>-propyl ester 39076-37-4 C5H11NOS
    methyl-thiocarbamic acid <i>S</i>-propyl ester
    —— 4-(2-Amino-1-phenylsulfanylethyl)phenol 1027955-71-0 C14H15NOS
    4-(2-Amino-1-phenylsulfanylethyl)phenol
    —— ethyl-thiocarbamic acid <i>S</i>-butyl ester 39078-40-5 C7H15NOS
    ethyl-thiocarbamic acid <i>S</i>-butyl ester
    —— 2,4(1H,3H)-Pyrimidinedione, 1-((2-hydroxyethoxy)methyl)-5-iodo-6-(phenylthio)- 125056-92-0 C13H13IN2O4S
    2,4(1H,3H)-Pyrimidinedione, 1-((2-hydroxyethoxy)methyl)-5-iodo-6-(phenylthio)-