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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,2-bis-ethenesulfonyl-ethane 39690-70-5 C6H10O4S2
    1,2-bis-ethenesulfonyl-ethane
    —— (2R,3R)-2-Methyl-3-sulfanyl-butan-1-ol 669070-07-9 C5H12OS
    (2R,3R)-2-Methyl-3-sulfanyl-butan-1-ol
    —— 4-allyl-4-hydroxy-thiosemicarbazide 744984-44-9 C4H9N3OS
    4-allyl-4-hydroxy-thiosemicarbazide
    —— 3-octylthio-5-amino-2H-1,2,4-triazole 100599-72-2 C10H20N4S
    3-octylthio-5-amino-2H-1,2,4-triazole
    —— 2,5-dichloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone 202404-39-5 C13H10Cl2O3S
    2,5-dichloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone
    —— 6-bromo-1-(phenylthio)cyclohexene 85894-93-5 C12H13BrS
    6-bromo-1-(phenylthio)cyclohexene
    —— 1-Hexanol, 3-mercapto-3-methyl-, (3R)- 828300-39-6 C7H16OS
    1-Hexanol, 3-mercapto-3-methyl-, (3R)-
    —— 7-methylthio-3-ortho-tolyl-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one 335653-72-0 C14H14N4OS
    7-methylthio-3-ortho-tolyl-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one
    —— 2-chlorobenzyl 4-fluorophenyl sulfide 328-30-3 C13H10ClFS
    2-chlorobenzyl 4-fluorophenyl sulfide
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-(2-chlorobenzylthio)imidazo<4,5-d>pyridazine 85732-93-0 C17H15ClN6S
    4-(3,5-Dimethylpyrazol-1-yl)-2-(2-chlorobenzylthio)imidazo<4,5-d>pyridazine
    —— 2-[(2-Chlorophenyl)methylsulfanyl]pyridine-4-carbonitrile 249553-05-7 C13H9ClN2S
    2-[(2-Chlorophenyl)methylsulfanyl]pyridine-4-carbonitrile
    —— 3-{6-[(2,4-difluorophenyl)thio][1,2,4]triazolo[4,3-a]pyridin-3-yl}-N-(2-hydroxyethyl)-4-methylbenzamide 876372-55-3 C22H18F2N4O2S
    3-{6-[(2,4-difluorophenyl)thio][1,2,4]triazolo[4,3-a]pyridin-3-yl}-N-(2-hydroxyethyl)-4-methylbenzamide
    —— 6-(2-chloro-benzyloxy)-2-(2-chlorobenzylsulfanyl)-pyrimidin-4-ylamine 1178896-48-4 C18H15Cl2N3OS
    6-(2-chloro-benzyloxy)-2-(2-chlorobenzylsulfanyl)-pyrimidin-4-ylamine
    —— 7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(2-chlorobenzylthio)imidazo<4,5-d>pyridazine 85732-84-9 C17H14Cl2N6S
    7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(2-chlorobenzylthio)imidazo<4,5-d>pyridazine
    —— 6-hydroxy-2-(2-chlorobenzylsulfanyl)-3H-pyrimidin-4-one 333420-95-4 C11H9ClN2O2S
    6-hydroxy-2-(2-chlorobenzylsulfanyl)-3H-pyrimidin-4-one
    —— 2-(2-chloro-benzylsulfanyl)-5-trifluoromethyl-[1,3,4]thiadiazole 62617-03-2 C10H6ClF3N2S2
    2-(2-chloro-benzylsulfanyl)-5-trifluoromethyl-[1,3,4]thiadiazole
    —— 1-methanesulfinyl-heptadecane 6075-69-0 C18H38OS
    1-methanesulfinyl-heptadecane
    —— N,N’-bis(5-((2-chlorobenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine 1516888-62-2 C19H16Cl2N6S4
    N,N’-bis(5-((2-chlorobenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine
    —— 2-fluoro-4-(2,2,2-trifluoroethylthio)aniline 1237538-14-5 C8H7F4NS
    2-fluoro-4-(2,2,2-trifluoroethylthio)aniline
    —— 2-fluoro-4-(1,1,2,3,3,3-hexafluoropropylthio)aniline 1237538-13-4 C9H6F7NS
    2-fluoro-4-(1,1,2,3,3,3-hexafluoropropylthio)aniline
    —— 4-bromo-3-thiophenesulfonyl isocyanate 81417-50-7 C5H2BrNO3S2
    4-bromo-3-thiophenesulfonyl isocyanate
    —— (5-Ethoxycarbonylmethylsulfanyl-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester 120929-93-3 C18H20N2O5S2
    (5-Ethoxycarbonylmethylsulfanyl-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-acetic acid ethyl ester
    —— (R)-1-(2-methyl-2-oxiranylmethyl)-2-(4-nitrophenylthio)imidazole 683276-72-4 C13H13N3O3S
    (R)-1-(2-methyl-2-oxiranylmethyl)-2-(4-nitrophenylthio)imidazole
    —— 4-phenylsulfanyl-3,4-dihydro-2H-oxepin-7-one 200798-59-0 C12H12O2S
    4-phenylsulfanyl-3,4-dihydro-2H-oxepin-7-one
    —— 1-nitro-2-(4-nitrophenylthio)imidazole 683276-69-9 C9H6N4O4S
    1-nitro-2-(4-nitrophenylthio)imidazole
    —— 1-(2-cyanoethyl)-5-nitro-2-(4-nitrophenylthio)imidazole 683276-57-5 C12H9N5O4S
    1-(2-cyanoethyl)-5-nitro-2-(4-nitrophenylthio)imidazole
    —— 2-methyl-3-phenylsulfanyl-pyridine 1-oxide 1350294-25-5 C12H11NOS
    2-methyl-3-phenylsulfanyl-pyridine 1-oxide
    —— 3,7-bis[(2-bromo-5-octylphenyl)thio]benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid 1618666-20-8 C40H44Br2O4S4
    3,7-bis[(2-bromo-5-octylphenyl)thio]benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylic acid
    —— ((Z)-2-Cyclohexyl-2-ethoxy-vinylsulfanyl)-benzene 89005-25-4 C16H22OS
    ((Z)-2-Cyclohexyl-2-ethoxy-vinylsulfanyl)-benzene
    —— 3-(2-methylsulfanyl-pyrimidin-4-yl)-1-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylic acid 2-chloro-benzylamide 852164-86-4 C19H18ClN5O2S
    3-(2-methylsulfanyl-pyrimidin-4-yl)-1-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylic acid 2-chloro-benzylamide
    —— 1-(2-cyanoethyl)-2-(4-nitrophenylthio)-imidazole 683276-73-5 C12H10N4O2S
    1-(2-cyanoethyl)-2-(4-nitrophenylthio)-imidazole
    —— (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-buta-1,3-diene 39198-73-7 C7H12S
    (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-buta-1,3-diene
    —— 3-(2-aminophenylthio)-1-(2,4-dimethoxypyrimidin-5-yl)prop-1-yne 260803-80-3 C15H15N3O2S
    3-(2-aminophenylthio)-1-(2,4-dimethoxypyrimidin-5-yl)prop-1-yne
    —— (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanylethyl)-5-methoxy-tetrahydropyran-3-ol 828914-54-1 C20H23N3O4S2
    (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanylethyl)-5-methoxy-tetrahydropyran-3-ol
    —— 4H-1,2,4-Triazol-3-amine, 4-methyl-5-[(phenylmethyl)thio]- 87866-45-3 C10H12N4S
    4H-1,2,4-Triazol-3-amine, 4-methyl-5-[(phenylmethyl)thio]-
    —— (5-Benzylsulfanyl-4-methyl-4H-[1,2,4]triazol-3-yl)-[1-phenyl-meth-(Z)-ylidene]-amine 99472-19-2 C17H16N4S
    (5-Benzylsulfanyl-4-methyl-4H-[1,2,4]triazol-3-yl)-[1-phenyl-meth-(Z)-ylidene]-amine
    —— N,N'-ethylene-4-nitro-2,2'-thiodibenzamide 1393085-57-8 C16H13N3O4S
    N,N'-ethylene-4-nitro-2,2'-thiodibenzamide
    —— 2-methylthio-4-vinylpyrimidine 131467-05-5 C7H8N2S
    2-methylthio-4-vinylpyrimidine
    —— 1-methyl-2-nitro-4-(phenylthio)benzene 1240287-70-0 C13H11NO2S
    1-methyl-2-nitro-4-(phenylthio)benzene
    —— 3-<(3,4-Dioxo-2-phenylcyclobut-1-enylthio)methyl>-4-phenylcyclobuten-1,2-dion 81758-67-0 C21H12O4S
    3-<(3,4-Dioxo-2-phenylcyclobut-1-enylthio)methyl>-4-phenylcyclobuten-1,2-dion
    —— 7-(4-aminophenylthio)-1H-imidazo[4,5-b]pyridin-2(3H)-one 1147504-07-1 C12H10N4OS
    7-(4-aminophenylthio)-1H-imidazo[4,5-b]pyridin-2(3H)-one
    —— [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea 1231765-11-9 C18H19FN2OS
    [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea
    —— [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine hydrochloride 1231765-10-8 C17H18FNS*ClH
    [(R)-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine hydrochloride
    —— (S)-3-[3-(o-bromophenylthio)butanoyl]oxazolidin-2-one 1334952-07-6 C13H14BrNO3S
    (S)-3-[3-(o-bromophenylthio)butanoyl]oxazolidin-2-one
    —— 3-(allyloxy)-2-(methylsulfanyl)-N-[2-(vinyloxy)ethyl]pyrrole 1252928-26-9 C12H17NO2S
    3-(allyloxy)-2-(methylsulfanyl)-N-[2-(vinyloxy)ethyl]pyrrole
    —— 132491-46-4 C25H32S4Si
    —— 4,5-bis(hexylthio)-1,3-dithiole-2-thione 149468-17-7 C15H26S5
    4,5-bis(hexylthio)-1,3-dithiole-2-thione
    —— 132491-47-5 C25H28O2S4
    —— 4-{3-[(4-bromo-2-chlorophenyl)thio]phenyl}tetrahydro-2H-pyran-4-carboxamide 1159186-47-6 C18H17BrClNO2S
    4-{3-[(4-bromo-2-chlorophenyl)thio]phenyl}tetrahydro-2H-pyran-4-carboxamide
    —— 3-phenyl-2-(phenylsufanyl)benzo[b]thiophene 77128-61-1 C20H14S2
    3-phenyl-2-(phenylsufanyl)benzo[b]thiophene