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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-methoxy-3-[(4-methylphenyl)thio]indole 889129-56-0 C16H15NOS
    6-methoxy-3-[(4-methylphenyl)thio]indole
    —— 3-((4-chlorophenyl)thio)-6-methoxy-1H-indole 1224875-73-3 C15H12ClNOS
    3-((4-chlorophenyl)thio)-6-methoxy-1H-indole
    —— (E)-(3-hexylnon-1-enyl)(phenyl)sulfane 1393672-37-1 C21H34S
    (E)-(3-hexylnon-1-enyl)(phenyl)sulfane
    —— (E)-2-((3-hexylnon-1-en-1-yl)thio)ethanol 1393672-41-7 C17H34OS
    (E)-2-((3-hexylnon-1-en-1-yl)thio)ethanol
    —— (E)-tert-butyl(3-hexylnon-1-en-1-yl)sulfane 1393672-39-3 C19H38S
    (E)-tert-butyl(3-hexylnon-1-en-1-yl)sulfane
    —— 2-Benzylsulfanyl-4-tert-butoxy-pyrimidine 497944-59-9 C15H18N2OS
    2-Benzylsulfanyl-4-tert-butoxy-pyrimidine
    —— 6-bromo-2,3-dihydro-7-methyl-5H-thiazolo<3,2-a>pyrimidin-5-one 111730-47-3 C7H7BrN2OS
    6-bromo-2,3-dihydro-7-methyl-5H-thiazolo<3,2-a>pyrimidin-5-one
    —— 2-Benzylsulfanyl-3-isopropyl-3H-pyrimidin-4-one 497944-65-7 C14H16N2OS
    2-Benzylsulfanyl-3-isopropyl-3H-pyrimidin-4-one
    —— 3-(phenylthio)-2,4,7,7a-tetrahydrobenzothiophene 1,1-dioxide 1268357-04-5 C14H14O2S2
    3-(phenylthio)-2,4,7,7a-tetrahydrobenzothiophene 1,1-dioxide
    —— (E)-5-Phenylsulfanyl-pent-4-enenitrile 104260-99-3 C11H11NS
    (E)-5-Phenylsulfanyl-pent-4-enenitrile
    —— 2-(4-bromophenyl)-2-(phenylsulfanyl)cyclohept-4-enone 878480-55-8 C19H17BrOS
    2-(4-bromophenyl)-2-(phenylsulfanyl)cyclohept-4-enone
    —— Allylthiocarbaminsaeure-isopropylester 76014-84-1 C7H13NOS
    Allylthiocarbaminsaeure-isopropylester
    —— (E)-3-(2-cyanovinyl)-9,10-dimethoxy-4-oxo-2-(phenylthio)-6,7-dihydro-4H-pyrido[2,1-a]isoquinoline-1-carbonitrile 1463869-15-9 C25H19N3O3S
    (E)-3-(2-cyanovinyl)-9,10-dimethoxy-4-oxo-2-(phenylthio)-6,7-dihydro-4H-pyrido[2,1-a]isoquinoline-1-carbonitrile
    —— 1-bromo-1-(methylsulfonyl)propan-2-one 1271024-83-9 C4H7BrO3S
    1-bromo-1-(methylsulfonyl)propan-2-one
    —— 2-Cyano-2-N,N-dimethylcarbamoyl-5-isopropylthio-1,3-dithiane 126832-94-8 C11H18N2OS3
    2-Cyano-2-N,N-dimethylcarbamoyl-5-isopropylthio-1,3-dithiane
    —— [4-(4,6-diamino-2-methylsulfanyl-pyrimidin-5-ylazo)-phenyl]-arsonic acid 17174-29-7 C11H13AsN6O3S
    [4-(4,6-diamino-2-methylsulfanyl-pyrimidin-5-ylazo)-phenyl]-arsonic acid
    —— 5-((4-chlorophenylthio)methyl)pyridazin-3(2H)-one 1243253-41-9 C11H9ClN2OS
    5-((4-chlorophenylthio)methyl)pyridazin-3(2H)-one
    —— 2-((4-chlorophenyl)thio)butanoic acid 155748-59-7 C10H11ClO2S
    2-((4-chlorophenyl)thio)butanoic acid
    —— 3-(3-bromo-phenylsulfanyl)-6-chloro-1H-indole 1359982-48-1 C14H9BrClNS
    3-(3-bromo-phenylsulfanyl)-6-chloro-1H-indole
    —— (-)-(S)-2-(4-Chlorothiophenoxy)butanoic acid 176021-34-4 C10H11ClO2S
    (-)-(S)-2-(4-Chlorothiophenoxy)butanoic acid
    —— ethyl 2-(p-chlorophenylthio)-2-fluorobutanoate 380859-98-3 C12H14ClFO2S
    ethyl 2-(p-chlorophenylthio)-2-fluorobutanoate
    —— Diethyl {4-[(2-amino-5-bromophenyl)thio]butyl}phosphonate 288073-37-0 C14H23BrNO3PS
    Diethyl {4-[(2-amino-5-bromophenyl)thio]butyl}phosphonate
    —— (1R<sup>*</sup>,3aS<sup>*</sup>,8b<sup>R*</sup>)-Methyl 1-<2-(2'',2''-Dimethoxyethyl)-1,3-dithian-2-yl>-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>-difuran-3a-carboxylate 145746-32-3 C20H30O6S2
    (1R<sup>*</sup>,3aS<sup>*</sup>,8b<sup>R*</sup>)-Methyl 1-<2-(2'',2''-Dimethoxyethyl)-1,3-dithian-2-yl>-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>-difuran-3a-carboxylate
    —— Methyl 2-<2'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>ethoxymethyl>propenoate 145746-21-0 C21H40O6S2Si
    Methyl 2-<2'-tert-Butyldimethylsiloxy-1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>ethoxymethyl>propenoate
    —— 2-[2,2-Bis(sulfanylmethyl)-1,3-dithian-5-ylidene]hydrazinecarboxamide 4085-04-5 C7H13N3OS4
    2-[2,2-Bis(sulfanylmethyl)-1,3-dithian-5-ylidene]hydrazinecarboxamide
    —— 4,6-dichloro-2-(ethylthio)pyrimidine 68498-47-5 C6H6Cl2N2S
    4,6-dichloro-2-(ethylthio)pyrimidine
    —— 4-chloro-7-methoxy-10<i>H</i>-pyrido[2,3-<i>b</i>]pyrimido[4,5-<i>e</i>][1,4]thiazin-2-ylamine 63931-20-4 C10H8ClN5OS
    4-chloro-7-methoxy-10<i>H</i>-pyrido[2,3-<i>b</i>]pyrimido[4,5-<i>e</i>][1,4]thiazin-2-ylamine
    —— 3-(methylthio)-5-(pyridin-4-yl)isoxazole 120803-22-7 C9H8N2OS
    3-(methylthio)-5-(pyridin-4-yl)isoxazole
    —— 4-[(4-chlorophenyl)thio]-N-hydroxybutanamide 59513-54-1 C10H12ClNO2S
    4-[(4-chlorophenyl)thio]-N-hydroxybutanamide
    —— 2-[2-fluoro-4-(methylthio)phenyl]-5-[(1-{1-[3-(1-methylethyl)-1,2,4-oxadiazol-5-yl]-4-piperidinyl}ethyl)oxy]pyrazine 1032825-61-8 C23H28FN5O2S
    2-[2-fluoro-4-(methylthio)phenyl]-5-[(1-{1-[3-(1-methylethyl)-1,2,4-oxadiazol-5-yl]-4-piperidinyl}ethyl)oxy]pyrazine
    —— α-Methylsulfonylmethyl-acrylsaeure 36525-60-7 C5H8O4S
    α-Methylsulfonylmethyl-acrylsaeure
    —— isobutyl chloromethyl sulfoxide 77407-41-1 C5H11ClOS
    isobutyl chloromethyl sulfoxide
    —— N-[2-[(2,4-difluorophenyl)thio]-4-oxoquinazolin-3(4H)-yl]methanesulfonamide 1018471-52-7 C15H11F2N3O3S2
    N-[2-[(2,4-difluorophenyl)thio]-4-oxoquinazolin-3(4H)-yl]methanesulfonamide
    —— (2E)-Methyl 3-<Dimethyl(phenyl)silyl>-2-<(E)-1'-<2''-(1,3-dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>-3'-methyl-4'-oxopent-2'-enyloxymethyl>propenoate 145746-28-7 C28H40O6S2Si
    (2E)-Methyl 3-<Dimethyl(phenyl)silyl>-2-<(E)-1'-<2''-(1,3-dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>-3'-methyl-4'-oxopent-2'-enyloxymethyl>propenoate
    —— 1-Methyl-4-thia-3,9,10a-triaza-benzo[f]azulen-10-ol 81382-63-0 C11H9N3OS
    1-Methyl-4-thia-3,9,10a-triaza-benzo[f]azulen-10-ol
    —— 2-methyl-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine 81382-79-8 C16H19N5S
    2-methyl-5-(4-methyl-1-piperazinyl)imidazo<2,1-b><1,3,5>benzothiadiazepine
    —— triethylammonium (4-chlorophenylthio)difluoromethanesulfonate 744221-74-7 C6H15N*C7H5ClF2O3S2
    triethylammonium (4-chlorophenylthio)difluoromethanesulfonate
    —— 2-methylimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-one 87011-02-7 C11H9N3OS
    2-methylimidazo<2,1-b><1,3,5>benzothiadiazepine-5(6H)-one
    —— 1-<2-(4-methyl-2-imidazolyl)thiophenyliminocarbonyl>-4-methylpiperazine 81382-64-1 C16H21N5OS
    1-<2-(4-methyl-2-imidazolyl)thiophenyliminocarbonyl>-4-methylpiperazine
    —— 3-(3-Isoxazolyl)-2-thiophenesulfonylisocyanate 103092-74-6 C8H4N2O4S2
    3-(3-Isoxazolyl)-2-thiophenesulfonylisocyanate
    —— 4-methyl-2-(2-aminophenylthio)imidazole 88251-73-4 C10H11N3S
    4-methyl-2-(2-aminophenylthio)imidazole
    —— 3-(4-chlorobenzyl)-2-methylthio-5-(morpholino)pyrimidine-4(3H)-one 1359818-39-5 C16H18ClN3O2S
    3-(4-chlorobenzyl)-2-methylthio-5-(morpholino)pyrimidine-4(3H)-one
    —— 5-(t-butoxycarbonyl)amino-3-(4-chlorobenzyl)-2-(methylthio)pyrimidine-4(3H)-one 1359818-40-8 C17H20ClN3O3S
    5-(t-butoxycarbonyl)amino-3-(4-chlorobenzyl)-2-(methylthio)pyrimidine-4(3H)-one
    —— 5-amino-3-(4-chlorobenzyl)-2-(methylthio)pyrimidine-4(3H)-one 1359818-41-9 C12H12ClN3OS
    5-amino-3-(4-chlorobenzyl)-2-(methylthio)pyrimidine-4(3H)-one
    —— Oct-6-yne-1-thiol 77213-95-7 C8H14S
    Oct-6-yne-1-thiol
    —— 6-(4-chloro-phenylsulfanyl)-hexylamine 149599-92-8 C12H18ClNS
    6-(4-chloro-phenylsulfanyl)-hexylamine
    —— 1,1,2-trifluoro-2-(p-chlorophenylthio)propane 817562-59-7 C9H8ClF3S
    1,1,2-trifluoro-2-(p-chlorophenylthio)propane
    —— 1.6-Bis-(2.6-dichlor-benzylmercapto)-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13616-23-4 C22H12Cl4N4S4
    1.6-Bis-(2.6-dichlor-benzylmercapto)-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— 3-chloro-2-(2,4-dichlorophenylthio)-N-methyl-sulphonyl-aniline 210823-47-5 C13H10Cl3NO2S2
    3-chloro-2-(2,4-dichlorophenylthio)-N-methyl-sulphonyl-aniline
    —— 1,4-Bis<(2-chloroethyl)thio>-2,3,5,6-tetrafluorobenzene 16956-51-7 C10H8Cl2F4S2
    1,4-Bis<(2-chloroethyl)thio>-2,3,5,6-tetrafluorobenzene