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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (3R,4R,6R)-4-hydroxy-3-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate 110474-30-1 C18H24O6S
    methyl (3R,4R,6R)-4-hydroxy-3-(2-methoxyethoxymethoxy)-6-phenylsulfanylcyclohexene-1-carboxylate
    —— Phenyl 2-deoxy-1-thio-α-L-threo-pentofuranoside 134614-93-0 C11H14O3S
    Phenyl 2-deoxy-1-thio-α-L-threo-pentofuranoside
    —— 5-(phenylthio)-3-o-tolyl-2-isoxazoline 1258507-20-8 C16H15NOS
    5-(phenylthio)-3-o-tolyl-2-isoxazoline
    —— (Z)-8-phenyl-5-(phenylthio)oct-5-en-2-one 1334484-20-6 C20H22OS
    (Z)-8-phenyl-5-(phenylthio)oct-5-en-2-one
    —— 4(R,S)-(Phenylthio)-6(S)-isopropenyl-1(9)-octalin 118575-88-5 C19H24S
    4(R,S)-(Phenylthio)-6(S)-isopropenyl-1(9)-octalin
    —— phenyl 1-(methyldiphenylsilyl)ethenyl sulfide 120395-08-6 C21H20SSi
    phenyl 1-(methyldiphenylsilyl)ethenyl sulfide
    —— 5-(phenylthio)norbornene 91911-07-8 C13H14S
    5-(phenylthio)norbornene
    —— 2-methyl-6-phenylthio-4H-5,6,-dihydropyran 75697-55-1 C12H14OS
    2-methyl-6-phenylthio-4H-5,6,-dihydropyran
    —— (Z)-3-amino-3-cyclohexylprop-2-enethioamide 95882-45-4 C9H16N2S
    (Z)-3-amino-3-cyclohexylprop-2-enethioamide
    —— 2-[2-(1,3,2-Benzodioxaborol-2-yl)-1-phenylsulfanylethyl]-1,3,2-benzodioxaborole 345921-80-4 C20H16B2O4S
    2-[2-(1,3,2-Benzodioxaborol-2-yl)-1-phenylsulfanylethyl]-1,3,2-benzodioxaborole
    —— 1-t-butyldimethylsilyl-1-phenylthioethylene 120395-09-7 C14H22SSi
    1-t-butyldimethylsilyl-1-phenylthioethylene
    —— bicyclo[2.2.1]hept-5-en-2-yl(phenyl)sulfane —— C13H14S
    bicyclo[2.2.1]hept-5-en-2-yl(phenyl)sulfane
    —— methyl (1R,4R,8R)-3-oxo-8-phenylsulfanyl-2-oxabicyclo[2.2.2]oct-5-ene-4-carboxylate 156899-11-5 C15H14O4S
    methyl (1R,4R,8R)-3-oxo-8-phenylsulfanyl-2-oxabicyclo[2.2.2]oct-5-ene-4-carboxylate
    —— 4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-selone 444603-47-8 C12H18O2S2Se3
    4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-selone
    —— 4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-diselenole-2-selone 444603-46-7 C12H18O2SSe4
    4-ethylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-diselenole-2-selone
    —— 3-(phenylsulfanyl)but-3-ene-1,2-diol 432502-72-2 C10H12O2S
    3-(phenylsulfanyl)but-3-ene-1,2-diol
    —— 4-ethylthio-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-one 444603-72-9 C12H18O3S3Se
    4-ethylthio-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-thiaselenole-2-one
    —— (Z)-1-nitro-2-phenylthioethene 130521-15-2 C8H7NO2S
    (Z)-1-nitro-2-phenylthioethene
    —— cis-/trans-1,3-Bis(mercaptomethyl)cyclohexane 4396-95-6 C8H16S2
    cis-/trans-1,3-Bis(mercaptomethyl)cyclohexane
    —— 4-chloro-2-methyl-butane-2-thiol 98137-31-6 C5H11ClS
    4-chloro-2-methyl-butane-2-thiol
    —— 2-chloro-3-methylthio-2-propenenitrile 127729-12-8 C4H4ClNS
    2-chloro-3-methylthio-2-propenenitrile
    —— acetone(6-chloropyridin-2-yl)[5-iodo-2-(methylthio)pyrimidin-4-yl]hydrazone 955369-81-0 C13H13ClIN5S
    acetone(6-chloropyridin-2-yl)[5-iodo-2-(methylthio)pyrimidin-4-yl]hydrazone
    —— 5-(Phenylthio)-3H-pyrrolizin 81927-41-5 C13H11NS
    5-(Phenylthio)-3H-pyrrolizin
    —— (2,3-Dihydro-5-oxo-5H-thiazolo(3,2-a)pyrimidin-6-yl)carbamic acid ethyl ester 93501-14-5 C9H11N3O3S
    (2,3-Dihydro-5-oxo-5H-thiazolo(3,2-a)pyrimidin-6-yl)carbamic acid ethyl ester
    —— methyl 2,3-dihydro-5H-oxothiazolo<3,2-a>pyrimidine-6-carbamate 93501-13-4 C8H9N3O3S
    methyl 2,3-dihydro-5H-oxothiazolo<3,2-a>pyrimidine-6-carbamate
    —— Benzene, [(1-chloro-2,2-difluoroethenyl)thio]- 102688-06-2 C8H5ClF2S
    Benzene, [(1-chloro-2,2-difluoroethenyl)thio]-
    —— (+-)-1'-Methyl-3-(2-methylphenyl)spiro(benzo(b)thiophene-2(3H),4'-piperidine) maleate 123245-21-6 C24H27NO4S
    (+-)-1'-Methyl-3-(2-methylphenyl)spiro(benzo(b)thiophene-2(3H),4'-piperidine) maleate
    —— 6-(2,4-Dimethylphenyl)-4-methylsulfanyl-2-oxopyran-3-carbonitrile 956041-33-1 C15H13NO2S
    6-(2,4-Dimethylphenyl)-4-methylsulfanyl-2-oxopyran-3-carbonitrile
    —— 2,3-dihydro-2-cyano-2-(tert-butylthio)-6-chlorobenzo<b>thiophene 92013-98-4 C13H14ClNS2
    2,3-dihydro-2-cyano-2-(tert-butylthio)-6-chlorobenzo<b>thiophene
    —— N,N-Dimethyl-5-fluoro-2-(3-hydroxyphenylthio)benzylamine maleate 134987-57-8 C19H20FNO5S
    N,N-Dimethyl-5-fluoro-2-(3-hydroxyphenylthio)benzylamine maleate
    —— N-(4-{4-[5-(2-methoxyethoxy)pyrazin-2-ylthio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide 1438638-83-5 C24H23N5O3S2
    N-(4-{4-[5-(2-methoxyethoxy)pyrazin-2-ylthio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide
    —— 2-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-23-4 C19H21NO5S
    2-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-32-5 C18H19NO5S
    2-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— N,N-Diethyl-2-(phenylthio)benzylamine maleate 127876-74-8 C21H25NO4S
    N,N-Diethyl-2-(phenylthio)benzylamine maleate
    —— N,N-Dimethyl-2-(2-(phenylthio)phenyl)ethylamine maleate 127876-80-6 C20H23NO4S
    N,N-Dimethyl-2-(2-(phenylthio)phenyl)ethylamine maleate
    —— 3,3-dimethoxyspirothiirane-2,2'-tricyclo[3.3.1.13.7]decane 359415-97-7 C13H20O2S
    3,3-dimethoxyspirothiirane-2,2'-tricyclo[3.3.1.13.7]decane
    —— N-Methyl-2-(2,4-dimethoxyphenylthio)benzylamine maleate 127905-88-8 C20H23NO6S
    N-Methyl-2-(2,4-dimethoxyphenylthio)benzylamine maleate
    —— 4-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-39-2 C18H19NO5S
    4-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2,5-Dimethoxyphenyl)thio)-N,N-dimethylbenzenemethanamine (Z)-2-butenedioate (1:1) 127905-79-7 C21H25NO6S
    2-((2,5-Dimethoxyphenyl)thio)-N,N-dimethylbenzenemethanamine (Z)-2-butenedioate (1:1)
    —— N,N-Dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine maleate 127876-86-2 C21H25NO4S
    N,N-Dimethyl-1-(2-(phenylthio)phenyl)-2-propylamine maleate
    —— 2-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-50-7 C17H17NO5S
    2-((2-(Aminomethyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 1-((2-(Phenylthio)phenyl)methyl)pyrrolidine (Z)-2-butenedioate (1:1) 127876-75-9 C21H23NO4S
    1-((2-(Phenylthio)phenyl)methyl)pyrrolidine (Z)-2-butenedioate (1:1)
    —— 4-((2-((Methylamino)methyl)phenyl)thio)-1,2-benzenediol (Z)-2-butenedioate (1:1) (salt) 127906-42-7 C18H19NO6S
    4-((2-((Methylamino)methyl)phenyl)thio)-1,2-benzenediol (Z)-2-butenedioate (1:1) (salt)
    —— N,N-Dimethyl-2-(2,4-dimethoxyphenylthio)benzylamine 127905-76-4 C21H25NO6S
    N,N-Dimethyl-2-(2,4-dimethoxyphenylthio)benzylamine
    —— N,N-Dimethyl-2-(phenylthio)benzylamine maleate 127876-73-7 C19H21NO4S
    N,N-Dimethyl-2-(phenylthio)benzylamine maleate
    —— (Z)-2-tert-butylsulfanyl-4-methoxynon-2-ene 88909-73-3 C14H28OS
    (Z)-2-tert-butylsulfanyl-4-methoxynon-2-ene
    —— 8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-91-4 C21H24N8O2S
    8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 6-methyl-2-(methylthio)-N-(tetrahydrofuran-3-yl)pyrimidin-4-amine 1071977-16-6 C10H15N3OS
    6-methyl-2-(methylthio)-N-(tetrahydrofuran-3-yl)pyrimidin-4-amine
    —— 8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine 1289544-13-3 C22H26N8O2S
    8-(6-(1H-pyrazol-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine
    —— 6-methyl-2-methylsulfanyl-pyrimidine-4-carbonitrile 65735-62-8 C7H7N3S
    6-methyl-2-methylsulfanyl-pyrimidine-4-carbonitrile