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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(benzylthio)-5-cyano-2-(2'-thienyl)pyrimidine 212621-35-7 C16H11N3S2
    4-(benzylthio)-5-cyano-2-(2'-thienyl)pyrimidine
    —— 4-Benzylsulfanyl-5-(4,5-dihydro-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine 212621-55-1 C18H15N3OS2
    4-Benzylsulfanyl-5-(4,5-dihydro-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine
    —— 5-ethylthio-5-(methoxycarbonylmethyl)-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-02-6 C13H19NO4S
    5-ethylthio-5-(methoxycarbonylmethyl)-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 2-ethoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole 445467-17-4 C12H14N4O5S
    2-ethoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole
    —— 2-methoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole 445467-16-3 C11H12N4O5S
    2-methoxycarbonylmethylsulfanyl-5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-1,3,4-oxadiazole
    —— 2-amino-3,4-dimethylphenyl-3-nitro-4-pyridinylsulfide 239791-57-2 C13H13N3O2S
    2-amino-3,4-dimethylphenyl-3-nitro-4-pyridinylsulfide
    —— 2-(methylthio)phenylphosphonic N,N,N',N'-tetramethyldiamidate 133617-49-9 C11H19N2OPS
    2-(methylthio)phenylphosphonic N,N,N',N'-tetramethyldiamidate
    —— Morpholine, 4-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)- 3562-89-8 C21H27ClN2OS
    Morpholine, 4-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)-
    —— 2,2'-(Methylimino)diethanol bismethanesulfonate picrylsulfonate 3545-53-7 C13H20N4O13S3
    2,2'-(Methylimino)diethanol bismethanesulfonate picrylsulfonate
    —— Pseudourea, 2,2',2''-(nitrilotriethylene)tris(2-thio-, tetrahydrobromide 3810-31-9 C9H25Br4N7S3
    Pseudourea, 2,2',2''-(nitrilotriethylene)tris(2-thio-, tetrahydrobromide
    —— 2-[4,5-dimethoxy-1,3-dithiol-2-ylidene]-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene 1313432-70-0 C12H8O2S8
    2-[4,5-dimethoxy-1,3-dithiol-2-ylidene]-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene
    —— (3-Cyano-4-furan-2-yl-5,6-dimethyl-pyridin-2-ylsulfanyl)-acetic acid ethyl ester 94639-44-8 C16H16N2O3S
    (3-Cyano-4-furan-2-yl-5,6-dimethyl-pyridin-2-ylsulfanyl)-acetic acid ethyl ester
    —— 2-phenoxycarbonylamino-5-phenylsulphanyl-1H-indole-3-carbonitrile 378236-69-2 C22H15N3O2S
    2-phenoxycarbonylamino-5-phenylsulphanyl-1H-indole-3-carbonitrile
    —— Benzimidazole, 2-(p-cumenylthio)-1-(2-(diethylamino)ethyl)-, dipicrate 4929-62-8 C34H35N9O14S
    Benzimidazole, 2-(p-cumenylthio)-1-(2-(diethylamino)ethyl)-, dipicrate
    —— 1-phenylsulfonyl-2-(2,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole 1150111-65-1 C29H25NO4S2
    1-phenylsulfonyl-2-(2,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole
    —— Piperidine, 1-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)- 3626-70-8 C22H29ClN2S
    Piperidine, 1-(3-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)propyl)-
    —— 1-phenylsulfonyl-2-(3,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole 144465-23-6 C29H25NO4S2
    1-phenylsulfonyl-2-(3,4-dimethoxybenzyl)-3-(phenylthio)-1H-indole
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-(4-methoxy-phenyl)-amine 171618-49-8 C28H24N2O3S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-(4-methoxy-phenyl)-amine
    —— (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine 171618-48-7 C28H24N2O2S2
    (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine
    —— 2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole 1372674-47-9 C29H22BrNO2S2
    2-(3-bromo-3-phenylallyl)-1-(phenylsulfonyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(3,4-dimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-63-9 C29H25NO2S2
    1-phenylsulfonyl-2-(3,4-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— (3-Phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine 171618-51-2 C22H20N2S
    (3-Phenylsulfanyl-1H-indol-2-ylmethyl)-p-tolyl-amine
    —— 1-phenylsulfonyl-3-(phenylthio)-2-((thiophen-2-yl)methyl)-1H-indole 1150111-68-4 C25H19NO2S3
    1-phenylsulfonyl-3-(phenylthio)-2-((thiophen-2-yl)methyl)-1H-indole
    —— (4-Methoxy-phenyl)-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 171618-52-3 C22H20N2OS
    (4-Methoxy-phenyl)-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine
    —— N-(3-Phenylsulfanyl-1H-indol-2-ylmethyl)-N-p-tolyl-acetamide 171618-55-6 C24H22N2OS
    N-(3-Phenylsulfanyl-1H-indol-2-ylmethyl)-N-p-tolyl-acetamide
    —— N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]acetamide 1227373-10-5 C23H20N2O3S2
    N-[(1-(phenylsulfonyl)-3-(phenylthio)-1H-indol-2-yl)methyl]acetamide
    —— N-(4-Methoxy-phenyl)-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide 171618-56-7 C24H22N2O2S
    N-(4-Methoxy-phenyl)-N-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-acetamide
    —— 1-phenylsulfonyl-2-(2,4-dimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-64-0 C29H25NO2S2
    1-phenylsulfonyl-2-(2,4-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(2,4,6-trimethylbenzyl)-3-(phenylthio)-1H-indole 1150111-66-2 C30H27NO2S2
    1-phenylsulfonyl-2-(2,4,6-trimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-phenylsulfonyl-2-(2,5-dimethylbenzyl)-3-(phenylthio)-1H-indole 870639-67-1 C29H25NO2S2
    1-phenylsulfonyl-2-(2,5-dimethylbenzyl)-3-(phenylthio)-1H-indole
    —— 1-Benzenesulfonyl-2-(4-bromo-2,5-dimethoxy-benzyl)-3-phenylsulfanyl-1H-indole 144465-25-8 C29H24BrNO4S2
    1-Benzenesulfonyl-2-(4-bromo-2,5-dimethoxy-benzyl)-3-phenylsulfanyl-1H-indole
    —— 2-((3-aminophenyl)thio)ethanol 27122-79-8 C8H11NOS
    2-((3-aminophenyl)thio)ethanol
    —— 1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine 110744-29-1 C14H8ClN3S
    1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine
    —— Methylsulfinylmethylacetat 13921-25-0 C4H8O3S
    Methylsulfinylmethylacetat
    —— (1-Benzenesulfonyl-5-methoxy-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phosphonic acid diethyl ester 98055-15-3 C26H28NO6PS2
    (1-Benzenesulfonyl-5-methoxy-3-phenylsulfanyl-1H-indol-2-ylmethyl)-phosphonic acid diethyl ester
    —— 3-ethyl-7,8,9,10,11,11a-hexahydro-6<i>H</i>-cycloocta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-37-9 C12H18N4S
    3-ethyl-7,8,9,10,11,11a-hexahydro-6<i>H</i>-cycloocta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 6-(5-Methoxy-3-phenylsulfanyl-1H-indol-2-yl)-5H-[1,3]dioxolo[4,5-f]indole 156749-38-1 C24H18N2O3S
    6-(5-Methoxy-3-phenylsulfanyl-1H-indol-2-yl)-5H-[1,3]dioxolo[4,5-f]indole
    —— 2-Methylthio-4-methyl-imidazol 14395-85-8 C5H8N2S
    2-Methylthio-4-methyl-imidazol
    —— 1,4-bis(5-amino-6-cyano-2-oxo-thiopyrano[2,3-d]thiazolyl)benzene 1019848-49-7 C20H12N6O2S4
    1,4-bis(5-amino-6-cyano-2-oxo-thiopyrano[2,3-d]thiazolyl)benzene
    —— 2-ethylthio-2-methyl-5-phenyltetrahydrofuran 164113-08-0 C13H18OS
    2-ethylthio-2-methyl-5-phenyltetrahydrofuran
    —— 2-{[2-chloro-4-(methylsulfonyl)phenyl]thio}-4-fluorophenol 847148-90-7 C13H10ClFO3S2
    2-{[2-chloro-4-(methylsulfonyl)phenyl]thio}-4-fluorophenol
    —— 1,4-bis[6-ethoxycarbonyl-2-oxo-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazolyl]benzene 1019848-47-5 C24H24N2O6S4
    1,4-bis[6-ethoxycarbonyl-2-oxo-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazolyl]benzene
    —— Trimethylstannanylium;thiocyanate —— C4H9NSSn
    Trimethylstannanylium;thiocyanate
    —— 5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-2-methylsulfanyl-1,3,4-oxadiazole 445467-14-1 C9H10N4O3S
    5-(6-methyl-2,4-dioxo-1,2,3,4-tetrahydro-3-pyrimidinyl)-methyl-2-methylsulfanyl-1,3,4-oxadiazole
    —— 2-<4-(phenylthio)phenyl>ethanol 102293-53-8 C14H14OS
    2-<4-(phenylthio)phenyl>ethanol
    —— Chloro-[2-(4-phenylsulfanyl-phenyl)-ethylsulfanyl]-acetic acid ethyl ester 107291-87-2 C18H19ClO2S2
    Chloro-[2-(4-phenylsulfanyl-phenyl)-ethylsulfanyl]-acetic acid ethyl ester
    —— ethyl <4-(phenylthio)phenyl>acetate 74002-18-9 C16H16O2S
    ethyl <4-(phenylthio)phenyl>acetate
    —— 7-Phenylsulfanyl-isothiochroman-1-carboxylic acid ethyl ester 107291-95-2 C18H18O2S2
    7-Phenylsulfanyl-isothiochroman-1-carboxylic acid ethyl ester
    —— 4-(benzylthio)-1H-1,2,3-triazole —— C9H9N3S
    4-(benzylthio)-1H-1,2,3-triazole
    —— 5-Benzylsulfanyl-1H-[1,2,3]triazole 79100-69-9 C9H9N3S
    5-Benzylsulfanyl-1H-[1,2,3]triazole