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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Ethylthio-3-n-propylthio-propan 4911-38-0 C8H18S2
    1-Ethylthio-3-n-propylthio-propan
    —— (4-phenyl-thiazol-2-ylmercapto)-acetic acid 15208-27-2 C11H9NO2S2
    (4-phenyl-thiazol-2-ylmercapto)-acetic acid
    —— 4,4,5-Trimethyl-4,5-dihydro-[1,2,5]thiadiazin-6-one 113817-46-2 C6H10N2OS
    4,4,5-Trimethyl-4,5-dihydro-[1,2,5]thiadiazin-6-one
    —— 2,2-Dimethyl-6-methylsulfon-capronitril 90950-52-0 C9H17NO2S
    2,2-Dimethyl-6-methylsulfon-capronitril
    —— 2-Chlor-6-phenylthiobenzonitril 38615-62-2 C13H8ClNS
    2-Chlor-6-phenylthiobenzonitril
    —— phenyl N-bis(dimethylamino)methylene-N'-phenylcarbamimidothioate 1564286-31-2 C18H22N4S
    phenyl N-bis(dimethylamino)methylene-N'-phenylcarbamimidothioate
    —— 1-((2-hydroxyethylthio)carbonyloxy)ethyl acetate 928370-73-4 C7H12O5S
    1-((2-hydroxyethylthio)carbonyloxy)ethyl acetate
    —— 3-(6-chloro-2-methyl-1-pyridin-3-yl-1H-indol-3-ylsulfanyl)-phenylboronic acid 1359982-14-1 C20H16BClN2O2S
    3-(6-chloro-2-methyl-1-pyridin-3-yl-1H-indol-3-ylsulfanyl)-phenylboronic acid
    —— 6-(3-Trifluoromethyl-phenylsulfanyl)-pteridine-2,4-diamine 77900-96-0 C13H9F3N6S
    6-(3-Trifluoromethyl-phenylsulfanyl)-pteridine-2,4-diamine
    —— 5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridin-2-carbonitrile 1454252-66-4 C13H7F3N2S
    5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridin-2-carbonitrile
    —— 4-((3-(trifluoromethyl)phenyl)thio)picolinonitrile 1374864-80-8 C13H7F3N2S
    4-((3-(trifluoromethyl)phenyl)thio)picolinonitrile
    —— 3-(3-trifluoromethylphenylthio)-5-methyl[1,2,4]triazine 1313039-57-4 C11H8F3N3S
    3-(3-trifluoromethylphenylthio)-5-methyl[1,2,4]triazine
    —— 2-chloro-4-[(3-trifluoromethyl)phenylthio]benzaldehyde 509088-81-7 C14H8ClF3OS
    2-chloro-4-[(3-trifluoromethyl)phenylthio]benzaldehyde
    —— 5-(3-Trifluoromethyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-30-4 C11H8F3NO2S3
    5-(3-Trifluoromethyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 1-ethyl-5-phenylthio-1H-1,2,4-triazole 535961-28-5 C10H11N3S
    1-ethyl-5-phenylthio-1H-1,2,4-triazole
    —— 3-hydroxy-4-cyano-5-phenylthioisothiazole 154845-93-9 C10H6N2OS2
    3-hydroxy-4-cyano-5-phenylthioisothiazole
    —— N-Hexyl-N-methylthiopivalamid 58832-24-9 C12H25NS
    N-Hexyl-N-methylthiopivalamid
    —— N-Athyl-N-methylthiopivalamid 58856-07-8 C8H17NS
    N-Athyl-N-methylthiopivalamid
    —— phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-β-ribo-hexopyranoside 241490-67-5 C20H25NO3S
    phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-β-ribo-hexopyranoside
    —— α-(phenylthio)-octyl cyanide 112921-77-4 C15H21NS
    α-(phenylthio)-octyl cyanide
    —— N-(2-Hydroxy-3-methylbutyl)-N-methylthiopivalamid 58832-29-4 C11H23NOS
    N-(2-Hydroxy-3-methylbutyl)-N-methylthiopivalamid
    —— 2,4-diamino-5-methyl-6-(3',5'-dimethylphenylthio)pyrrolo[2,3-d]pyrimidine 1221521-88-5 C15H17N5S
    2,4-diamino-5-methyl-6-(3',5'-dimethylphenylthio)pyrrolo[2,3-d]pyrimidine
    —— (3,5-dimethylphenyl)(ethyl)sulfane 1108726-18-6 C10H14S
    (3,5-dimethylphenyl)(ethyl)sulfane
    —— 3-(3,5-dimethylphenylsulfanyl)-propanoic acid 102143-17-9 C11H14O2S
    3-(3,5-dimethylphenylsulfanyl)-propanoic acid
    —— 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile 1185189-90-5 C15H14N2OS
    4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile
    —— 4-Chloro-3-(3,5-dimethylphenylthio)-9H-thioxanthen-9-one 1372152-31-2 C21H15ClOS2
    4-Chloro-3-(3,5-dimethylphenylthio)-9H-thioxanthen-9-one
    —— 2-Chloro-4-(3,5-dimethyl-phenylsulfanyl)-5-ethyl-6-methyl-3-nitro-pyridine 175437-67-9 C16H17ClN2O2S
    2-Chloro-4-(3,5-dimethyl-phenylsulfanyl)-5-ethyl-6-methyl-3-nitro-pyridine
    —— [4-<sup>14</sup>C]-(R)-2-(2-amino-5-((S)-1-phenylethylthio)thiazolo[4,5-d]pyrimidin-7-ylamino)-4-methylpentan-1-ol 1403762-01-5 C19H25N5OS2
    [4-<sup>14</sup>C]-(R)-2-(2-amino-5-((S)-1-phenylethylthio)thiazolo[4,5-d]pyrimidin-7-ylamino)-4-methylpentan-1-ol
    —— ethyl 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarboxylate 1185189-75-6 C17H19NO3S
    ethyl 4-(3,5-dimethylphenylsulfanyl)-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarboxylate
    —— ethyl 2-acetyl-5-[(3,5-dimethylphenyl)thio]-5-(p-tolyl)pentanoate 1338781-70-6 C24H30O3S
    ethyl 2-acetyl-5-[(3,5-dimethylphenyl)thio]-5-(p-tolyl)pentanoate
    —— 3-amino-1-methyl-5-(2-mercaptoethylthio)-1,2,4-triazole 150366-95-3 C5H10N4S2
    3-amino-1-methyl-5-(2-mercaptoethylthio)-1,2,4-triazole
    —— phenyl 3-allyloxycarbonylamino-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside 849071-48-3 C16H21NO4S
    phenyl 3-allyloxycarbonylamino-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside
    —— 2-(1-acetonylthio)-5-methylthiazolo(2,3-b)-1,3,4-thiadiazolium perchlorate 122841-09-2 C8H9N2OS3*ClO4
    2-(1-acetonylthio)-5-methylthiazolo(2,3-b)-1,3,4-thiadiazolium perchlorate
    —— phenyl 3-azido-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside 849071-47-2 C12H15N3O2S
    phenyl 3-azido-2,3,6-trideoxy-1-thio-L-lyxo-hexopyranoside
    —— 3-Phenylmercapto-acrylsaeure-chlorid 1077-15-2 C9H7ClOS
    3-Phenylmercapto-acrylsaeure-chlorid
    —— Methoxymethyl-vinyl-sulfid 4410-85-9 C4H8OS
    Methoxymethyl-vinyl-sulfid
    —— 5-chloromethyl-2,3-dihydro-7H-thiazolo<3,2-a>pyrimidin-7-one 111730-43-9 C7H7ClN2OS
    5-chloromethyl-2,3-dihydro-7H-thiazolo<3,2-a>pyrimidin-7-one
    —— 6-(4-fluorophenyl)-4-{[4-(trifluoromethyl)phenyl]thio}thieno[3,2-d]pyrimidine 1610410-47-3 C19H10F4N2S2
    6-(4-fluorophenyl)-4-{[4-(trifluoromethyl)phenyl]thio}thieno[3,2-d]pyrimidine
    —— 1-Cyclopent-1-enyl-2-methanesulfonyl-ethanone 74190-39-9 C8H12O3S
    1-Cyclopent-1-enyl-2-methanesulfonyl-ethanone
    —— 5-(4-nitro-phenylsulfanyl)-1<i>H</i>-tetrazole 91448-02-1 C7H5N5O2S
    5-(4-nitro-phenylsulfanyl)-1<i>H</i>-tetrazole
    —— 2-[(E)-2-(2-Chloro-phenyl)-vinyl]-3-phenylsulfanyl-quinoxaline 366018-64-6 C22H15ClN2S
    2-[(E)-2-(2-Chloro-phenyl)-vinyl]-3-phenylsulfanyl-quinoxaline
    —— ethyl 3-{4-cyano-5-[(2-ethoxy-2-oxoethyl)sulfanyl]-3-hydroxythiophen-2-yl}-3-oxopropanoate 1448180-44-6 C14H15NO6S2
    ethyl 3-{4-cyano-5-[(2-ethoxy-2-oxoethyl)sulfanyl]-3-hydroxythiophen-2-yl}-3-oxopropanoate
    —— 4,7,10-trioxa-1,13-dithia[13](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane 1009834-83-6 C24H30N2O3S2
    4,7,10-trioxa-1,13-dithia[13](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane
    —— 2-Methyl-2-(2-phenylsulfanyl-cyclopentyl)-[1,3]dioxolane 137846-59-4 C15H20O2S
    2-Methyl-2-(2-phenylsulfanyl-cyclopentyl)-[1,3]dioxolane
    —— 4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane sulfoxide 1303611-48-4 C20H22N2O2S2
    4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane sulfoxide
    —— 1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane 1303611-46-2 C21H24N2S2
    1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane
    —— 4,7,10,13-tetraoxa-1,16-dithia[16](6,6')-2,2'-bis(cyclopenta[c]pyridine-2-yl)cyclophane 1009834-84-7 C26H34N2O4S2
    4,7,10,13-tetraoxa-1,16-dithia[16](6,6')-2,2'-bis(cyclopenta[c]pyridine-2-yl)cyclophane
    —— 4,7-dioxa-1,10-dithia[10](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane 1009834-82-5 C22H26N2O2S2
    4,7-dioxa-1,10-dithia[10](6,6')-2,2'-bis(cyclopenta[c]pyridin-2-yl)cyclophane
    —— 4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane 1009834-81-4 C20H22N2OS2
    4-oxa-1,7-dithia[7](6,6')-2,2'-bis(cyclopenta[c]pyridine)cyclophane
    —— 5-(benzylthio)-3,4-cyclopenteno-6-methylpyridine 99702-57-5 C16H17NS
    5-(benzylthio)-3,4-cyclopenteno-6-methylpyridine