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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Aminocyclobutane-1-thiol--hydrogen chloride (1/1) 38238-24-3 C4H10ClNS
    2-Aminocyclobutane-1-thiol--hydrogen chloride (1/1)
    —— N,N'-[Disulfanediyldi(ethane-2,1-diyl)]bis(2-cyclohexylbutan-1-amine)--hydrogen chloride (1/2) 38920-72-8 C24H50Cl2N2S2
    N,N'-[Disulfanediyldi(ethane-2,1-diyl)]bis(2-cyclohexylbutan-1-amine)--hydrogen chloride (1/2)
    —— (trans)-2-Mercaptocyclobutylamine hydrochloride 38238-25-4 C4H10ClNS
    (trans)-2-Mercaptocyclobutylamine hydrochloride
    —— 2,2'-Disulfanediylbis[N-(cyclooctylmethyl)ethanimidamide]--hydrogen chloride (1/2) 40284-21-7 C22H44Cl2N4S2
    2,2'-Disulfanediylbis[N-(cyclooctylmethyl)ethanimidamide]--hydrogen chloride (1/2)
    —— 2,2'-Disulfanediylbis(N-{2-[4-(tert-butylsulfanyl)phenyl]ethyl}ethanimidamide)--hydrogen chloride (1/2) 40284-25-1 C28H44Cl2N4S4
    2,2'-Disulfanediylbis(N-{2-[4-(tert-butylsulfanyl)phenyl]ethyl}ethanimidamide)--hydrogen chloride (1/2)
    —— 2,2'-Disulfanediylbis[N-(cyclopentylmethyl)ethanimidamide]--hydrogen chloride (1/2) 40284-17-1 C16H32Cl2N4S2
    2,2'-Disulfanediylbis[N-(cyclopentylmethyl)ethanimidamide]--hydrogen chloride (1/2)
    —— 2,2'-Disulfanediylbis[N-(2-cycloheptylethyl)ethanimidamide]--hydrogen chloride (1/2) 40284-20-6 C22H44Cl2N4S2
    2,2'-Disulfanediylbis[N-(2-cycloheptylethyl)ethanimidamide]--hydrogen chloride (1/2)
    —— Pyridazine, 3-chloro-4-(2-chloro-1,1-dimethylethyl)-6-(ethylthio)- 124420-47-9 C10H14Cl2N2S
    Pyridazine, 3-chloro-4-(2-chloro-1,1-dimethylethyl)-6-(ethylthio)-
    —— 5-((p-((2-Chloropropyl)ethylamino)phenyl)thio)-2,4-dinitrobenzamide 32868-91-0 C18H19ClN4O5S
    5-((p-((2-Chloropropyl)ethylamino)phenyl)thio)-2,4-dinitrobenzamide
    —— Bis(methylsulfanyl)-lambda~2~-plumbane —— C2H6PbS2
    Bis(methylsulfanyl)-lambda~2~-plumbane
    —— 1-Butanesulfinic acid, 4,4'-dithiobis-, disodium salt 34915-82-7 C8H16Na2O4S4
    1-Butanesulfinic acid, 4,4'-dithiobis-, disodium salt
    —— 4-(1-Hydroxy-3-{[3-(phenylsulfanyl)propyl]amino}propyl)phenol--hydrogen chloride (1/1) 34920-64-4 C18H24ClNO2S
    4-(1-Hydroxy-3-{[3-(phenylsulfanyl)propyl]amino}propyl)phenol--hydrogen chloride (1/1)
    —— BENZAMIDE, 5-((p-(BIS(2-BROMOETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO- 32868-88-5 C17H16Br2N4O5S
    BENZAMIDE, 5-((p-(BIS(2-BROMOETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO-
    —— diethyl-(bis-diethylthiocarbamoylmercapto-[1,3,5]triazin-2-yl)-amine 30863-11-7 C17H30N6S4
    diethyl-(bis-diethylthiocarbamoylmercapto-[1,3,5]triazin-2-yl)-amine
    —— BENZAMIDE, 5-((p-(BIS(2-IODOETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO- 32869-04-8 C17H16I2N4O5S
    BENZAMIDE, 5-((p-(BIS(2-IODOETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO-
    —— ACETAMIDE, 2-(o-TOLYLTHIO)- 32175-45-4 C9H11NOS
    ACETAMIDE, 2-(o-TOLYLTHIO)-
    —— 2-chloro-4,6-bis-dimethylthiocarbamoylsulfanyl-[1,3,5]triazine 30863-05-9 C9H12ClN5S4
    2-chloro-4,6-bis-dimethylthiocarbamoylsulfanyl-[1,3,5]triazine
    —— BENZAMIDE, 5-((p-(BIS(2-CHLOROETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO- 32868-87-4 C17H16Cl2N4O5S
    BENZAMIDE, 5-((p-(BIS(2-CHLOROETHYL)AMINO)PHENYL)THIO)-2,4-DINITRO-
    —— 2,4-Dibromo-6-phenylsulfanyl-1,3,5-triazine 30894-97-4 C9H5Br2N3S
    2,4-Dibromo-6-phenylsulfanyl-1,3,5-triazine
    —— N-methyl-4-(trichloromethyl)-6-(2,4,5-trichlorophenyl)sulfanyl-1,3,5-triazin-2-amine 30369-63-2 C11H6Cl6N4S
    N-methyl-4-(trichloromethyl)-6-(2,4,5-trichlorophenyl)sulfanyl-1,3,5-triazin-2-amine
    —— 4-(4-chlorophenyl)sulfanyl-N-ethyl-6-(trichloromethyl)-1,3,5-triazin-2-amine 30369-59-6 C12H10Cl4N4S
    4-(4-chlorophenyl)sulfanyl-N-ethyl-6-(trichloromethyl)-1,3,5-triazin-2-amine
    —— 2-chloro-4,6-bis-diethylthiocarbamoylsulfanyl-[1,3,5]triazine 30863-06-0 C13H20ClN5S4
    2-chloro-4,6-bis-diethylthiocarbamoylsulfanyl-[1,3,5]triazine
    —— 4-(4-chlorophenyl)sulfanyl-N-propan-2-yl-6-(trichloromethyl)-1,3,5-triazin-2-amine 30369-60-9 C13H12Cl4N4S
    4-(4-chlorophenyl)sulfanyl-N-propan-2-yl-6-(trichloromethyl)-1,3,5-triazin-2-amine
    —— 4-(2,4-Dichlorophenyl)sulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine 30576-31-9 C10H5Cl5N4S
    4-(2,4-Dichlorophenyl)sulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine
    —— (4,6-Dithiocyanato-1,3,5-triazin-2-yl) thiocyanate 30863-24-2 C6N6S3
    (4,6-Dithiocyanato-1,3,5-triazin-2-yl) thiocyanate
    —— 4-Phenylsulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine 30369-55-2 C10H7Cl3N4S
    4-Phenylsulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine
    —— N-methyl-4-phenylsulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine 30369-56-3 C11H9Cl3N4S
    N-methyl-4-phenylsulfanyl-6-(trichloromethyl)-1,3,5-triazin-2-amine
    —— 2-(2-chloro-anilino)-4,6-bis-thiocyanato-[1,3,5]triazine 30362-24-4 C11H5ClN6S2
    2-(2-chloro-anilino)-4,6-bis-thiocyanato-[1,3,5]triazine
    —— 4-Chloro-6-phenylsulfanyl-1,3,5-triazin-2-amine 30357-97-2 C9H7ClN4S
    4-Chloro-6-phenylsulfanyl-1,3,5-triazin-2-amine
    —— 2-(4-chloro-3-nitro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine 24478-15-7 C11H3Cl7N4O2S
    2-(4-chloro-3-nitro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine
    —— 2-(3-chloro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine 24478-07-7 C11H4Cl7N3S
    2-(3-chloro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine
    —— 2-(2,4-dichloro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine 24478-09-9 C11H3Cl8N3S
    2-(2,4-dichloro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine
    —— 2-<i>o</i>-tolylsulfanyl-4,6-bis-trichloromethyl-[1,3,5]triazine 24477-99-4 C12H7Cl6N3S
    2-<i>o</i>-tolylsulfanyl-4,6-bis-trichloromethyl-[1,3,5]triazine
    —— 2-(4-nitro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine 24478-14-6 C11H4Cl6N4O2S
    2-(4-nitro-phenylsulfanyl)-4,6-bis-trichloromethyl-[1,3,5]triazine
    —— 2,2',2''-(Methanetriyltrisulfanediyl)tri(ethan-1-amine)--hydrogen chloride (1/3) 22907-46-6 C7H22Cl3N3S3
    2,2',2''-(Methanetriyltrisulfanediyl)tri(ethan-1-amine)--hydrogen chloride (1/3)
    —— 2,2'-[Methylenebis(thio)]bisethanamine Dihydrochloride 22965-82-8 C5H16Cl2N2S2
    2,2'-[Methylenebis(thio)]bisethanamine Dihydrochloride
    —— Bis[(2-aminoethyl)sulfanyl]acetic acid--hydrogen chloride (1/2) 22907-45-5 C6H16Cl2N2O2S2
    Bis[(2-aminoethyl)sulfanyl]acetic acid--hydrogen chloride (1/2)
    —— Diethyl bis[(2-aminoethyl)sulfanyl]propanedioate--hydrogen chloride (1/2) 22907-49-9 C11H24Cl2N2O4S2
    Diethyl bis[(2-aminoethyl)sulfanyl]propanedioate--hydrogen chloride (1/2)
    —— (Carboxamidinium)-methyl-disulfid 44957-28-0 C4H10N4S2
    (Carboxamidinium)-methyl-disulfid
    —— 1,1-Aethylendithio-3-methyl-cyclohexan 17482-40-5 C9H16S2
    1,1-Aethylendithio-3-methyl-cyclohexan
    —— S-Methyl O-(2-methylcyclohexyl) dithiocarbonate 15288-12-7 C9H16OS2
    S-Methyl O-(2-methylcyclohexyl) dithiocarbonate
    —— (3-Hydroxypropyl)trimethylammonium iodide (o-(benzylthio)phenyl)acetate 14200-08-9 C21H28INO2S
    (3-Hydroxypropyl)trimethylammonium iodide (o-(benzylthio)phenyl)acetate
    —— 2-(Dimethylamino)ethyl [2-(benzylsulfanyl)phenyl]acetate--hydrogen chloride (1/1) 14200-07-8 C19H24ClNO2S
    2-(Dimethylamino)ethyl [2-(benzylsulfanyl)phenyl]acetate--hydrogen chloride (1/1)
    —— 4-Chlor-6-phenyl-1,3,5,-triazin-yl-(2)-N,N-diethyl-dithiocarbamat 13733-97-6 C14H15ClN4S2
    4-Chlor-6-phenyl-1,3,5,-triazin-yl-(2)-N,N-diethyl-dithiocarbamat
    —— Pyridazine, 3-chloro-4-(2-chloro-1,1-dimethylethyl)-6-(phenylthio)- 124420-48-0 C14H14Cl2N2S
    Pyridazine, 3-chloro-4-(2-chloro-1,1-dimethylethyl)-6-(phenylthio)-
    —— Propionitrile, 2-chloro-3-(m-tolylthio)- 91587-53-0 C10H10ClNS
    Propionitrile, 2-chloro-3-(m-tolylthio)-
    —— Acetamide, N-formyl-2-(phenylthio)- 107265-23-6 C9H9NO2S
    Acetamide, N-formyl-2-(phenylthio)-
    —— 2-(4-chlorophenylthio)-3,3-dimethylbutanoic acid 110577-63-4 C12H15ClO2S
    2-(4-chlorophenylthio)-3,3-dimethylbutanoic acid
    —— 6-(4-chlorophenyl)sulfanyl-2-N,4-N-diethyl-1,3,5-triazine-2,4-diamine 6560-09-4 C13H16ClN5S
    6-(4-chlorophenyl)sulfanyl-2-N,4-N-diethyl-1,3,5-triazine-2,4-diamine
    —— Bithionolate sodium 6385-58-6 C12H4Cl4Na2O2S
    Bithionolate sodium