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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 8-(4-chlorophenylthio)-6-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine 1076691-36-5 C23H21ClN2S2
    8-(4-chlorophenylthio)-6-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine
    —— 5-[2-(4-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine 1172612-55-3 C14H12N2S
    5-[2-(4-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine
    —— 5-[2-(3-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine 1172612-54-2 C14H12N2S
    5-[2-(3-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine
    —— N-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]formamide 1185189-96-1 C16H17IN2O2S
    N-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]formamide
    —— 5-aminomethyl-4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-pyridin-2(1H)-one 1185189-94-9 C15H17IN2OS
    5-aminomethyl-4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile 1185189-92-7 C15H13IN2OS
    4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile
    —— 3-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-3H-imidazol-4-ylcarbonitrile 1185190-29-7 C20H19IN4OS
    3-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-3H-imidazol-4-ylcarbonitrile
    —— [(4R,6R)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl] butanoate 1202395-63-8 C12H16O2S2
    [(4R,6R)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl] butanoate
    —— 4-[(2-bromo-4-ethyl-N-methylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one 1205745-53-4 C19H20BrNO2S
    4-[(2-bromo-4-ethyl-N-methylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one
    —— 3-(5-(cyclopropylmethyl)-3-isopropyl-6-methyl-2-oxo-1,2-dihydropyridin-4-ylthio)-5-methylbenzonitrile 1205513-56-9 C21H24N2OS
    3-(5-(cyclopropylmethyl)-3-isopropyl-6-methyl-2-oxo-1,2-dihydropyridin-4-ylthio)-5-methylbenzonitrile
    —— 4-Bromo-6-[(1-methylethyl)thio]pyrimidine 889942-35-2 C7H9BrN2S
    4-Bromo-6-[(1-methylethyl)thio]pyrimidine
    —— 5-(5-cyclopropylmethyl-3-isopropyl-6-methyl-2-oxo-1,2-dihydro-pyridin-4-ylsulfanyl)-isophthalonitrile 1205513-50-3 C21H21N3OS
    5-(5-cyclopropylmethyl-3-isopropyl-6-methyl-2-oxo-1,2-dihydro-pyridin-4-ylsulfanyl)-isophthalonitrile
    —— methyl 3-[4-chloro-5-(dodecylthio)-1-oxido-3-oxoisothiazol-2(3H)-yl]propanoate 1203704-50-0 C19H32ClNO4S2
    methyl 3-[4-chloro-5-(dodecylthio)-1-oxido-3-oxoisothiazol-2(3H)-yl]propanoate
    —— [2-(1,3-Benzodithiol-2-ylidene)-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-67-6 C46H44O2S4Si2
    [2-(1,3-Benzodithiol-2-ylidene)-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— 1,4-bis(4-methoxybenzyl)-2-(phenylthio)-1H-imidazole 1202222-94-3 C25H24N2O2S
    1,4-bis(4-methoxybenzyl)-2-(phenylthio)-1H-imidazole
    —— [2-[4,5-Bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-63-2 C48H54O2S6Si2
    [2-[4,5-Bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— (4'S,2''R,3''R)-2-[4',5'-bis((tert-butyldimethylsilyl)oxy)pentyl]-2-[2''-methyl-3''-((tetrahydropyran-2-yl)oxy)butyl]-1,3-dithiane 1206551-63-4 C31H64O4S2Si2
    (4'S,2''R,3''R)-2-[4',5'-bis((tert-butyldimethylsilyl)oxy)pentyl]-2-[2''-methyl-3''-((tetrahydropyran-2-yl)oxy)butyl]-1,3-dithiane
    —— 2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole-4,7-dione 1206719-74-5 C14H6O2S4
    2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole-4,7-dione
    —— 1,4-dibenzyl-2-(phenylthio)-1H-imidazole 1202223-04-8 C23H20N2S
    1,4-dibenzyl-2-(phenylthio)-1H-imidazole
    —— [2-[4,5-Bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-66-5 C66H90O2S6Si2
    [2-[4,5-Bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— [2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-61-0 C44H46O2S6Si2
    [2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— 5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-2-(phenylthio)-1H-imidazole 1202223-18-4 C32H30N2O2S
    5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-2-(phenylthio)-1H-imidazole
    —— 4,5-dibenzyl-1-methyl-2-(phenylthio)-1H-imidazole 1202223-11-7 C24H22N2S
    4,5-dibenzyl-1-methyl-2-(phenylthio)-1H-imidazole
    —— 2-[(4-Aminophenyl)sulfanyl]propanoic acid hydrochloride 1803584-33-9 C9H12ClNO2S
    2-[(4-Aminophenyl)sulfanyl]propanoic acid hydrochloride
    —— (E)-1,2-Bis-trifluoromethanesulfonyl-ethene 56172-19-1 C4H2F6O4S2
    (E)-1,2-Bis-trifluoromethanesulfonyl-ethene
    —— 2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride 1049727-24-3 C13H15Cl2N3OS
    2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride
    —— 2-(1-Methyltetrazol-5-yl)sulfanylethyl-(thiophen-3-ylmethyl)azanium;chloride 1049713-42-9 C9H14ClN5S2
    2-(1-Methyltetrazol-5-yl)sulfanylethyl-(thiophen-3-ylmethyl)azanium;chloride
    —— 2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride 1054552-28-1 C13H14Cl2FN3OS
    2-[(2-chloro-6-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride
    —— 5-[(2-Chloro-1,1,2-trifluoroethyl)sulfanyl]pyridin-2-amine 887267-86-9 C7H6ClF3N2S
    5-[(2-Chloro-1,1,2-trifluoroethyl)sulfanyl]pyridin-2-amine
    —— 2,5-Dimethoxy-4-phenylthioamphetamine 952006-44-9 C17H21NO2S
    2,5-Dimethoxy-4-phenylthioamphetamine
    —— methyl N-(2,2,2-trichloro-1-phenylsulfanylethyl)carbamate 25801-39-2 C10H10Cl3NO2S
    methyl N-(2,2,2-trichloro-1-phenylsulfanylethyl)carbamate
    —— 6-benzyl-2-(benzylthio)-5-iodopyrimidin-4(3H)-one 1202564-60-0 C18H15IN2OS
    6-benzyl-2-(benzylthio)-5-iodopyrimidin-4(3H)-one
    —— 6-Benzyl-2-(1-phenylethylsulfanyl)pyrimidin-4-amine 1202564-73-5 C19H19N3S
    6-Benzyl-2-(1-phenylethylsulfanyl)pyrimidin-4-amine
    —— (2R)-Pentane-2-thiol 212195-83-0 C5H12S
    (2R)-Pentane-2-thiol
    —— 2-(benzylsulfanyl)-6-(3,5-dimethylbenzyl)-5-ethylpyrimidin-4(3H)-one 1147724-28-4 C22H24N2OS
    2-(benzylsulfanyl)-6-(3,5-dimethylbenzyl)-5-ethylpyrimidin-4(3H)-one
    —— N-({6-[(2-Hydroxyethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide 1158786-09-4 C17H24N4O5S3
    N-({6-[(2-Hydroxyethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide
    —— 2-(6-Ethylsulfanylpyridazin-3-yl)-2-phenylethanethioamide 1159497-83-2 C14H15N3S2
    2-(6-Ethylsulfanylpyridazin-3-yl)-2-phenylethanethioamide
    —— 1-{4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone 1173658-74-6 C19H17FN2OS2
    1-{4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone
    —— 5-acetyl-4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-56-4 C19H17FN2O2S
    5-acetyl-4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 5-Bromo-4-dimethylamino-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one 109880-28-6 C14H17BrN4OS
    5-Bromo-4-dimethylamino-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one
    —— 4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-55-3 C20H19FN2O3S
    4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— N-[1-[4-(Methylthio)phenyl]ethyl]-1-piperidinepropanamine 1036591-10-2 C17H28N2S
    N-[1-[4-(Methylthio)phenyl]ethyl]-1-piperidinepropanamine
    —— N-(1-Ethyl-3-methylpentyl)-4-(methylthio)benzenamine 1036436-76-6 C15H25NS
    N-(1-Ethyl-3-methylpentyl)-4-(methylthio)benzenamine
    —— 2-[(2,3-Dihydro-1H-inden-5-yl)thio]benzonitrile 1094423-94-5 C16H13NS
    2-[(2,3-Dihydro-1H-inden-5-yl)thio]benzonitrile
    —— 2-chloro-6-(propylthio)pyrazine 1094842-84-8 C7H9ClN2S
    2-chloro-6-(propylthio)pyrazine
    —— 1-(2,5-Dichlorothiophen-3-yl)-2-(4-methylphenyl)sulfanylethanone 1152899-15-4 C13H10Cl2OS2
    1-(2,5-Dichlorothiophen-3-yl)-2-(4-methylphenyl)sulfanylethanone
    —— 2-[(6-Chloro-3-pyridazinyl)thio]-6-ethoxy-1H-benzimidazole 1094842-85-9 C13H11ClN4OS
    2-[(6-Chloro-3-pyridazinyl)thio]-6-ethoxy-1H-benzimidazole
    —— 5-[(3,3-Dimethylbutyl)thio]-2-pyridinamine 1095560-62-5 C11H18N2S
    5-[(3,3-Dimethylbutyl)thio]-2-pyridinamine
    —— 4-Ethyl-2-[(1-methyl-1H-tetrazol-5-yl)thio]cyclohexanecarbonitrile 1218642-41-1 C11H17N5S
    4-Ethyl-2-[(1-methyl-1H-tetrazol-5-yl)thio]cyclohexanecarbonitrile
    —— 2-(4-bromophenylthio)pyridin-3-amine 353277-66-4 C11H9BrN2S
    2-(4-bromophenylthio)pyridin-3-amine