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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[2-(2-azido-ethoxy)ethylsulfonyl]ethanol 1303532-01-5 C6H13N3O4S
    2-[2-(2-azido-ethoxy)ethylsulfonyl]ethanol
    —— 5-Hydrazino-6-phenylthio-as-triazin-3(2H)-on 32331-03-6 C9H9N5OS
    5-Hydrazino-6-phenylthio-as-triazin-3(2H)-on
    —— 1h-Imidazole, 5,5'-thiobis[1-methyl-4-nitro- 13755-68-5 C8H8N6O4S
    1h-Imidazole, 5,5'-thiobis[1-methyl-4-nitro-
    —— N-(4-(8-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrazin-6-ylthio)phenyl)cyclopropane carboxamide 883734-21-2 C20H19N7OS
    N-(4-(8-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrazin-6-ylthio)phenyl)cyclopropane carboxamide
    —— 1,1,2-trifluoro-2-chloro-2'-bromodiethyl thioether 61810-45-5 C4H5BrClF3S
    1,1,2-trifluoro-2-chloro-2'-bromodiethyl thioether
    —— 2,3'-Bithiethan-tetroxid 17471-12-4 C6H10O4S2
    2,3'-Bithiethan-tetroxid
    —— 5-Amino-6-methylthio-as-triazin-3(2H)-on 31697-23-1 C4H6N4OS
    5-Amino-6-methylthio-as-triazin-3(2H)-on
    —— methyl 2-(4-cyclopropanecarboxamido-phenylsulfanyl)-5-nitro-6-(5-methylpyrazol-3-ylamino)-4-pyrimidinecarboxylate 888020-13-1 C20H19N7O5S
    methyl 2-(4-cyclopropanecarboxamido-phenylsulfanyl)-5-nitro-6-(5-methylpyrazol-3-ylamino)-4-pyrimidinecarboxylate
    —— N-[4-[4-[4-(aminomethyl)piperidin-1-yl]-6-[(5-methyl-1H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide 1152262-47-9 C24H30N8OS
    N-[4-[4-[4-(aminomethyl)piperidin-1-yl]-6-[(5-methyl-1H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide
    —— N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide 883734-14-3 C20H19N7OS
    N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide
    —— N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)-[1,2,4]triazolo[1,5-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide 883734-19-8 C19H18N8OS
    N-(4-(5-(5-methyl-1H-pyrazol-3-ylamino)-[1,2,4]triazolo[1,5-f]pyrimidin-7-ylthio)phenyl)cyclopropane carboxamide
    —— 4-Amino-3-methyl-2-methylthio-6-oxo-3,6-dihydropyrimidin 29877-80-3 C6H9N3OS
    4-Amino-3-methyl-2-methylthio-6-oxo-3,6-dihydropyrimidin
    —— N-[4-[[4-(1H-imidazol-2-ylamino)-6-phenyl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-45-8 C22H19N7OS
    N-[4-[[4-(1H-imidazol-2-ylamino)-6-phenyl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-(4-(2-ethyl-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide 883737-15-3 C22H23N7OS
    N-(4-(2-ethyl-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide
    —— 1,4,8,12-Tetrathiadispiro[4.1.57.15]tridecan-6-one 1018781-79-7 C9H12OS4
    1,4,8,12-Tetrathiadispiro[4.1.57.15]tridecan-6-one
    —— (Z)-5-(3-Nitro-4-((2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)thio) benzylidene)-2-thioxothiazolidin-4-one 21 1489285-12-2 C17H5F7N2O3S3
    (Z)-5-(3-Nitro-4-((2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)thio) benzylidene)-2-thioxothiazolidin-4-one 21
    —— N-(4-(5-(5-Methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrimidin-7-ylthio)phenyl)-cyclopropane carboxamide 883734-23-4 C20H19N7OS
    N-(4-(5-(5-Methyl-1H-pyrazol-3-ylamino)imidazo[1,2-a]pyrimidin-7-ylthio)phenyl)-cyclopropane carboxamide
    —— 2,4-diamino-5-methyl-6-(2',3',5',6'-tetrafluoro-4'-trifluoromethylphenylsulfanyl)furo[2,3-d]pyrimidine 1217309-57-3 C14H7F7N4OS
    2,4-diamino-5-methyl-6-(2',3',5',6'-tetrafluoro-4'-trifluoromethylphenylsulfanyl)furo[2,3-d]pyrimidine
    —— 2-(2-Methylsulfonylethyl)guanidine 1149763-47-2 C4H11N3O2S
    2-(2-Methylsulfonylethyl)guanidine
    —— octanedithioamide 157122-35-5 C8H16N2S2
    octanedithioamide
    —— 2-(3,5-Bis-trifluoromethyl-phenylsulfanyl)-benzaldehyde 643763-23-9 C15H8F6OS
    2-(3,5-Bis-trifluoromethyl-phenylsulfanyl)-benzaldehyde
    —— 3-Isobutylsulfinyl-propionsaeure 7318-61-8 C7H14O3S
    3-Isobutylsulfinyl-propionsaeure
    —— 2,3,5,6-tetrafluorothioanisole 1480-02-0 C7H4F4S
    2,3,5,6-tetrafluorothioanisole
    —— 2-amino-5-phenyl-3-(3,5-bis-trifluoromethylphenyl)thiopyrazine 1262118-45-5 C18H11F6N3S
    2-amino-5-phenyl-3-(3,5-bis-trifluoromethylphenyl)thiopyrazine
    —— (2-chloroethylsulfanyl)-2,3,5,6-tetrafluorobenzene 111873-89-3 C8H5ClF4S
    (2-chloroethylsulfanyl)-2,3,5,6-tetrafluorobenzene
    —— heptyl vinyl sulfone 30719-65-4 C9H18O2S
    heptyl vinyl sulfone
    —— ethyl 2,3,5,6-tetrafluorophenyl sulphide 78522-94-8 C8H6F4S
    ethyl 2,3,5,6-tetrafluorophenyl sulphide
    —— 1-methylsulfanylmethoxy-hexane 66675-05-6 C8H18OS
    1-methylsulfanylmethoxy-hexane
    —— (R)-2-((R)-2-Methyl-1-methylsulfanylmethoxy-allyl)-oxirane 251305-18-7 C8H14O2S
    (R)-2-((R)-2-Methyl-1-methylsulfanylmethoxy-allyl)-oxirane
    —— 1,4-bis(diphenylphosphino)ethylthiobenzene 289909-61-1 C34H32P2S2
    1,4-bis(diphenylphosphino)ethylthiobenzene
    —— 5-Hydrazino-6-benzylthio-as-triazin-3(2H)-on 32331-04-7 C10H11N5OS
    5-Hydrazino-6-benzylthio-as-triazin-3(2H)-on
    —— 3,6-dimethyl-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 1050440-02-2 C6H8N4S
    3,6-dimethyl-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 1,4-bis(6-chloro-s-tetrazin-3-ylthio)butane 1206227-55-5 C8H8Cl2N8S2
    1,4-bis(6-chloro-s-tetrazin-3-ylthio)butane
    —— 2-methylthio-4-chloro-6-(4-methyl-piperidin-1-yl)-5-isopropyl-pyrimidine 1111757-48-2 C14H22ClN3S
    2-methylthio-4-chloro-6-(4-methyl-piperidin-1-yl)-5-isopropyl-pyrimidine
    —— 6-(4-Chloro-phenyl)-3-methyl-7-phenylsulfanyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 153235-57-5 C17H13ClN4S2
    6-(4-Chloro-phenyl)-3-methyl-7-phenylsulfanyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-methyl-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazin-6-one 54025-84-2 C5H6N4OS
    3-methyl-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazin-6-one
    —— 4-Amino-3-benzylthio-5-methyl-4H-1,2,4-triazole 90871-40-2 C10H12N4S
    4-Amino-3-benzylthio-5-methyl-4H-1,2,4-triazole
    —— 3-Methyl-5-prop-2-ynylsulfanyl-1,2,4-triazol-4-amine 1050439-98-9 C6H8N4S
    3-Methyl-5-prop-2-ynylsulfanyl-1,2,4-triazol-4-amine
    —— 3,9-dimethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 66933-15-1 C10H14N4S
    3,9-dimethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— tert-butyl {2-[(2-hydroxyethyl)sulfonyl]-1,1-dimethylethyl}carbamate 947665-49-8 C11H23NO5S
    tert-butyl {2-[(2-hydroxyethyl)sulfonyl]-1,1-dimethylethyl}carbamate
    —— 3-methyl-6-<i>p</i>-tolyl-7<i>H</i>-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 54025-91-1 C12H12N4S
    3-methyl-6-<i>p</i>-tolyl-7<i>H</i>-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 2,2-Bis-(2-chloro-ethylsulfanyl)-N-methyl-acetamide 164725-79-5 C7H13Cl2NOS2
    2,2-Bis-(2-chloro-ethylsulfanyl)-N-methyl-acetamide
    —— 5-n-Heptylthio-1,3,4-thiadiazolyl-2-amin 33313-10-9 C9H17N3S2
    5-n-Heptylthio-1,3,4-thiadiazolyl-2-amin
    —— 3,5-bis-methylsulfanyl-6-phenylsulfanyl-[1,2,4]triazine 32331-00-3 C11H11N3S3
    3,5-bis-methylsulfanyl-6-phenylsulfanyl-[1,2,4]triazine
    —— 6-(4-chloro-phenyl)-3-methyl-7<i>H</i>-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 54025-90-0 C11H9ClN4S
    6-(4-chloro-phenyl)-3-methyl-7<i>H</i>-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-Methyl-7-phenylsulfanyl-6-p-tolyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 153235-50-8 C18H16N4S2
    3-Methyl-7-phenylsulfanyl-6-p-tolyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— β-Hydroxyethyl-β-hydroxyisopropyl-sulfid 39093-47-5 C5H12O2S
    β-Hydroxyethyl-β-hydroxyisopropyl-sulfid
    —— 3-methyl-(1:2:4)-triazolo-[3,4-b](1,3,4)thiadiazepino(6,7-3,2)quinoline 246221-76-1 C13H9N5S
    3-methyl-(1:2:4)-triazolo-[3,4-b](1,3,4)thiadiazepino(6,7-3,2)quinoline
    —— 7-(4-Chloro-phenylsulfanyl)-3-methyl-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 153235-46-2 C17H13ClN4S2
    7-(4-Chloro-phenylsulfanyl)-3-methyl-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— chloromethyl-(2-chloro-propyl)-sulfide 98023-00-8 C4H8Cl2S
    chloromethyl-(2-chloro-propyl)-sulfide