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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-Benzylsulfanyl-4-cyano-isothiazol-3-ylsulfanyl)-acetamide 135489-18-8 C13H11N3OS3
    2-(5-Benzylsulfanyl-4-cyano-isothiazol-3-ylsulfanyl)-acetamide
    —— Phenol, 3-((3-((dimethylamino)methyl)-3-thienyl)thio)-, ethanedioate (2:1) (salt) 134508-41-1 C15H17NO5S2
    Phenol, 3-((3-((dimethylamino)methyl)-3-thienyl)thio)-, ethanedioate (2:1) (salt)
    —— [4-(3-Methoxy-phenylsulfanyl)-thiophen-3-ylmethyl]-dimethyl-amine; hydrochloride 134478-63-0 C14H17NOS2*ClH
    [4-(3-Methoxy-phenylsulfanyl)-thiophen-3-ylmethyl]-dimethyl-amine; hydrochloride
    —— [4-Fluoro-2-(3-methoxy-phenylsulfanyl)-benzyl]-dimethyl-amine; hydrochloride 134987-46-5 C16H18FNOS*ClH
    [4-Fluoro-2-(3-methoxy-phenylsulfanyl)-benzyl]-dimethyl-amine; hydrochloride
    —— 2-[4-Cyano-5-(4-fluoro-benzylsulfanyl)-isothiazol-3-ylsulfanyl]-acetamide 135489-19-9 C13H10FN3OS3
    2-[4-Cyano-5-(4-fluoro-benzylsulfanyl)-isothiazol-3-ylsulfanyl]-acetamide
    —— Benzenemethanamine, N,N-dimethyl-2-(2-thienylthio)-, hydrochloride 134478-64-1 C13H16ClNS2
    Benzenemethanamine, N,N-dimethyl-2-(2-thienylthio)-, hydrochloride
    —— [2-(3-Methoxy-phenylsulfanyl)-thiophen-3-ylmethyl]-dimethyl-amine; hydrochloride 134478-62-9 C14H17NOS2*ClH
    [2-(3-Methoxy-phenylsulfanyl)-thiophen-3-ylmethyl]-dimethyl-amine; hydrochloride
    —— [3-(3-Methoxy-phenylsulfanyl)-thiophen-2-ylmethyl]-dimethyl-amine; hydrochloride 134478-61-8 C14H17NOS2*ClH
    [3-(3-Methoxy-phenylsulfanyl)-thiophen-2-ylmethyl]-dimethyl-amine; hydrochloride
    —— N,N-Dimethyl-3-(3-hydroxyphenylthio)-2-thienylamine hemioxalate 134478-66-3 C28H32N2O6S4
    N,N-Dimethyl-3-(3-hydroxyphenylthio)-2-thienylamine hemioxalate
    —— Phenol, 3-((4-((dimethylamino)methyl)-3-thienyl)thio)-, ethanedioate (2:1) (salt) 134478-67-4 C28H32N2O6S4
    Phenol, 3-((4-((dimethylamino)methyl)-3-thienyl)thio)-, ethanedioate (2:1) (salt)
    —— 1-Chloro-3-((1H-1,2,4-triazol-3-yl)thio)-2-propanol 134399-10-3 C5H8ClN3OS
    1-Chloro-3-((1H-1,2,4-triazol-3-yl)thio)-2-propanol
    —— 5-Cyanomethylsulfanyl-3-(4-fluoro-benzylsulfanyl)-isothiazole-4-carbonitrile 135489-20-2 C13H8FN3S3
    5-Cyanomethylsulfanyl-3-(4-fluoro-benzylsulfanyl)-isothiazole-4-carbonitrile
    —— 3-Cyanomethylsulfanyl-5-(4-fluoro-benzylsulfanyl)-isothiazole-4-carbonitrile 135489-12-2 C13H8FN3S3
    3-Cyanomethylsulfanyl-5-(4-fluoro-benzylsulfanyl)-isothiazole-4-carbonitrile
    —— 1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)- 136633-13-1 C18H9Cl2N5S
    1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)-
    —— 4-Chloro-8-(4-fluoro-benzylsulfanyl)-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine 135518-31-9 C13H6ClFN4S3
    4-Chloro-8-(4-fluoro-benzylsulfanyl)-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine
    —— 8-Benzylsulfanyl-4-chloro-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine 135489-03-1 C13H7ClN4S3
    8-Benzylsulfanyl-4-chloro-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine
    —— 5-Cyanomethylsulfanyl-3-propylsulfanyl-isothiazole-4-carbonitrile 135518-36-4 C9H9N3S3
    5-Cyanomethylsulfanyl-3-propylsulfanyl-isothiazole-4-carbonitrile
    —— 1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)-9-methoxy- 136633-21-1 C19H11Cl2N5OS
    1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)-9-methoxy-
    —— 2-(4-Cyano-5-propylsulfanyl-isothiazol-3-ylsulfanyl)-acetamide 135489-13-3 C9H11N3OS3
    2-(4-Cyano-5-propylsulfanyl-isothiazol-3-ylsulfanyl)-acetamide
    —— 2-(4-Cyano-3-propylsulfanyl-isothiazol-5-ylsulfanyl)-acetamide 135489-21-3 C9H11N3OS3
    2-(4-Cyano-3-propylsulfanyl-isothiazol-5-ylsulfanyl)-acetamide
    —— 2-(3-Benzylsulfanyl-4-cyano-isothiazol-5-ylsulfanyl)-acetamide 135489-22-4 C13H11N3OS3
    2-(3-Benzylsulfanyl-4-cyano-isothiazol-5-ylsulfanyl)-acetamide
    —— 4-Chloro-8-propylsulfanyl-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine 135489-02-0 C9H7ClN4S3
    4-Chloro-8-propylsulfanyl-isothiazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine
    —— 1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)-9-methyl- 136633-17-5 C19H11Cl2N5S
    1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(2,4-dichlorophenyl)-9-methyl-
    —— 9-Methoxy-3-(4-methoxyphenyl)-1,2,4-triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline 136633-19-7 C20H15N5O2S
    9-Methoxy-3-(4-methoxyphenyl)-1,2,4-triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline
    —— 1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(4-methoxyphenyl)- 136633-11-9 C19H13N5OS
    1,2,4-Triazolo(3',4':2,3)(1,3,4)thiadiazepino(7,6-b)quinoline, 3-(4-methoxyphenyl)-
    —— 4-Pyrimidinamine, 2,2'-(1,3-propanediylbis(thio))bis- 123392-12-1 C11H14N6S2
    4-Pyrimidinamine, 2,2'-(1,3-propanediylbis(thio))bis-
    —— Pyrimidine, 2,2'-(1,10-decanediylbis(thio))bis(4,6-dimethyl- 123392-11-0 C22H34N4S2
    Pyrimidine, 2,2'-(1,10-decanediylbis(thio))bis(4,6-dimethyl-
    —— Morpholine, 4,4'-(1,6-hexanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-15-4 C24H36N6O2S2
    Morpholine, 4,4'-(1,6-hexanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— Morpholine, 4,4'-(1,4-butanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-13-2 C22H32N6O2S2
    Morpholine, 4,4'-(1,4-butanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— Morpholine, 4,4'-(1,5-pentanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis- 123392-14-3 C23H34N6O2S2
    Morpholine, 4,4'-(1,5-pentanediylbis(thio(6-methyl-2,4-pyrimidinediyl)))bis-
    —— N,N-dimethyl-2-[(1-methylimidazol-2-yl)sulfanylmethyl]aniline;hydron;dichloride —— C13H19Cl2N3S
    N,N-dimethyl-2-[(1-methylimidazol-2-yl)sulfanylmethyl]aniline;hydron;dichloride
    —— N-Methyl-1-(2-(phenylthio)phenyl)-2-propylamine oxalate 127876-84-0 C18H21NO4S
    N-Methyl-1-(2-(phenylthio)phenyl)-2-propylamine oxalate
    —— 4-(2-Difluoromethylsulfanyl-phenyl)-2-methyl-5-oxo-1,4,5,7-tetrahydro-furo[3,4-b]pyridine-3-carboxylic acid methyl ester 126335-07-7 C17H15F2NO4S
    4-(2-Difluoromethylsulfanyl-phenyl)-2-methyl-5-oxo-1,4,5,7-tetrahydro-furo[3,4-b]pyridine-3-carboxylic acid methyl ester
    —— [2-(3,4-dimethoxyphenyl)sulfanylphenyl]methanamine;hydron;chloride —— C15H18ClNO2S
    [2-(3,4-dimethoxyphenyl)sulfanylphenyl]methanamine;hydron;chloride
    —— hydron;4-[2-(methylaminomethyl)phenyl]sulfanylbenzene-1,3-diol;bromide —— C14H16BrNO2S
    hydron;4-[2-(methylaminomethyl)phenyl]sulfanylbenzene-1,3-diol;bromide
    —— 1-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;hydron;chloride —— C17H22ClNO2S
    1-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;hydron;chloride
    —— hydron;[2-(3-methoxyphenyl)sulfanylphenyl]methanamine;chloride —— C14H16ClNOS
    hydron;[2-(3-methoxyphenyl)sulfanylphenyl]methanamine;chloride
    —— N-Methyl-2-(2-(phenylthio)phenyl)ethylamine oxalate 127876-79-3 C17H19NO4S
    N-Methyl-2-(2-(phenylthio)phenyl)ethylamine oxalate
    —— Phenol, 3-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride 127906-68-7 C19H26ClNOS
    Phenol, 3-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride
    —— 2-[2-(aminomethyl)phenyl]sulfanylphenol;hydron;chloride —— C13H14ClNOS
    2-[2-(aminomethyl)phenyl]sulfanylphenol;hydron;chloride
    —— hydron;[2-(4-methoxyphenyl)sulfanylphenyl]methanamine;chloride —— C14H16ClNOS
    hydron;[2-(4-methoxyphenyl)sulfanylphenyl]methanamine;chloride
    —— Phenol, 2-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride 127906-67-6 C19H26ClNOS
    Phenol, 2-((2-((dipropylamino)methyl)phenyl)thio)-, hydrochloride
    —— Phenol, 3-((2-((dimethylamino)methyl)phenyl)thio)-, hydrobromide 127906-25-6 C15H18BrNOS
    Phenol, 3-((2-((dimethylamino)methyl)phenyl)thio)-, hydrobromide
    —— hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride —— C16H20ClNOS
    hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride
    —— [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium;chloride —— C15H18ClNOS
    [2-(3-Hydroxyphenyl)sulfanylphenyl]methyl-dimethylazanium;chloride
    —— hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— Benzenemethanamine, 2-((2-methoxyphenyl)thio)-, hydrochloride 127905-98-0 C14H16ClNOS
    Benzenemethanamine, 2-((2-methoxyphenyl)thio)-, hydrochloride
    —— hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(2-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— hydron;1-[2-(3-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride —— C15H18ClNOS
    hydron;1-[2-(3-methoxyphenyl)sulfanylphenyl]-N-methylmethanamine;chloride
    —— hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride —— C16H20ClNOS
    hydron;1-[2-(4-methoxyphenyl)sulfanylphenyl]-N,N-dimethylmethanamine;chloride