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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-chloro-6-methyl-5-(1-methylethyl)-2-(methylthio)pyrimidine 1379580-86-5 C9H13ClN2S
    4-chloro-6-methyl-5-(1-methylethyl)-2-(methylthio)pyrimidine
    —— 2,4-Bis-methylsulfanyl-6-thiazol-2-yl-pyrimidine 116137-72-5 C9H9N3S3
    2,4-Bis-methylsulfanyl-6-thiazol-2-yl-pyrimidine
    —— 1-(Phenylthio)-1,5-hexadien-3-ol 63540-13-6 C12H14OS
    1-(Phenylthio)-1,5-hexadien-3-ol
    —— 3-(Methanesulfonyl-methylsulfanyl-methyl)-hept-1-ene 81236-46-6 C10H20O2S2
    3-(Methanesulfonyl-methylsulfanyl-methyl)-hept-1-ene
    —— (3-(5-(2-(methylthio)-4-pyrimidinyl)-1,3-thiazol-4-yl)phenyl)amine 1160624-79-2 C14H12N4S2
    (3-(5-(2-(methylthio)-4-pyrimidinyl)-1,3-thiazol-4-yl)phenyl)amine
    —— O-methylthiomethyl-(S)-lactal 172703-58-1 C5H10O2S
    O-methylthiomethyl-(S)-lactal
    —— 3,3-Difluoro-2-phenyl-4-phenylsulfanyl-pent-4-en-2-ol 221557-79-5 C17H16F2OS
    3,3-Difluoro-2-phenyl-4-phenylsulfanyl-pent-4-en-2-ol
    —— (E)-5-Methyl-1-phenylsulfanyl-hexa-1,5-dien-3-ol 63540-15-8 C13H16OS
    (E)-5-Methyl-1-phenylsulfanyl-hexa-1,5-dien-3-ol
    —— 4-(difluoromethylthio)-2-fluoro-N-methylaniline 935440-64-5 C8H8F3NS
    4-(difluoromethylthio)-2-fluoro-N-methylaniline
    —— N-ethyl-2-fluoro-4-(trifluoromethylthio)-aniline 935440-21-4 C9H9F4NS
    N-ethyl-2-fluoro-4-(trifluoromethylthio)-aniline
    —— (E)-1-octenyl bromomethyl sulfone 86823-63-4 C9H17BrO2S
    (E)-1-octenyl bromomethyl sulfone
    —— 5-tert-Butyl-3-phenylsulfanyl-5H-furan-2-one 127459-06-7 C14H16O2S
    5-tert-Butyl-3-phenylsulfanyl-5H-furan-2-one
    —— 1,2-bis(phenylthio)cyclopentene 123558-55-4 C17H16S2
    1,2-bis(phenylthio)cyclopentene
    —— 2,6-difluoro-N-[(6-phenylsulfanylpyridazin-3-yl)carbamoyl]benzamide 1173149-91-1 C18H12F2N4O2S
    2,6-difluoro-N-[(6-phenylsulfanylpyridazin-3-yl)carbamoyl]benzamide
    —— N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935440-59-8 C9H9F4NS
    N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-chloro-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-02-4 C9H8ClF4NS
    2-chloro-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-methyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-03-5 C10H11F4NS
    2-methyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2,5-difluoro-N-methyl-4-(trifluoromethylthio)-aniline 935440-57-6 C8H6F5NS
    2,5-difluoro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-[(3,4-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol 666753-00-0 C14H14F3N3O2S
    2-[(3,4-difluorobenzyl)thio]-5-fluoro-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-ol
    —— 2-chloro-4-(difluoromethylthio)-N-methylaniline 935440-66-7 C8H8ClF2NS
    2-chloro-4-(difluoromethylthio)-N-methylaniline
    —— 2-fluoro-N-(3-methylthiopropyl)-4-(trifluoromethylthio)aniline 939038-32-1 C11H13F4NS2
    2-fluoro-N-(3-methylthiopropyl)-4-(trifluoromethylthio)aniline
    —— N-methyl-2-methyl-4-(trifluoromethylthio)aniline 935440-55-4 C9H10F3NS
    N-methyl-2-methyl-4-(trifluoromethylthio)aniline
    —— 2-fluoro-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline 935440-95-2 C9H7F6NS
    2-fluoro-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline
    —— 2-fluoro-N-(2-methoxyethyl)-4-(trifluoromethylthio)aniline 939037-89-5 C10H11F4NOS
    2-fluoro-N-(2-methoxyethyl)-4-(trifluoromethylthio)aniline
    —— 2,6-difluoro-N-methyl-4-(trifluoromethylthio)-aniline 935440-58-7 C8H6F5NS
    2,6-difluoro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-chloro-N-methyl-4-(pentafluoroethylthio)-aniline 935440-62-3 C9H7ClF5NS
    2-chloro-N-methyl-4-(pentafluoroethylthio)-aniline
    —— 2-fluoro-4-(1,1,2,3,3,3-hexafluoro-1-propylthio)-N-methylaniline 935440-65-6 C10H8F7NS
    2-fluoro-4-(1,1,2,3,3,3-hexafluoro-1-propylthio)-N-methylaniline
    —— 2-fluoro-N-methyl-4-(2-propynylthio)-aniline 935440-49-6 C10H10FNS
    2-fluoro-N-methyl-4-(2-propynylthio)-aniline
    —— N-(2-hydroxyethyl)-2-fluoro-4-(trifluoromethylthio)aniline 939037-92-0 C9H9F4NOS
    N-(2-hydroxyethyl)-2-fluoro-4-(trifluoromethylthio)aniline
    —— 2,3-dimethyl-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline 935440-96-3 C11H12F5NS
    2,3-dimethyl-N-methyl-4-(1,1,2,2,2-pentafluoroethylthio)-aniline
    —— 2,3-dimethyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline 935441-04-6 C11H13F4NS
    2,3-dimethyl-N-methyl-4-(1,1,2,2-tetrafluoroethylthio)-aniline
    —— 2-fluoro-N-methyl-4-(1,1,2-trifluoro-2-trifluoromethoxyethylthio)-aniline 935440-61-2 C10H8F7NOS
    2-fluoro-N-methyl-4-(1,1,2-trifluoro-2-trifluoromethoxyethylthio)-aniline
    —— 2-chloro-N-methyl-4-(trifluoromethylthio)-aniline 935440-56-5 C8H7ClF3NS
    2-chloro-N-methyl-4-(trifluoromethylthio)-aniline
    —— 2-methyl-N-methyl-4-(pentafluoroethylthio)-aniline 935440-63-4 C10H10F5NS
    2-methyl-N-methyl-4-(pentafluoroethylthio)-aniline
    —— 2-isopropyl-6-nitro-3,1-benzoxathian 148899-05-2 C11H13NO3S
    2-isopropyl-6-nitro-3,1-benzoxathian
    —— 6-amino-2-[(3,4-difluorobenzyl)thio]pyrimidin-4-ol 166751-46-8 C11H9F2N3OS
    6-amino-2-[(3,4-difluorobenzyl)thio]pyrimidin-4-ol
    —— 3,6-Bis[4-(2,3-dihydrothieno[3,4-b][1,4]dithiin-5-yl)phenyl]furo[3,2-g][1]benzofuran-2,7-dione 1353052-00-2 C34H20O4S6
    3,6-Bis[4-(2,3-dihydrothieno[3,4-b][1,4]dithiin-5-yl)phenyl]furo[3,2-g][1]benzofuran-2,7-dione
    —— 5-((3,4-difluorobenzyl)thio)-4H-1,2,4-triazol-3-amine 1446246-55-4 C9H8F2N4S
    5-((3,4-difluorobenzyl)thio)-4H-1,2,4-triazol-3-amine
    —— 2-[3-(4-chlorophenyl)-ureido]-5-{4-[3-(4-chlorophenyl)-ureido]phenylsulfanyl}benzoic acid 1192315-63-1 C27H20Cl2N4O4S
    2-[3-(4-chlorophenyl)-ureido]-5-{4-[3-(4-chlorophenyl)-ureido]phenylsulfanyl}benzoic acid
    —— 2-amino-5-(4-aminophenylthio)benzoic acid 1192319-15-5 C13H12N2O2S
    2-amino-5-(4-aminophenylthio)benzoic acid
    —— methyl 2-[(4-chlorophenyl)sulfanyl]-4-hydroxybutanoate 1369958-09-7 C11H13ClO3S
    methyl 2-[(4-chlorophenyl)sulfanyl]-4-hydroxybutanoate
    —— 1-(4-chlorophenyl)-3-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)urea 1263499-71-3 C19H17ClN4OS
    1-(4-chlorophenyl)-3-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)urea
    —— (Z)-3-Amino-4-methyl-pent-2-enethioic acid amide 95882-21-6 C6H12N2S
    (Z)-3-Amino-4-methyl-pent-2-enethioic acid amide
    —— 3-cyclohexyl-1-propylthiourea 70498-34-9 C10H20N2S
    3-cyclohexyl-1-propylthiourea
    —— 4-Aethyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-23-9 C8H9N3OS
    4-Aethyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— (2-Methyl-1-phenylthiopropyl)-diphenylphosphinoxid 61173-99-7 C22H23OPS
    (2-Methyl-1-phenylthiopropyl)-diphenylphosphinoxid
    —— (4R,5S)-5-tert-Butyl-4-p-tolylsulfanyl-dihydro-furan-2-one 110968-94-0 C15H20O2S
    (4R,5S)-5-tert-Butyl-4-p-tolylsulfanyl-dihydro-furan-2-one
    —— 1-Isopropyl-2-methylthioacetylen 33563-69-8 C6H10S
    1-Isopropyl-2-methylthioacetylen
    —— 4-Benzyl-2-methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one 53265-28-4 C14H13N3OS
    4-Benzyl-2-methyl-2H-pyrazino(2,3-b)-1,4-thiazin-3(4H)-one
    —— Ethyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate 154079-04-6 C26H44O3S
    Ethyl (S)-2-hydroxy-2-<<(4-methylphenyl)sulfenyl>methyl>hexadecanoate