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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-tert-Butylsulfanyl-5-methyl-pyridine 18794-47-3 C10H15NS
    3-tert-Butylsulfanyl-5-methyl-pyridine
    —— (R)-5-(α-p-chlorophenylthio)acetoxy-1,1-dimethoxyhexane 158575-46-3 C16H23ClO4S
    (R)-5-(α-p-chlorophenylthio)acetoxy-1,1-dimethoxyhexane
    —— 2-methyl-5-(((3-(trifluoromethyl)thieno[3,4-b]pyrazin-2-yl)thio)methyl)-1,3,4-oxadiazole 1381779-33-4 C11H7F3N4OS2
    2-methyl-5-(((3-(trifluoromethyl)thieno[3,4-b]pyrazin-2-yl)thio)methyl)-1,3,4-oxadiazole
    —— 2-t-butylthio-3-methylpyridine 18833-87-9 C10H15NS
    2-t-butylthio-3-methylpyridine
    —— 10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-45-9 C18H11N3O2S
    10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 2-tert-Butylsulfanyl-5-methyl-pyridine 18794-46-2 C10H15NS
    2-tert-Butylsulfanyl-5-methyl-pyridine
    —— 7-cyano-2-hexylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one 112589-33-0 C12H14N4OS2
    7-cyano-2-hexylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one
    —— 2-(2-chloro-6-nitrophenylthio)-1-nitroimidazole 683276-71-3 C9H5ClN4O4S
    2-(2-chloro-6-nitrophenylthio)-1-nitroimidazole
    —— 7-phenyl-3-phenylsulfanylheptanoic acid hydroxyamide 193549-05-2 C19H23NO2S
    7-phenyl-3-phenylsulfanylheptanoic acid hydroxyamide
    —— 3-<3-(pentylthio)pyrazinyl>-1,2,5,6-tetrahydro-1-methylpyridine hydrochloride 138430-96-3 C15H23N3S*ClH
    3-<3-(pentylthio)pyrazinyl>-1,2,5,6-tetrahydro-1-methylpyridine hydrochloride
    —— 3.5-Dihydroxy-6-hexylmercapto-1.2.4-triazin 4956-08-5 C9H15N3O2S
    3.5-Dihydroxy-6-hexylmercapto-1.2.4-triazin
    —— 2-Chlorcyclopentyl-4-chlorphenylsulfid 99860-81-8 C11H12Cl2S
    2-Chlorcyclopentyl-4-chlorphenylsulfid
    —— 5-hydroxy-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-47-1 C18H11N3O3S
    5-hydroxy-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 7-methyl-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline 1451058-48-2 C19H13N3O2S
    7-methyl-10-nitro-8H-thiochromeno[2',3':4,5]imidazo[2,1-a]isoquinoline
    —— 3.5-Dihydroxy-6-butylmercapto-1.2.4-triazin 4968-47-2 C7H11N3O2S
    3.5-Dihydroxy-6-butylmercapto-1.2.4-triazin
    —— (4-Chloro-phenylsulfanyl)-acetic acid (R)-1-methyl-5-oxo-pentyl ester 158575-47-4 C14H17ClO3S
    (4-Chloro-phenylsulfanyl)-acetic acid (R)-1-methyl-5-oxo-pentyl ester
    —— 3.5-Dihydroxy-6-cyclohexylmercapto-1.2.4-triazin 90792-89-5 C9H13N3O2S
    3.5-Dihydroxy-6-cyclohexylmercapto-1.2.4-triazin
    —— N-Methyl-thiocarbamidsaeure-chlorid 867-51-6 C2H4ClNS
    N-Methyl-thiocarbamidsaeure-chlorid
    —— 6-cyano-2-heptylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one 112589-32-9 C13H16N4OS2
    6-cyano-2-heptylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidin-5-one
    —— 5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl decanoylcarbamate 196406-02-7 C26H37Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl decanoylcarbamate
    —— 1,7-diperfluorohexyl-4-[(hydrothio)methyl]heptane 1334164-80-5 C20H16F26S
    1,7-diperfluorohexyl-4-[(hydrothio)methyl]heptane
    —— 7-(2-Chloro-4-fluoro-phenylsulfanyl)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile 905435-06-5 C14H7ClFN3S3
    7-(2-Chloro-4-fluoro-phenylsulfanyl)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile
    —— 5-(Pyridin-2-ylsulfanylmethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 569649-46-3 C11H9NS6
    5-(Pyridin-2-ylsulfanylmethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— (R)-2-Amino-2-(2-(methylthio)phenyl)ethan-1-ol 1212933-22-6 C9H13NOS
    (R)-2-Amino-2-(2-(methylthio)phenyl)ethan-1-ol
    —— methyl 4,6-dimethyl-2-(phenylthio)benzoate 102736-34-5 C16H16O2S
    methyl 4,6-dimethyl-2-(phenylthio)benzoate
    —— 5-Methylmercapto-2-methyl-s-triazolo<3,4-b>-1,3,4-thiadiazol 14778-91-7 C5H6N4S2
    5-Methylmercapto-2-methyl-s-triazolo<3,4-b>-1,3,4-thiadiazol
    —— (3-amino-phenylsulfanyl)-acetic acid 100960-92-7 C8H9NO2S
    (3-amino-phenylsulfanyl)-acetic acid
    —— 5-hexyl-3-methyl-2-phenylthiofuran 110363-47-8 C17H22OS
    5-hexyl-3-methyl-2-phenylthiofuran
    —— n-Benzyl-1-[(4-bromophenyl)sulfanyl]-n-{[(4-bromophenyl)sulfanyl]methyl}methanamine 67857-78-7 C21H19Br2NS2
    n-Benzyl-1-[(4-bromophenyl)sulfanyl]-n-{[(4-bromophenyl)sulfanyl]methyl}methanamine
    —— 1-methylsulfanyl-2-(4-nitro-phenylsulfanyl)-benzene 107622-55-9 C13H11NO2S2
    1-methylsulfanyl-2-(4-nitro-phenylsulfanyl)-benzene
    —— 3-((6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid 948226-98-0 C7H8N2O3S
    3-((6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid
    —— 1-Chloro-3-(4,5-dimethyl-4H-[1,2,4]triazol-3-ylsulfanyl)-propan-2-ol 125707-64-4 C7H12ClN3OS
    1-Chloro-3-(4,5-dimethyl-4H-[1,2,4]triazol-3-ylsulfanyl)-propan-2-ol
    —— 3-methyl-2-phenylthio-5-propylfuran 110363-46-7 C14H16OS
    3-methyl-2-phenylthio-5-propylfuran
    —— n,n-Bis{[(4-chlorophenyl)sulfanyl]methyl}-2-methylpropan-2-amine 67857-77-6 C18H21Cl2NS2
    n,n-Bis{[(4-chlorophenyl)sulfanyl]methyl}-2-methylpropan-2-amine
    —— 5-(3,5-dichloro-phenylsulphanyl)-1-ethyl-3-methyl-1H-pyrazole-4-carbaldehyde 412327-40-3 C13H12Cl2N2OS
    5-(3,5-dichloro-phenylsulphanyl)-1-ethyl-3-methyl-1H-pyrazole-4-carbaldehyde
    —— 7-chloro-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine 1259513-96-6 C7H7ClN2S
    7-chloro-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine
    —— 2-(benzylthio)-3-(4,5-dihydroisoxazol-3-yl)pyridine 1161871-66-4 C15H14N2OS
    2-(benzylthio)-3-(4,5-dihydroisoxazol-3-yl)pyridine
    —— methyl 3-isopropylidene-2-(methylsulfonyl)bicyclo<2.2.1>hept-5-ene-2-carboxylate 130884-34-3 C13H18O4S
    methyl 3-isopropylidene-2-(methylsulfonyl)bicyclo<2.2.1>hept-5-ene-2-carboxylate
    —— 4-((1H-indol-3-yl)thio)aniline 32884-76-7 C14H12N2S
    4-((1H-indol-3-yl)thio)aniline
    —— <<(bromomethyl)sulfonyl>methylene>cycloheptane 102683-73-8 C9H15BrO2S
    <<(bromomethyl)sulfonyl>methylene>cycloheptane
    —— dimethyl (S)-3-t-butoxycarbonylamino-5-[2-chloro-4-(2-methoxymethoxy-5-trifluoromethylphenylthio)phenyl]-3-methyl-1-pentylphosphonate 1260512-36-4 C28H38ClF3NO7PS
    dimethyl (S)-3-t-butoxycarbonylamino-5-[2-chloro-4-(2-methoxymethoxy-5-trifluoromethylphenylthio)phenyl]-3-methyl-1-pentylphosphonate
    —— (4S,1'R,2'S)-4-2'-acetyl-1'-methylcyclobut-1,3-dioxolan-2-thione 173612-98-1 C10H14O3S
    (4S,1'R,2'S)-4-2'-acetyl-1'-methylcyclobut-1,3-dioxolan-2-thione
    —— dimethyl (S)-3-(((tert-butoxy)carbonyl)amino)-5-(2-chloro-4-(5-ethoxy-2-(methoxymethyloxy)phenylthio)phenyl)-3-propylpentylphosphonate 1383617-60-4 C31H47ClNO8PS
    dimethyl (S)-3-(((tert-butoxy)carbonyl)amino)-5-(2-chloro-4-(5-ethoxy-2-(methoxymethyloxy)phenylthio)phenyl)-3-propylpentylphosphonate
    —— N-(2-Methylallyl)-thioacetamid 6638-31-9 C6H11NS
    N-(2-Methylallyl)-thioacetamid
    —— (-)-(4S,1'R,2'S)-4-2'-1"-hydroxy-1"-methylethyl-1'-methylcyclobutyl-1,3-dioxolan-2-thione 153530-82-6 C11H18O3S
    (-)-(4S,1'R,2'S)-4-2'-1"-hydroxy-1"-methylethyl-1'-methylcyclobutyl-1,3-dioxolan-2-thione
    —— (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-trifluoromethylphenylthio)phenyl]-2-methylbutan-1-ol 1260512-33-1 C25H31ClF3NO5S
    (S)-2-t-butoxycarbonylamino-4-[2-chloro-4-(2-methoxymethoxy-5-trifluoromethylphenylthio)phenyl]-2-methylbutan-1-ol
    —— N-2-Methylpropenylthioacetamid 37109-54-9 C6H11NS
    N-2-Methylpropenylthioacetamid
    —— (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-(5-ethoxy-2-(methoxymethyloxy)phenylthio)phenyl}-2-propylbutan-1-ol 1383617-57-9 C28H40ClNO6S
    (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-(5-ethoxy-2-(methoxymethyloxy)phenylthio)phenyl}-2-propylbutan-1-ol
    —— N-(tert-Butyloxycarbonyl)-DL-dithioalanin-methylester 141041-85-2 C9H17NO2S2
    N-(tert-Butyloxycarbonyl)-DL-dithioalanin-methylester
    —— (-)-(4S,1'S,2'R)-4-2'-1"-hydroxy-1"-methylethyl-1'-methylcyclobutyl-1,3-dioxolan-2-thione 153610-34-5 C11H18O3S
    (-)-(4S,1'S,2'R)-4-2'-1"-hydroxy-1"-methylethyl-1'-methylcyclobutyl-1,3-dioxolan-2-thione