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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[3-chloro-4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione 38560-72-4 C15H9Cl2N3O2S
    2-[3-chloro-4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione
    —— 6-fluoro-1-benzothiophen-3(2H)-one 1098607-88-5 C8H5FOS
    6-fluoro-1-benzothiophen-3(2H)-one
    —— 1,3,10,12-tetrathia[3.3](2,6)pyridinophane 80693-51-2 C12H10N2S4
    1,3,10,12-tetrathia[3.3](2,6)pyridinophane
    —— 4-methylsulfanyl-benzamidine; hydrochloride —— C8H10N2S*ClH
    4-methylsulfanyl-benzamidine; hydrochloride
    —— 2,2,2-trifluoro-1-(2-p-tolylsulfanyl-thiazol-5-yl)-ethanone 915137-42-7 C12H8F3NOS2
    2,2,2-trifluoro-1-(2-p-tolylsulfanyl-thiazol-5-yl)-ethanone
    —— 5-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-3-nitro-pyridine 96592-36-8 C10H10N4O2S
    5-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-3-nitro-pyridine
    —— 2,2'-disulfanediylbis(N-methylethan-1-amine) dihydrochloride 15788-33-7 C6H16N2S2*2ClH
    2,2'-disulfanediylbis(N-methylethan-1-amine) dihydrochloride
    —— 4-(1-Methyl-1H-imidazol-2-ylsulfanyl)-3-nitro-pyridine 96592-25-5 C9H8N4O2S
    4-(1-Methyl-1H-imidazol-2-ylsulfanyl)-3-nitro-pyridine
    —— 1,2-bis-(3-phenylthiopropynyl)benzene 220316-70-1 C24H18S2
    1,2-bis-(3-phenylthiopropynyl)benzene
    —— methyl-1 (nitro-3 pyridyl-2)-thio-2 imidazole 96592-22-2 C9H8N4O2S
    methyl-1 (nitro-3 pyridyl-2)-thio-2 imidazole
    —— thiocarbamic acid <i>S</i>-heptyl ester 78961-04-3 C8H17NOS
    thiocarbamic acid <i>S</i>-heptyl ester
    —— (R)-2,2,2-trifluoro-N-[2-[4-[(4-hydroxyphenyl)thio]phenyl]-1-methylethyl]acetamide —— C21H22NO4Pol
    (R)-2,2,2-trifluoro-N-[2-[4-[(4-hydroxyphenyl)thio]phenyl]-1-methylethyl]acetamide
    —— 4-difluorochloromethylmercaptophenylisocyanate 52072-48-7 C8H4ClF2NOS
    4-difluorochloromethylmercaptophenylisocyanate
    —— 2-Isopropylsulfanyl-4-phenyl-thiazole 104942-39-4 C12H13NS2
    2-Isopropylsulfanyl-4-phenyl-thiazole
    —— 3,5-Dimethylthio-6-carbethoxy-as-triazin 31143-84-7 C8H11N3O2S2
    3,5-Dimethylthio-6-carbethoxy-as-triazin
    —— (4S,5S)-2-methyl-4-mesyloxymethyl-5-(4-methylsulfanylphenyl)-oxazoline 914477-57-9 C13H17NO4S2
    (4S,5S)-2-methyl-4-mesyloxymethyl-5-(4-methylsulfanylphenyl)-oxazoline
    —— 1,3-dimethyl-5-(1,2-propadienylthio)uracil 127802-09-9 C9H10N2O2S
    1,3-dimethyl-5-(1,2-propadienylthio)uracil
    —— 2-(tert-Butylthio)-N,N,3,trimethyl-4-pententhioamid 86318-80-1 C12H23NS2
    2-(tert-Butylthio)-N,N,3,trimethyl-4-pententhioamid
    —— 1,3-dimethyl-5-(2-propynylthio)uracil 127802-05-5 C9H10N2O2S
    1,3-dimethyl-5-(2-propynylthio)uracil
    —— (+/-)-N,N-dihexyl-5-hydroxy-6-{2-[2-(4-hydroxyphenyl)-ethyl]-[1,3]dithian-2-yl}-3-oxohexanamide 1051966-63-2 C30H49NO4S2
    (+/-)-N,N-dihexyl-5-hydroxy-6-{2-[2-(4-hydroxyphenyl)-ethyl]-[1,3]dithian-2-yl}-3-oxohexanamide
    —— 2-Phenylthio-5-chlorthiazol 33342-71-1 C9H6ClNS2
    2-Phenylthio-5-chlorthiazol
    —— 1,3-dimethyl-5-(1-propynylthio)uracil 127802-11-3 C9H10N2O2S
    1,3-dimethyl-5-(1-propynylthio)uracil
    —— ethyl 4-(5-bromo-4-(pyridin-2-ylthio)thiophen-2-yl)benzoate 1435937-37-3 C18H14BrNO2S2
    ethyl 4-(5-bromo-4-(pyridin-2-ylthio)thiophen-2-yl)benzoate
    —— 2,3-bis(methoxymethyl)-5,6-dihydro-1λ<sup>6</sup>,4λ<sup>6</sup>-dithiine-1,1,4,4-tetrone 1360762-22-6 C8H14O6S2
    2,3-bis(methoxymethyl)-5,6-dihydro-1λ<sup>6</sup>,4λ<sup>6</sup>-dithiine-1,1,4,4-tetrone
    —— 2H,3H,5H,6H,7H-1λ<sup>6</sup>,4λ<sup>6</sup>-cyclopenta[1λ<sup>6</sup>,4λ<sup>6</sup>]dithiine-1,1,4,4-tetrone 58951-30-7 C7H10O4S2
    2H,3H,5H,6H,7H-1λ<sup>6</sup>,4λ<sup>6</sup>-cyclopenta[1λ<sup>6</sup>,4λ<sup>6</sup>]dithiine-1,1,4,4-tetrone
    —— 3-[3-(4-vinyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester 944924-98-5 C24H36O3S
    3-[3-(4-vinyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester
    —— N-(n-decyloxythiocarbonyl)-N,N-dimethylamine 92120-32-6 C13H27NOS
    N-(n-decyloxythiocarbonyl)-N,N-dimethylamine
    —— 3-{3-[4-(methoxyimino-methyl)-tetrahydro-pyran-4-yl]-phenylsulfanyl}-propionic acid 2-ethyl-hexyl ester 944924-97-4 C24H37NO4S
    3-{3-[4-(methoxyimino-methyl)-tetrahydro-pyran-4-yl]-phenylsulfanyl}-propionic acid 2-ethyl-hexyl ester
    —— 3-[3-(4-acetyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester 944924-95-2 C24H36O4S
    3-[3-(4-acetyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester
    —— 3-[3-((2S,4R)-4-Hydroxy-2-methyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester 944925-01-3 C23H36O4S
    3-[3-((2S,4R)-4-Hydroxy-2-methyl-tetrahydro-pyran-4-yl)-phenylsulfanyl]-propionic acid 2-ethyl-hexyl ester
    —— 4-Aza-phenothiazin-10-carbonsaeure-1-diisopropylamino-propylester-3 101632-57-9 C21H27N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-1-diisopropylamino-propylester-3
    —— Trifluoro-methanesulfonic acid 6-methyl-8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester 1303510-47-5 C9H7F3N2O6S2
    Trifluoro-methanesulfonic acid 6-methyl-8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester
    —— N,N-diisopropyl-2-(phenylsulfanyl)acetamide 61698-72-4 C14H21NOS
    N,N-diisopropyl-2-(phenylsulfanyl)acetamide
    —— N-[5-(4-methoxy-phenylsulfanyl)-thiazol-2-yl]-3-pyridin-3-yl-propionamide 1384184-08-0 C18H17N3O2S2
    N-[5-(4-methoxy-phenylsulfanyl)-thiazol-2-yl]-3-pyridin-3-yl-propionamide
    —— 6-Hydroxymethyl-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine-2-thione 209917-57-7 C7H8OS5
    6-Hydroxymethyl-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine-2-thione
    —— 7-(2-Fluoro-4-trimethylsilanyl-phenylamino)-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one 1303510-48-6 C17H20FN3O3SSi
    7-(2-Fluoro-4-trimethylsilanyl-phenylamino)-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one
    —— (3R,4R,5R)-5-Pentyl-3-phenylsulfanylmethyl-4-vinyl-dihydro-furan-2-one 180982-32-5 C18H24O2S
    (3R,4R,5R)-5-Pentyl-3-phenylsulfanylmethyl-4-vinyl-dihydro-furan-2-one
    —— 3,4-Dihydro-3-hydroxy-2H-thiazino<3,2-a>imidazole 34035-41-1 C6H8N2OS
    3,4-Dihydro-3-hydroxy-2H-thiazino<3,2-a>imidazole
    —— 1-Chloro-3-(5-methyl-1H-[1,2,4]triazol-3-ylsulfanyl)-propan-2-ol 111014-64-3 C6H10ClN3OS
    1-Chloro-3-(5-methyl-1H-[1,2,4]triazol-3-ylsulfanyl)-propan-2-ol
    —— 7-methyl-3-hydroxy-1,2,4-triazolo<3,2-b>-1,3-thiazane 111014-70-1 C6H9N3OS
    7-methyl-3-hydroxy-1,2,4-triazolo<3,2-b>-1,3-thiazane
    —— 5,5'-dichloro-7,7'-dimethyl-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione 5462-29-3 C18H10Cl2O2S2
    5,5'-dichloro-7,7'-dimethyl-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione
    —— cis-1.2-Dibutylsulfon-ethen 876657-92-0 C10H20O4S2
    cis-1.2-Dibutylsulfon-ethen
    —— 3-nitro-2-(phenylthio)pyridine 4282-51-3 C11H8N2O2S
    3-nitro-2-(phenylthio)pyridine
    —— 1-Methyl-4-phenylsulfanyl-pyrrolidin-2-one 87884-53-5 C11H13NOS
    1-Methyl-4-phenylsulfanyl-pyrrolidin-2-one
    —— (E)-1,2-Di(n-butylthio)aethen 40661-41-4 C10H20S2
    (E)-1,2-Di(n-butylthio)aethen
    —— [2,2-bis(phenylthio)ethyl]dimethyl(1-phenethylbut-3-enyloxy)silane 332188-11-1 C28H34OS2Si
    [2,2-bis(phenylthio)ethyl]dimethyl(1-phenethylbut-3-enyloxy)silane
    —— 4-Phenylsulfanyl-dihydro-thiophen-2-one 87884-54-6 C10H10OS2
    4-Phenylsulfanyl-dihydro-thiophen-2-one
    —— 2-(3-pyridylmethylthio)-5-(4-pyridyl)-1,3,4-oxadiazole 557073-58-2 C13H10N4OS
    2-(3-pyridylmethylthio)-5-(4-pyridyl)-1,3,4-oxadiazole
    —— 1-phenylthio-2-trifluoroacetoxycyclohexane 98289-55-5 C14H15F3O2S
    1-phenylthio-2-trifluoroacetoxycyclohexane
    —— 2-Chloro-6-methylsulfanyl-phenol 66624-04-2 C7H7ClOS
    2-Chloro-6-methylsulfanyl-phenol