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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-diethylcarbamothioate;nickel(2+) —— C10H20N2NiO2S2
    N,N-diethylcarbamothioate;nickel(2+)
    —— Methylsulfinylmethane;tetrachlororhodium 39248-47-0 C4H12Cl4O2RhS2
    Methylsulfinylmethane;tetrachlororhodium
    —— 5-(methylthio)pent-1-en-3-amine hydrochloride 1552316-40-1 C6H13NS*ClH
    5-(methylthio)pent-1-en-3-amine hydrochloride
    —— 2,2'-dichloro-4,4'-sulfanediyl-di-phenol 79718-62-0 C12H8Cl2O2S
    2,2'-dichloro-4,4'-sulfanediyl-di-phenol
    —— Hexafluor-2-phenyl-2-propyl-o-phenylthiobenzoat 37847-84-0 C22H14F6O2S
    Hexafluor-2-phenyl-2-propyl-o-phenylthiobenzoat
    —— (E)-3-Ethyl-7-methyl-6-phenylsulfanyl-octa-4,6-dien-3-ol 88904-69-2 C17H24OS
    (E)-3-Ethyl-7-methyl-6-phenylsulfanyl-octa-4,6-dien-3-ol
    —— (2R)-2-[[2-[2-[(2R)-1,4-dioxan-2-yl]ethyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane 934346-57-3 C15H26O4S2
    (2R)-2-[[2-[2-[(2R)-1,4-dioxan-2-yl]ethyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane
    —— 1-(1-cyclohexenyl)-4-(phenylthio)-1-butanone 98678-10-5 C16H20OS
    1-(1-cyclohexenyl)-4-(phenylthio)-1-butanone
    —— (2R)-2-[[2-[[(2S)-1,4-dioxan-2-yl]methyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane 934346-64-2 C14H24O4S2
    (2R)-2-[[2-[[(2S)-1,4-dioxan-2-yl]methyl]-1,3-dithian-2-yl]methyl]-1,4-dioxane
    —— 1-(1-cyclohexenyl)-4-(phenylthio)-1-butanone ethylene ketal 127257-40-3 C18H24O2S
    1-(1-cyclohexenyl)-4-(phenylthio)-1-butanone ethylene ketal
    —— Carbanide;gold(3+);dithiocyanate —— C6H12Au2N2S2
    Carbanide;gold(3+);dithiocyanate
    —— (E)-2,6-Dimethyl-5-phenylsulfanyl-5-trimethylsilanyl-hept-3-en-2-ol 79409-74-8 C18H30OSSi
    (E)-2,6-Dimethyl-5-phenylsulfanyl-5-trimethylsilanyl-hept-3-en-2-ol
    —— (E)-5-Cycloheptyl-2-methyl-5-phenylsulfanyl-5-trimethylsilanyl-pent-3-en-2-ol 79409-76-0 C22H36OSSi
    (E)-5-Cycloheptyl-2-methyl-5-phenylsulfanyl-5-trimethylsilanyl-pent-3-en-2-ol
    —— 2,4-diamino-5-hydroxyphenyl 2'-aminophenyl sulfide 81384-33-0 C12H13N3OS
    2,4-diamino-5-hydroxyphenyl 2'-aminophenyl sulfide
    —— 1-bromo-2-methylsulfanyl-ethene 98022-30-1 C3H5BrS
    1-bromo-2-methylsulfanyl-ethene
    —— 1,2-Bis-(o-amino-phenyl-mercapto)-ethylen 66920-01-2 C14H14N2S2
    1,2-Bis-(o-amino-phenyl-mercapto)-ethylen
    —— 1-Aethylsulfonyl-1-butin 13894-55-8 C6H10O2S
    1-Aethylsulfonyl-1-butin
    —— ethyl 4-chloro-2,5-di(2-nitrophenylthio)benzoate 62486-41-3 C21H15ClN2O6S2
    ethyl 4-chloro-2,5-di(2-nitrophenylthio)benzoate
    —— (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-but-1-ene 52101-07-2 C7H14S
    (<i>E</i>)-2,3-dimethyl-1-methylsulfanyl-but-1-ene
    —— Propyl-β-hydroxy-aethylsulfon 22812-93-7 C5H12O3S
    Propyl-β-hydroxy-aethylsulfon
    —— pentacarbonyl(2-methyl-1-methylthio-4,5,6,7-tetrahydro-3aH-indene-S)chromium 178534-76-4 C16H16CrO5S
    pentacarbonyl(2-methyl-1-methylthio-4,5,6,7-tetrahydro-3aH-indene-S)chromium
    —— (Ξ)-1-ethoxy-2-butylsulfanyl-ethylene 98560-28-2 C8H16OS
    (Ξ)-1-ethoxy-2-butylsulfanyl-ethylene
    —— (<i>E</i>)-2-methyl-1-methylsulfanyl-but-1-ene 52101-05-0 C6H12S
    (<i>E</i>)-2-methyl-1-methylsulfanyl-but-1-ene
    —— (4R,5S)-3-acetyl-2,2-dimethyl-4-(hydroxymethyl)-5-<4-(methylthio)phenyl>-1,3-oxazolidine 135204-37-4 C15H21NO3S
    (4R,5S)-3-acetyl-2,2-dimethyl-4-(hydroxymethyl)-5-<4-(methylthio)phenyl>-1,3-oxazolidine
    —— 1-Isopropyl-1-ethylmercapto-propadien-1,2 34262-53-8 C8H14S
    1-Isopropyl-1-ethylmercapto-propadien-1,2
    —— Phenyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 148900-37-2 C21H18N2S
    Phenyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine
    —— (+)-(1S,2R)-2-amino-1-<4-(methylthio)phenyl>-1,3-propanediol 27348-48-7 C10H15NO2S
    (+)-(1S,2R)-2-amino-1-<4-(methylthio)phenyl>-1,3-propanediol
    —— (4S,5S)-5-(4-methylthiophenyl)-4-hydroxymethyl-2,2-dimethyl-1,3-oxazolidine 135204-38-5 C13H19NO2S
    (4S,5S)-5-(4-methylthiophenyl)-4-hydroxymethyl-2,2-dimethyl-1,3-oxazolidine
    —— (4S,5S)-3-acetyl-2,2-dimethyl-4-formyl-5-<4-(methylthio)phenyl>-1,3-oxazolidine 135204-36-3 C15H19NO3S
    (4S,5S)-3-acetyl-2,2-dimethyl-4-formyl-5-<4-(methylthio)phenyl>-1,3-oxazolidine
    —— 4-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)butanamide 1061318-00-0 C17H16IN5O3S
    4-(4-amino-2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-1-yl)butanamide
    —— (2-ethyl-2-methyl-[1,3]oxathiolan-5-yl)-methanol 24606-77-7 C7H14O2S
    (2-ethyl-2-methyl-[1,3]oxathiolan-5-yl)-methanol
    —— Bis-<2,5-dimethoxy-phenyl>-sulfid 93006-86-1 C16H18O4S
    Bis-<2,5-dimethoxy-phenyl>-sulfid
    —— N-Phenyl-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide 171618-54-5 C23H20N2OS
    N-Phenyl-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phenyl-amine 171618-47-6 C27H22N2O2S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phenyl-amine
    —— 1-Ethyl-1-ethylmercapto-propadien-1,2 89942-02-9 C7H12S
    1-Ethyl-1-ethylmercapto-propadien-1,2
    —— 2-bromo-3-(2-cyanoethylsulfanyl)thiophene 499793-74-7 C7H6BrNS2
    2-bromo-3-(2-cyanoethylsulfanyl)thiophene
    —— 2-bromo-3-(2-trimethylsilylethylsulfanyl)thiophene 1310380-03-0 C9H15BrS2Si
    2-bromo-3-(2-trimethylsilylethylsulfanyl)thiophene
    —— (cyclohexylidenemethyl)(2-methylbutyl)sulfane 1332526-10-9 C12H22S
    (cyclohexylidenemethyl)(2-methylbutyl)sulfane
    —— 3,3-Dimethyl-2-phenylsulfanyl-butan-1-ol 54441-95-1 C12H18OS
    3,3-Dimethyl-2-phenylsulfanyl-butan-1-ol
    —— S-<Guanyl-aethyl-1>-isothioharnstoff 88526-36-7 C4H10N4S
    S-<Guanyl-aethyl-1>-isothioharnstoff
    —— 3,3-Dimethyl-2-methylsulfanyl-butan-1-ol 111661-09-7 C7H16OS
    3,3-Dimethyl-2-methylsulfanyl-butan-1-ol
    —— 4-[(4-bromophenyl)thio]butanoic acid 15115-76-1 C10H11BrO2S
    4-[(4-bromophenyl)thio]butanoic acid
    —— (E)-6,6-Dimethyl-5-phenylsulfanyl-hept-3-en-2-one 173200-93-6 C15H20OS
    (E)-6,6-Dimethyl-5-phenylsulfanyl-hept-3-en-2-one
    —— (E)-5,5-Dimethyl-4-phenylsulfanyl-hex-2-enal 711028-77-2 C14H18OS
    (E)-5,5-Dimethyl-4-phenylsulfanyl-hex-2-enal
    —— 2-Adamantan-1-yl-isothiourea 30771-94-9 C11H18N2S
    2-Adamantan-1-yl-isothiourea
    —— 1-methylsulfinyl-4,4-dimethylheptan-2-one 109902-08-1 C10H20O2S
    1-methylsulfinyl-4,4-dimethylheptan-2-one
    —— (E)-5-Methanesulfonyl-6,6-dimethyl-hept-3-en-2-one 711028-71-6 C10H18O3S
    (E)-5-Methanesulfonyl-6,6-dimethyl-hept-3-en-2-one
    —— 3,3-dimethyl-2-methylsulfanyl-butyraldehyde 69769-61-5 C7H14OS
    3,3-dimethyl-2-methylsulfanyl-butyraldehyde
    —— bis-<2,2-bis(ethylthio)vinyl> sulphide 89880-17-1 C12H22S5
    bis-<2,2-bis(ethylthio)vinyl> sulphide
    —— 1-((E)-2-Ethylsulfanyl-2-methylsulfanyl-ethenesulfinyl)-pentan-2-ol 89880-10-4 C10H20O2S3
    1-((E)-2-Ethylsulfanyl-2-methylsulfanyl-ethenesulfinyl)-pentan-2-ol