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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,6-dithio-1,8-octanediol 807638-73-9 C8H18O2S2
    3,6-dithio-1,8-octanediol
    —— Isopropyl-thiocarbamic acid S-(2-hydroxy-ethyl) ester 61578-94-7 C6H13NO2S
    Isopropyl-thiocarbamic acid S-(2-hydroxy-ethyl) ester
    —— 4-{1-[4-(Methylsulfanyl)phenyl]prop-1-en-2-yl}morpholine 138172-67-5 C14H19NOS
    4-{1-[4-(Methylsulfanyl)phenyl]prop-1-en-2-yl}morpholine
    —— 6-(4-Chlorophenyl-thio)-3-hexen-2-one 94723-64-5 C12H13ClOS
    6-(4-Chlorophenyl-thio)-3-hexen-2-one
    —— 2-(2,4,5-Trichlorophenyl)sulfanylacetyl chloride 175987-80-1 C8H4Cl4OS
    2-(2,4,5-Trichlorophenyl)sulfanylacetyl chloride
    —— S-(4-Chloro-3 5-dimethylphenyl) N,N-dimethylthiocarbamate 150729-71-8 C11H14ClNOS
    S-(4-Chloro-3 5-dimethylphenyl) N,N-dimethylthiocarbamate
    —— N,N-dimethyl-4-(2,3,4,5,6-pentafluorophenyl)sulfanylaniline 57517-95-0 C14H10F5NS
    N,N-dimethyl-4-(2,3,4,5,6-pentafluorophenyl)sulfanylaniline
    —— (2E)-2-hydroxyimino-N-[2-[2-[[(2E)-2-hydroxyimino-3-(4-methylsulfanylphenyl)propanoyl]amino]ethyldisulfanyl]ethyl]-3-(4-methylsulfanylphenyl)propanamide 1356930-38-5 C24H30N4O4S4
    (2E)-2-hydroxyimino-N-[2-[2-[[(2E)-2-hydroxyimino-3-(4-methylsulfanylphenyl)propanoyl]amino]ethyldisulfanyl]ethyl]-3-(4-methylsulfanylphenyl)propanamide
    —— (2E)-3-(3-bromo-4-methylsulfanylphenyl)-N-[2-[2-[[(2E)-3-(3-bromo-4-methylsulfanylphenyl)-2-hydroxyiminopropanoyl]amino]ethyldisulfanyl]ethyl]-2-hydroxyiminopropanamide 1356930-41-0 C24H28Br2N4O4S4
    (2E)-3-(3-bromo-4-methylsulfanylphenyl)-N-[2-[2-[[(2E)-3-(3-bromo-4-methylsulfanylphenyl)-2-hydroxyiminopropanoyl]amino]ethyldisulfanyl]ethyl]-2-hydroxyiminopropanamide
    —— S-pentanoylsulfanyl pentanethioate 62652-56-6 C10H18O2S2
    S-pentanoylsulfanyl pentanethioate
    —— ethyl 3-(4-hydroxyphenyl)-2-phenylthiopropionate 710326-88-8 C17H18O3S
    ethyl 3-(4-hydroxyphenyl)-2-phenylthiopropionate
    —— (2E)-2-hydroxyimino-3-(4-methylsulfanylphenyl)-N-(2-sulfanylethyl)propanamide 1356930-05-6 C12H16N2O2S2
    (2E)-2-hydroxyimino-3-(4-methylsulfanylphenyl)-N-(2-sulfanylethyl)propanamide
    —— (2E)-3-(3-bromo-4-methylsulfanylphenyl)-2-hydroxyimino-N-(2-sulfanylethyl)propanamide 1356930-08-9 C12H15BrN2O2S2
    (2E)-3-(3-bromo-4-methylsulfanylphenyl)-2-hydroxyimino-N-(2-sulfanylethyl)propanamide
    —— N-(3-non-2-ynylsulfonylpropyl)acetamide 1353894-50-4 C14H25NO3S
    N-(3-non-2-ynylsulfonylpropyl)acetamide
    —— 2-[(8S,10S,11R)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde 1374424-57-3 C17H22O2S2
    2-[(8S,10S,11R)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde
    —— (Z,4R)-4-[2-[(2R)-2-hydroxybutyl]-1,3-dithian-2-yl]pent-2-enal 1374424-50-6 C13H22O2S2
    (Z,4R)-4-[2-[(2R)-2-hydroxybutyl]-1,3-dithian-2-yl]pent-2-enal
    —— 2-[(8S,10R,11R)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde 1374424-54-0 C17H22O2S2
    2-[(8S,10R,11R)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde
    —— 2-[(8R,10R,11R)-8-ethyl-11-methyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde 1374424-53-9 C13H22O2S2
    2-[(8R,10R,11R)-8-ethyl-11-methyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde
    —— 2-[(8S,10S,11S)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde 1374424-73-3 C17H22O2S2
    2-[(8S,10S,11S)-11-methyl-8-phenyl-9-oxa-1,5-dithiaspiro[5.5]undecan-10-yl]acetaldehyde
    —— 1-{1-[difluoro(phenylthio)methyl]cyclohe-1-xyl}pyrrolidine 1357268-72-4 C17H23F2NS
    1-{1-[difluoro(phenylthio)methyl]cyclohe-1-xyl}pyrrolidine
    —— 4,6,16,18-tetraaza-5,17-bis(methylsulfanyl)-2,8,14,20-tetrathiacalix[4]arene 1369593-92-9 C22H16N4S6
    4,6,16,18-tetraaza-5,17-bis(methylsulfanyl)-2,8,14,20-tetrathiacalix[4]arene
    —— 14,38,62,86-Tetrakis[4,5-bis(octylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene 1372813-90-5 C136H202N8O8S40
    14,38,62,86-Tetrakis[4,5-bis(octylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene
    —— Magnesium;14,38,62,86-tetrakis[4,5-bis(octylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,98-hexaza-97,99-diazanidatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene 1372813-88-1 C136H200MgN8O8S40
    Magnesium;14,38,62,86-tetrakis[4,5-bis(octylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,98-hexaza-97,99-diazanidatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene
    —— 14,38,62,86-Tetrakis[4,5-bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene 1372813-91-6 C168H266N8O8S40
    14,38,62,86-Tetrakis[4,5-bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-8,20,32,44,56,68,80,92-octaoxa-5,11,13,15,17,23,29,35,37,39,41,47,53,59,61,63,65,71,77,83,85,87,89,95-tetracosathia-a,2,26,50,74,97,98,99-octazatridecacyclo[73.21.1.13,25.127,49.151,73.04,24.012,16.028,48.036,40.052,72.060,64.076,96.084,88]hecta-a(25),1(96),2,4(24),12(16),26,28(48),36(40),49,51(98),52(72),60(64),73,75,84(88)-pentadecaene
    —— 4-phenylsulfanyl-N-(2,2,6,6-tetramethylpiperidin-4-yl)benzamide 1377996-98-9 C22H28N2OS
    4-phenylsulfanyl-N-(2,2,6,6-tetramethylpiperidin-4-yl)benzamide
    —— 1-(Methanesulfinyl)-1-methoxyethene 111674-84-1 C4H8O2S
    1-(Methanesulfinyl)-1-methoxyethene
    —— 2-Hydroxyprop-2-en-1-yl carbamimidothioate 147608-23-9 C4H8N2OS
    2-Hydroxyprop-2-en-1-yl carbamimidothioate
    —— Acetic acid;2-(2-hydroxyethylsulfanylmethylsulfanyl)ethanol 41123-73-3 C9H20O6S2
    Acetic acid;2-(2-hydroxyethylsulfanylmethylsulfanyl)ethanol
    —— 5H-[1,2,4]Triazolo[3,4-b][1,3]thiazocine 585528-63-8 C7H7N3S
    5H-[1,2,4]Triazolo[3,4-b][1,3]thiazocine
    —— N-Carbamothioyl-N,N'-diethylmethanehydrazonamide 577746-68-0 C6H14N4S
    N-Carbamothioyl-N,N'-diethylmethanehydrazonamide
    —— [(2-Methoxybuta-1,3-dien-1-yl)sulfanyl]benzene 60466-66-2 C11H12OS
    [(2-Methoxybuta-1,3-dien-1-yl)sulfanyl]benzene
    —— N-Carbamothioyl-N-methylmethanehydrazonamide 577746-69-1 C3H8N4S
    N-Carbamothioyl-N-methylmethanehydrazonamide
    —— 6-Chloro-4-methyl-2-(phenylimino)benzo[B]thiophen-3(2H)-one 5858-08-2 C15H10ClNOS
    6-Chloro-4-methyl-2-(phenylimino)benzo[B]thiophen-3(2H)-one
    —— 3,3'-[Sulfanediylbis(methylene)]bis{3-[(2-hydroxyethyl)sulfanyl]pentane-1,5-diol} 64036-92-6 C16H34O6S3
    3,3'-[Sulfanediylbis(methylene)]bis{3-[(2-hydroxyethyl)sulfanyl]pentane-1,5-diol}
    —— 2-ethyl-6-thiomethoxy-7-azabenzothiazole 666702-54-1 C9H10N2S2
    2-ethyl-6-thiomethoxy-7-azabenzothiazole
    —— S-pyridin-2-yl 2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoethanethioate —— C11H10N4O2S2
    S-pyridin-2-yl 2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoethanethioate
    —— 1-Chloropyrrolidine-2,5-dione;methylsulfanylbenzene 82661-92-5 C11H12ClNO2S
    1-Chloropyrrolidine-2,5-dione;methylsulfanylbenzene
    —— 2-Ethoxy-5-[(phenylsulfanyl)methyl]-3-(prop-1-en-1-yl)furan 941270-51-5 C16H18O2S
    2-Ethoxy-5-[(phenylsulfanyl)methyl]-3-(prop-1-en-1-yl)furan
    —— 3-(3-Chlorophenyl)-2-methyl-5-(phenylthio)furan 941270-45-7 C17H13ClOS
    3-(3-Chlorophenyl)-2-methyl-5-(phenylthio)furan
    —— 2-tert-Butyl-5-phenylsulfanyl-furan 941270-60-6 C14H16OS
    2-tert-Butyl-5-phenylsulfanyl-furan
    —— 1-(2-methyl-5-(phenylthiomethyl)furan-3-yl)ethanone 941270-52-6 C14H14O2S
    1-(2-methyl-5-(phenylthiomethyl)furan-3-yl)ethanone
    —— 3-(2-Chlorophenyl)-2-methyl-5-(phenylthio)furan 941270-46-8 C17H13ClOS
    3-(2-Chlorophenyl)-2-methyl-5-(phenylthio)furan
    —— 3-(2,4-Dichlorophenyl)-2-methoxy-5-(phenylthio)furan 941270-41-3 C17H12Cl2O2S
    3-(2,4-Dichlorophenyl)-2-methoxy-5-(phenylthio)furan
    —— 2-methoxy-3-phenyl-5-[(phenylthio)methyl]furan 941270-39-9 C18H16O2S
    2-methoxy-3-phenyl-5-[(phenylthio)methyl]furan
    —— 2-methoxy-3-(3-methylphenyl)-5-[(phenylthio)methyl]furan 941270-43-5 C19H18O2S
    2-methoxy-3-(3-methylphenyl)-5-[(phenylthio)methyl]furan
    —— Tetramethylen tetraxanthogen 35106-11-7 C12H16O4S8
    Tetramethylen tetraxanthogen
    —— 2-(Trifluoromethylthio)-benzeneboronic acid 947533-17-7 C7H6BF3O2S
    2-(Trifluoromethylthio)-benzeneboronic acid
    —— 3-[(Hexa-1,4-dien-3-yl)disulfanyl]hexa-1,4-diene 33368-82-0 C12H18S2
    3-[(Hexa-1,4-dien-3-yl)disulfanyl]hexa-1,4-diene
    —— 2H-Thieno[2',3':4,5]pyrrolo[1,2-c]imidazole 389860-21-3 C8H6N2S
    2H-Thieno[2',3':4,5]pyrrolo[1,2-c]imidazole
    —— 2,4-Dioxo-1,3-diazetidine-1,3-diylbis(p-phenylenethio-o-phenylene)diisocyanate 85818-49-1 C28H16N4O4S2
    2,4-Dioxo-1,3-diazetidine-1,3-diylbis(p-phenylenethio-o-phenylene)diisocyanate