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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Benzylthio-1-methyl-1,2-dihydro-pyrimido<5,4-e>as-triazine 31791-01-2 C13H13N5S
    5-Benzylthio-1-methyl-1,2-dihydro-pyrimido<5,4-e>as-triazine
    —— (1S,3aS,7aR)-1-(hydroxymethyl)-7a-methylhexahydrospiro[indene-5,2'-[1,3]dithian]-3a(4H)-ol 162240-24-6 C14H24O2S2
    (1S,3aS,7aR)-1-(hydroxymethyl)-7a-methylhexahydrospiro[indene-5,2'-[1,3]dithian]-3a(4H)-ol
    —— (4-Amino-2,6-dimethyl-phenyl)-methyl-sulfid 90648-07-0 C9H13NS
    (4-Amino-2,6-dimethyl-phenyl)-methyl-sulfid
    —— Dimethylsulfonium-dichlorid 65082-58-8 C2H6Cl2S
    Dimethylsulfonium-dichlorid
    —— 1-Bromo-5-tert-butylsulfanyl-pentane 115412-81-2 C9H19BrS
    1-Bromo-5-tert-butylsulfanyl-pentane
    —— trans-3,4,4a,5,8,8a-hexahydro-7-methyl-5,5-bis(phenylthio)naphthalen-1(2H)-one 125846-86-8 C23H24OS2
    trans-3,4,4a,5,8,8a-hexahydro-7-methyl-5,5-bis(phenylthio)naphthalen-1(2H)-one
    —— trans-2-(2-methyl-2-propenyl)-3-<tris(phenylthio)methyl>cyclohexan-1-one 125846-83-5 C29H30OS3
    trans-2-(2-methyl-2-propenyl)-3-<tris(phenylthio)methyl>cyclohexan-1-one
    —— (2,6-Dimethyl-4-dimethylamino-phenyl)-methyl-sulfid 16463-14-2 C11H17NS
    (2,6-Dimethyl-4-dimethylamino-phenyl)-methyl-sulfid
    —— 2-methyl-3-<(phenylthio)methyl>-2-cyclopentenone 122190-10-7 C13H14OS
    2-methyl-3-<(phenylthio)methyl>-2-cyclopentenone
    —— trans-3-(2-methyl-2-propenyl)-4-<tris(phenylthio)methyl>-3,4,5,6-tetrahydropyran-2-one 125846-84-6 C28H28O2S3
    trans-3-(2-methyl-2-propenyl)-4-<tris(phenylthio)methyl>-3,4,5,6-tetrahydropyran-2-one
    —— 7-methyl-4-(phenylthio)-3,4-dihydronaphthalen-1(2H)-one 125846-89-1 C17H16OS
    7-methyl-4-(phenylthio)-3,4-dihydronaphthalen-1(2H)-one
    —— (5-Bromo-pentylsulfanyl)-cyclohexane 115412-82-3 C11H21BrS
    (5-Bromo-pentylsulfanyl)-cyclohexane
    —— trans-2-(2-methyl-2-propenyl)-3-<tris(phenylthio)methyl>cyclopentan-1-one 125846-82-4 C28H28OS3
    trans-2-(2-methyl-2-propenyl)-3-<tris(phenylthio)methyl>cyclopentan-1-one
    —— 4-phenyl-5,5,5-tri(phenylthio)pentan-2-one 56003-68-0 C29H26OS3
    4-phenyl-5,5,5-tri(phenylthio)pentan-2-one
    —— (Z)-1-(methylthio)-1-phenylthio-1-sulfinylmethane 188055-17-6 C8H8OS3
    (Z)-1-(methylthio)-1-phenylthio-1-sulfinylmethane
    —— trans-1-(phenylthio)-2-acetylcyclopropane 122190-11-8 C11H12OS
    trans-1-(phenylthio)-2-acetylcyclopropane
    —— 3-(Bis-phenylsulfanyl-methyl)-cyclohexanone 69814-21-7 C19H20OS2
    3-(Bis-phenylsulfanyl-methyl)-cyclohexanone
    —— (3S,4S,5R)-3-Methyl-4-<tris(phenylthio)methyl>-5-tridecyl-4,5-dihydro-2(3H)-furanone 165605-86-7 C37H48O2S3
    (3S,4S,5R)-3-Methyl-4-<tris(phenylthio)methyl>-5-tridecyl-4,5-dihydro-2(3H)-furanone
    —— (E)-3-(2-(phenylthio)vinyl)oxazolidin-2-one 1227929-11-4 C11H11NO2S
    (E)-3-(2-(phenylthio)vinyl)oxazolidin-2-one
    —— 4,4,4-tris(phenylthio)-3-methylbutanal 88130-74-9 C23H22OS3
    4,4,4-tris(phenylthio)-3-methylbutanal
    —— (Z)-3-(2-(phenylthio)vinyl)oxazolidin-2-one 1227929-12-5 C11H11NO2S
    (Z)-3-(2-(phenylthio)vinyl)oxazolidin-2-one
    —— (4S,5R)-5-Tridecyl-4-(tris-phenylsulfanyl-methyl)-dihydro-furan-2-one 1025911-12-9 C36H46O2S3
    (4S,5R)-5-Tridecyl-4-(tris-phenylsulfanyl-methyl)-dihydro-furan-2-one
    —— 2-phenyl-2-(5'-bromopentyl)-1,3-dithiane 144227-05-4 C15H21BrS2
    2-phenyl-2-(5'-bromopentyl)-1,3-dithiane
    —— 1-Chloro-3-(5-phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propan-2-ol 125707-66-6 C11H11ClN2O2S
    1-Chloro-3-(5-phenyl-[1,3,4]oxadiazol-2-ylsulfanyl)-propan-2-ol
    —— (S)-3-(tert-butyldimethylsiloxy)-6-(2-{(2R,3R)-2-(tert-butyldimethylsiloxy)-3-[(tert-butyldimethylsiloxy)methyl]pentyl}-1,3-dithiolan-2-yl)hexanal 1442440-26-7 C33H70O4S2Si3
    (S)-3-(tert-butyldimethylsiloxy)-6-(2-{(2R,3R)-2-(tert-butyldimethylsiloxy)-3-[(tert-butyldimethylsiloxy)methyl]pentyl}-1,3-dithiolan-2-yl)hexanal
    —— 2-[(S)-4-(tert-butyldimethylsiloxy)-5-(1,3-dithian-2-yl)pentyl]-2-{(2R,3R)-2-(tert-butyldimethylsiloxy)-3-[(tert-butyldimethylsiloxy)-methyl]pentyl}-1,3-dithiolane 1442440-25-6 C36H76O3S4Si3
    2-[(S)-4-(tert-butyldimethylsiloxy)-5-(1,3-dithian-2-yl)pentyl]-2-{(2R,3R)-2-(tert-butyldimethylsiloxy)-3-[(tert-butyldimethylsiloxy)-methyl]pentyl}-1,3-dithiolane
    —— (1,3-dithian-2-yl)(2-methyl-1,3-dithian-2-yl)methanone 1155851-71-0 C10H16OS4
    (1,3-dithian-2-yl)(2-methyl-1,3-dithian-2-yl)methanone
    —— 2-phenyl-2-(phenylethynyl)-1,3-dithiane 1155423-94-1 C18H16S2
    2-phenyl-2-(phenylethynyl)-1,3-dithiane
    —— 3,3-Dibromothietane 1,1-dioxide 59463-73-9 C3H4Br2O2S
    3,3-Dibromothietane 1,1-dioxide
    —— N-(3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenyl)acetamide 850663-90-0 C18H17N7O2S
    N-(3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenyl)acetamide
    —— N-(3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenyl)ethanethioamide 850663-89-7 C18H17N7OS2
    N-(3-{[2-(4-amino-furazan-3-yl)-1-ethyl-1H-imidazo[4,5-c]pyridin-6-yl]thio}phenyl)ethanethioamide
    —— 3,3,3-Trifluoro-1-trifluoromethanesulfonyl-2-trifluoromethyl-propene 55866-00-7 C5HF9O2S
    3,3,3-Trifluoro-1-trifluoromethanesulfonyl-2-trifluoromethyl-propene
    —— 6-(2-Methyl-3-phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane 200860-42-0 C17H24O2S
    6-(2-Methyl-3-phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane
    —— 1,5,6,10-tetrathiadecane 88300-05-4 C6H14S4
    1,5,6,10-tetrathiadecane
    —— 4-(benzylsulfanyl)-2-methylpyridine 147149-91-5 C13H13NS
    4-(benzylsulfanyl)-2-methylpyridine
    —— 1-(4-aminophenylthio)-3-chloropropan-2-ol 16781-11-6 C9H12ClNOS
    1-(4-aminophenylthio)-3-chloropropan-2-ol
    —— 1-phenylsulfonyl-2-(4-methoxybenzyl)-3-(phenylthio)-1H-indole 144465-22-5 C28H23NO3S2
    1-phenylsulfonyl-2-(4-methoxybenzyl)-3-(phenylthio)-1H-indole
    —— 4-(benzylsulfanyl)-2-methoxypyridine 147149-93-7 C13H13NOS
    4-(benzylsulfanyl)-2-methoxypyridine
    —— 4-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-4-oxo-butyric acid methyl ester 110984-30-0 C8H12N4O3S
    4-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-4-oxo-butyric acid methyl ester
    —— 4-[5-Amino-3-(4-chloro-benzylsulfanyl)-[1,2,4]triazol-1-yl]-4-oxo-butyric acid methyl ester 111020-83-8 C14H15ClN4O3S
    4-[5-Amino-3-(4-chloro-benzylsulfanyl)-[1,2,4]triazol-1-yl]-4-oxo-butyric acid methyl ester
    —— 3-(4-fluorophenyl)-6-(methylthio)-1,2,4,5-tetrazine 72116-57-5 C9H7FN4S
    3-(4-fluorophenyl)-6-(methylthio)-1,2,4,5-tetrazine
    —— ethyl 2-(4-chloro-2-(2-methoxy-2-oxoethyl)phenyl)-2-(phenylthio)acetate 1011458-44-8 C19H19ClO4S
    ethyl 2-(4-chloro-2-(2-methoxy-2-oxoethyl)phenyl)-2-(phenylthio)acetate
    —— 4-phenyl-2,2,6,6-tetrakis-trifluoromethyl-6<i>H</i>-[1,3,5]oxathiazine 57014-91-2 C13H5F12NOS
    4-phenyl-2,2,6,6-tetrakis-trifluoromethyl-6<i>H</i>-[1,3,5]oxathiazine
    —— 4,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane 170016-26-9 C10H22S7
    4,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane
    —— 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane 170016-27-0 C10H22S7
    5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane
    —— 3-phenylsulfanyl-2,3-dihydro-benzo[<i>b</i>]thiophene-1,1-dioxide 246168-99-0 C14H12O2S2
    3-phenylsulfanyl-2,3-dihydro-benzo[<i>b</i>]thiophene-1,1-dioxide
    —— 4-(2-Cyan-ethylmercapto)-pyridin 89977-36-6 C8H8N2S
    4-(2-Cyan-ethylmercapto)-pyridin
    —— 4-amino-3-(2-thien-2-oyl)vinylthio-1,2,4-triazol 138792-96-8 C9H8N4OS2
    4-amino-3-(2-thien-2-oyl)vinylthio-1,2,4-triazol
    —— 1,4-Dibromo-2-(3,7-dimethyl-octylsulfanyl)-benzene 908094-00-8 C16H24Br2S
    1,4-Dibromo-2-(3,7-dimethyl-octylsulfanyl)-benzene
    —— N-Cyclopropylthioacetamide 1182359-15-4 C5H9NS
    N-Cyclopropylthioacetamide