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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— O-[2-(tert-butyldisulfanyl)ethyl]hydroxylamine 1221405-60-2 C6H15NOS2
    O-[2-(tert-butyldisulfanyl)ethyl]hydroxylamine
    —— 7,15,16,24,25,33,34-heptakis(tert-butylsulfanyl)-N,N-diethyl-2,5,8,11,14,17,20,23,26,29,32,35,37,38,39,40-hexadecazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,12(39),13(18),14,16,19,21(38),22(27),23,25,28,30(37),31(36),32,34-nonadecaen-6-amine 1203577-04-1 C56H75N17S7
    7,15,16,24,25,33,34-heptakis(tert-butylsulfanyl)-N,N-diethyl-2,5,8,11,14,17,20,23,26,29,32,35,37,38,39,40-hexadecazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,12(39),13(18),14,16,19,21(38),22(27),23,25,28,30(37),31(36),32,34-nonadecaen-6-amine
    —— 2-methyl-N-[3-(phenylsulfanylmethyl)oxetan-3-yl]propane-2-sulfinamide 1211284-27-3 C14H21NO2S2
    2-methyl-N-[3-(phenylsulfanylmethyl)oxetan-3-yl]propane-2-sulfinamide
    —— [1-(1,3-Dithian-2-yl)-4,4-bis(methylsulfanyl)octan-2-yl]oxy-trimethylsilane 1216983-45-7 C17H36OS4Si
    [1-(1,3-Dithian-2-yl)-4,4-bis(methylsulfanyl)octan-2-yl]oxy-trimethylsilane
    —— tert-butyl N-phenylsulfanylcarbothioylcarbamate 1228437-30-6 C12H15NO2S2
    tert-butyl N-phenylsulfanylcarbothioylcarbamate
    —— methyl (2R,3R,4S)-3-acetamido-4-azido-2-[(2-methylpropan-2-yl)oxycarbonylcarbamothioyloxymethyl]-3,4-dihydro-2H-pyran-6-carboxylate 1228437-24-8 C16H23N5O7S
    methyl (2R,3R,4S)-3-acetamido-4-azido-2-[(2-methylpropan-2-yl)oxycarbonylcarbamothioyloxymethyl]-3,4-dihydro-2H-pyran-6-carboxylate
    —— 2,2'-bis[(S)-4-phenyloxazolin-2-yl]diphenylsulfide 1224301-67-0 C30H24N2O2S
    2,2'-bis[(S)-4-phenyloxazolin-2-yl]diphenylsulfide
    —— 2,2'-bis[(S)-4-benzyloxazolin-2-yl]diphenylsulfide 1224301-68-1 C32H28N2O2S
    2,2'-bis[(S)-4-benzyloxazolin-2-yl]diphenylsulfide
    —— (S)-N-methoxy-N-methyl-2-(5-(methylthio)-3,4-dihydro-2H-pyrrol-2-yl)acetamide 1207721-57-0 C9H16N2O2S
    (S)-N-methoxy-N-methyl-2-(5-(methylthio)-3,4-dihydro-2H-pyrrol-2-yl)acetamide
    —— 1-Methyl-2,5-bis(3-methyl-5-methylsulfanylthiophen-2-yl)pyrrole 1452807-76-9 C17H19NS4
    1-Methyl-2,5-bis(3-methyl-5-methylsulfanylthiophen-2-yl)pyrrole
    —— 4-fluoro-N-methyl-2-phenylsulfanylbenzamide 1233541-59-7 C14H12FNOS
    4-fluoro-N-methyl-2-phenylsulfanylbenzamide
    —— methyl-(3-(p-hydroxyphenylthio)propyl)sulfane 1234217-80-1 C10H14OS2
    methyl-(3-(p-hydroxyphenylthio)propyl)sulfane
    —— 2,2,6,6-Tetrabutyl-4,8-bis(2-phenylethynyl)-[1,3]dithiolo[4,5-f][1,3]benzodithiole 1225230-43-2 C40H46S4
    2,2,6,6-Tetrabutyl-4,8-bis(2-phenylethynyl)-[1,3]dithiolo[4,5-f][1,3]benzodithiole
    —— 4-chlorobutyl prop-2-ene-1-sulfinate 1235334-85-6 C7H13ClO2S
    4-chlorobutyl prop-2-ene-1-sulfinate
    —— (1S)-N-diphenylphosphanyl-N-methyl-1-(2-phenylsulfanylphenyl)ethanamine 1227795-25-6 C27H26NPS
    (1S)-N-diphenylphosphanyl-N-methyl-1-(2-phenylsulfanylphenyl)ethanamine
    —— 2,2,2-trichloro-N-[(2S)-3-methyl-1-phenylsulfanylbutan-2-yl]acetamide 1239889-58-7 C13H16Cl3NOS
    2,2,2-trichloro-N-[(2S)-3-methyl-1-phenylsulfanylbutan-2-yl]acetamide
    —— Diethylaminomethyl-[diethylaminomethyl(dithiocarboxy)carbamothioyl]carbamodithioic acid 84522-25-8 C13H26N4S5
    Diethylaminomethyl-[diethylaminomethyl(dithiocarboxy)carbamothioyl]carbamodithioic acid
    —— 4-[[2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethylsulfanyl]-5-methylsulfanyl-1,3-dithiol-2-one 1344677-91-3 C14H14OS12
    4-[[2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethylsulfanyl]-5-methylsulfanyl-1,3-dithiol-2-one
    —— 6-(4-Aminophenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine-5,8-dione 129137-20-8 C14H11NO4S
    6-(4-Aminophenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine-5,8-dione
    —— 6-(4-Hydroxyphenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine-5,8-dione 129700-49-8 C14H10O5S
    6-(4-Hydroxyphenyl)sulfanyl-2,3-dihydro-1,4-benzodioxine-5,8-dione
    —— 4-[3-[[2-(5H-[1,3]dithiolo[4,5-c]pyrrol-2-ylidene)-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanyl]propyl]phenol 1346683-31-5 C18H17NOS6
    4-[3-[[2-(5H-[1,3]dithiolo[4,5-c]pyrrol-2-ylidene)-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanyl]propyl]phenol
    —— 2,3,6,7,10,11,13,14-octahydro-5H,9H-4,12-(propanothiopropano)-1,8,15,23,4,12-benzote-trathiodiazacycloheptadecane-17,18-dicarbonitrile 1346257-73-5 C24H34N4S4
    2,3,6,7,10,11,13,14-octahydro-5H,9H-4,12-(propanothiopropano)-1,8,15,23,4,12-benzote-trathiodiazacycloheptadecane-17,18-dicarbonitrile
    —— 4-(5-(ethylthio)pyrazin-2-yl)morpholine 1345837-78-6 C10H15N3OS
    4-(5-(ethylthio)pyrazin-2-yl)morpholine
    —— Ph2PCH2CH2S(2-C6H4NH2) 1351378-84-1 C20H20NPS
    Ph2PCH2CH2S(2-C6H4NH2)
    —— 3-(1-(p-tolylthio)-3-(trimethylsilyl)propan-2-yl)thiazol-2(3H)-one 1338723-66-2 C16H23NOS2Si
    3-(1-(p-tolylthio)-3-(trimethylsilyl)propan-2-yl)thiazol-2(3H)-one
    —— 3-allyl-2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio)thiophene 1338723-62-8 C17H11F17S2
    3-allyl-2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio)thiophene
    —— N,N'-dibenzyl-2-(methylsulfanyl)pyrimidine-4,6-diamine 1345837-59-3 C19H20N4S
    N,N'-dibenzyl-2-(methylsulfanyl)pyrimidine-4,6-diamine
    —— (5R)-5-(difluoromethyl)-3-phenylsulfanyloxolan-2-one 1338560-69-2 C11H10F2O2S
    (5R)-5-(difluoromethyl)-3-phenylsulfanyloxolan-2-one
    —— methyl (4R)-4-[tert-butyl(dimethyl)silyl]oxy-5,5-difluoro-2-phenylsulfanylpentanoate 1338560-77-2 C18H28F2O3SSi
    methyl (4R)-4-[tert-butyl(dimethyl)silyl]oxy-5,5-difluoro-2-phenylsulfanylpentanoate
    —— (3RS,5S)-3-{(13R)-13-hydroxy-13-[(2R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]tetrahydrofuran-2-yl]tridec-11-ynyl}-5-methyl-3-(phenylsulfenyl)tetrahydrofuran-2-one 1161847-77-3 C33H48O6S
    (3RS,5S)-3-{(13R)-13-hydroxy-13-[(2R,5R)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]tetrahydrofuran-2-yl]tridec-11-ynyl}-5-methyl-3-(phenylsulfenyl)tetrahydrofuran-2-one
    —— 3-[(2R)-3-(4-bromophenyl)sulfanyl-2-methylpropanoyl]-1,3-oxazolidin-2-one 1346947-42-9 C13H14BrNO3S
    3-[(2R)-3-(4-bromophenyl)sulfanyl-2-methylpropanoyl]-1,3-oxazolidin-2-one
    —— 2-[2-[2-[2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethylsulfanyl]phenyl]sulfanylethoxy]ethoxy]ethanol 1427476-34-3 C18H30O6S2
    2-[2-[2-[2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethylsulfanyl]phenyl]sulfanylethoxy]ethoxy]ethanol
    —— 7,8-Dimethyl-2,13-dithia-4,11,15,22-tetrazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16,18,20-decaene 1346128-39-9 C18H12N4S2
    7,8-Dimethyl-2,13-dithia-4,11,15,22-tetrazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16,18,20-decaene
    —— 18,19-Dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene 1346128-42-4 C17H11N5S2
    18,19-Dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene
    —— (Z)-2-{[1-(p-tolylthio)dec-1-en-2-yl]thio}pyridine 1370652-40-6 C22H29NS2
    (Z)-2-{[1-(p-tolylthio)dec-1-en-2-yl]thio}pyridine
    —— (Z)-(1-cyclohexylethene-1,2-diyl)bis(p-tolylsulfane) 1370652-44-0 C22H26S2
    (Z)-(1-cyclohexylethene-1,2-diyl)bis(p-tolylsulfane)
    —— 8-Bromo-18,19-dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene 1346128-44-6 C17H10BrN5S2
    8-Bromo-18,19-dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene
    —— 8-Chloro-18,19-dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene 1346128-43-5 C17H10ClN5S2
    8-Chloro-18,19-dimethyl-2,13-dithia-4,6,11,15,22-pentazapentacyclo[12.8.0.03,12.05,10.016,21]docosa-1(22),3,5(10),6,8,11,14,16(21),17,19-decaene
    —— (Z)-(3-methylbut-1-ene-1,2-diyl)bis(p-tolylsulfane) 1370652-43-9 C19H22S2
    (Z)-(3-methylbut-1-ene-1,2-diyl)bis(p-tolylsulfane)
    —— 1,3,5-tri-(3,4,5-tridecylsulfanylphenyl)-6-oxoverdazyl 1355037-33-0 C110H195N4OS9
    1,3,5-tri-(3,4,5-tridecylsulfanylphenyl)-6-oxoverdazyl
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-7-methoxy-5-methyl-[1,3]dithiolo[4,5-d]pyridazin-4(5H)-one 1359021-07-0 C18H24N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-7-methoxy-5-methyl-[1,3]dithiolo[4,5-d]pyridazin-4(5H)-one
    —— 1,3,5-tri-(3,4,5-trihexylsulfanylphenyl)-6-oxoverdazyl 1355037-29-4 C74H123N4OS9
    1,3,5-tri-(3,4,5-trihexylsulfanylphenyl)-6-oxoverdazyl
    —— 1,3,5-tri-(3,4,5-tridodecylsulfanylphenyl)-6-oxoverdazyl 1355037-35-2 C128H231N4OS9
    1,3,5-tri-(3,4,5-tridodecylsulfanylphenyl)-6-oxoverdazyl
    —— [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxyphenyl)sulfanyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanyl-2-hydroxyphenyl]sulfanylphenyl] trifluoromethanesulfonate 1293286-38-0 C42H48F6O8S5
    [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxyphenyl)sulfanyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanyl-2-hydroxyphenyl]sulfanylphenyl] trifluoromethanesulfonate
    —— [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxyphenyl)sulfanyl-2-hydroxyphenyl]sulfanyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanylphenyl] trifluoromethanesulfonate 1293286-43-7 C42H48F6O8S5
    [4-Tert-butyl-2-[5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxyphenyl)sulfanyl-2-hydroxyphenyl]sulfanyl-2-(trifluoromethylsulfonyloxy)phenyl]sulfanylphenyl] trifluoromethanesulfonate
    —— 3-Phenylthieno[3,4-b][1,4]dithiine 1355645-99-6 C12H8S3
    3-Phenylthieno[3,4-b][1,4]dithiine
    —— (2R)-2-(1,3-benzodithiol-2-yl)-2-(3-methylphenyl)propan-1-ol 1369965-72-9 C17H18OS2
    (2R)-2-(1,3-benzodithiol-2-yl)-2-(3-methylphenyl)propan-1-ol
    —— (2R)-2-(1,3-benzodithiol-2-yl)-2-(4-bromophenyl)propan-1-ol 1369965-76-3 C16H15BrOS2
    (2R)-2-(1,3-benzodithiol-2-yl)-2-(4-bromophenyl)propan-1-ol
    —— 1,3,5-tri-(3,4,5-trioctylsulfanylphenyl)-6-oxoverdazyl 1355037-31-8 C92H159N4OS9
    1,3,5-tri-(3,4,5-trioctylsulfanylphenyl)-6-oxoverdazyl
    —— (3R)-1-(3,5-dimethylpyrazol-1-yl)-4,4,4-trifluoro-3-phenylsulfanylbutan-1-one 1374034-22-6 C15H15F3N2OS
    (3R)-1-(3,5-dimethylpyrazol-1-yl)-4,4,4-trifluoro-3-phenylsulfanylbutan-1-one