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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-((5-aminopyrimidin-4-yl)thio)propan-1-ol 1422469-87-1 C7H11N3OS
    3-((5-aminopyrimidin-4-yl)thio)propan-1-ol
    —— ethyl 3-ethylthio-2-hydroxy-2-trifluoromethyl-1,4-dioxane-3-carboxylate 310460-93-6 C10H15F3O5S
    ethyl 3-ethylthio-2-hydroxy-2-trifluoromethyl-1,4-dioxane-3-carboxylate
    —— 3-Brom-6-methylthio-1,2,4,5-tetrazin 64499-97-4 C3H3BrN4S
    3-Brom-6-methylthio-1,2,4,5-tetrazin
    —— 4-cyclohexyl-N-[2-[2-(4-cyclohexylbutylamino)ethylsulfonylsulfanyl]ethyl]butan-1-amine;hydron;dichloride —— C24H50Cl2N2O2S2
    4-cyclohexyl-N-[2-[2-(4-cyclohexylbutylamino)ethylsulfonylsulfanyl]ethyl]butan-1-amine;hydron;dichloride
    —— 3-(2-Cyanphenylthio)-6-methylthio-1,2,4,5-tetrazin 121288-79-7 C10H7N5S2
    3-(2-Cyanphenylthio)-6-methylthio-1,2,4,5-tetrazin
    —— 3-[(2-cyanophenyl)thio]-1,2-benzisothiazole 190970-00-4 C14H8N2S2
    3-[(2-cyanophenyl)thio]-1,2-benzisothiazole
    —— <4-Chlor-phenylmercapto>-essigsaeure-butylamid 91802-77-6 C12H16ClNOS
    <4-Chlor-phenylmercapto>-essigsaeure-butylamid
    —— Mono-ethylmercaptodiethoxymethan 25604-63-1 C7H16O2S
    Mono-ethylmercaptodiethoxymethan
    —— 1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-phenylsulfanyl-4-thioxo-3,4-dihydro-1H-pyrimidin-2-one 125057-09-2 C14H16N2O3S2
    1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-phenylsulfanyl-4-thioxo-3,4-dihydro-1H-pyrimidin-2-one
    —— 1-Trimethylsiloxy-1-phenylthio-2,2-difluoroethene 169199-37-5 C11H14F2OSSi
    1-Trimethylsiloxy-1-phenylthio-2,2-difluoroethene
    —— 1-(2-Hydroxy-ethoxymethyl)-3,5-dimethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione 132885-44-0 C15H18N2O4S
    1-(2-Hydroxy-ethoxymethyl)-3,5-dimethyl-6-phenylsulfanyl-1H-pyrimidine-2,4-dione
    —— 6-tert-Butylsulfanyl-1-(2-hydroxy-ethoxymethyl)-5-methyl-1H-pyrimidine-2,4-dione 131193-99-2 C12H20N2O4S
    6-tert-Butylsulfanyl-1-(2-hydroxy-ethoxymethyl)-5-methyl-1H-pyrimidine-2,4-dione
    —— 1-ethyl-6-(phenylthio)thymine 136160-20-8 C13H14N2O2S
    1-ethyl-6-(phenylthio)thymine
    —— 4,4,4-trifluorobutanethioamide 1184850-75-6 C4H6F3NS
    4,4,4-trifluorobutanethioamide
    —— 1-<<2-(benzyloxy)ethoxy>methyl>-6-(phenylthio)thymine 132774-36-8 C21H22N2O4S
    1-<<2-(benzyloxy)ethoxy>methyl>-6-(phenylthio)thymine
    —— 1-butyl-6-(phenylthio)thymine 136160-21-9 C15H18N2O2S
    1-butyl-6-(phenylthio)thymine
    —— 1-[(2-hydroxyethoxy)methyl]-3-benzyl-6-phenylthiothymine 132885-45-1 C21H22N2O4S
    1-[(2-hydroxyethoxy)methyl]-3-benzyl-6-phenylthiothymine
    —— 3,5-bis(methylsulfanyl)aniline 1352311-14-8 C8H11NS2
    3,5-bis(methylsulfanyl)aniline
    —— 1-Methyl-4-((E)-1-methyl-2-phenyl-vinylsulfanyl)-benzene 153215-23-7 C16H16S
    1-Methyl-4-((E)-1-methyl-2-phenyl-vinylsulfanyl)-benzene
    —— 2-Amino-4-(4-chloro-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 357289-62-4 C9H7ClN6S
    2-Amino-4-(4-chloro-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 3-Phenyl-1,4,2-benzodithiazine 77598-01-7 C13H9NS2
    3-Phenyl-1,4,2-benzodithiazine
    —— (2'R,3'R,4R,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<3'-<(4''-methylphenyl)thio>-3'-nitrooxiran-2'-yl>-1,3-dioxolane 157661-83-1 C21H33NO6SSi
    (2'R,3'R,4R,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<3'-<(4''-methylphenyl)thio>-3'-nitrooxiran-2'-yl>-1,3-dioxolane
    —— Z-(4S,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<2'-<(4''-methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane 157661-82-0 C21H33NO5SSi
    Z-(4S,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<2'-<(4''-methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane
    —— Phosphorothioic acid, O-(6-((4-chlorophenyl)thio)-3-pyridazinyl) O,O-diethyl ester 53605-09-7 C14H16ClN2O3PS2
    Phosphorothioic acid, O-(6-((4-chlorophenyl)thio)-3-pyridazinyl) O,O-diethyl ester
    —— 5-allyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-97-6 C13H19NO2S
    5-allyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-(2-hydroxyethylthio)-1-methyl-1H-tetrazole 136621-97-1 C4H8N4OS
    5-(2-hydroxyethylthio)-1-methyl-1H-tetrazole
    —— (E)-2-Methyl-3-phenylsulfanyl-prop-2-en-1-ol 401893-43-4 C10H12OS
    (E)-2-Methyl-3-phenylsulfanyl-prop-2-en-1-ol
    —— N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(R)-phenylethyl]amine 920512-69-2 C24H27NS2
    N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(R)-phenylethyl]amine
    —— 5-ethylthio-5-methyl-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-95-4 C11H17NO2S
    5-ethylthio-5-methyl-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-ethylthio-5-(1-hydroxyprop-1-yl)-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-08-2 C13H21NO3S
    5-ethylthio-5-(1-hydroxyprop-1-yl)-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(S)-phenylethyl]amine 920512-70-5 C24H27NS2
    N-[4,4-bis(phenylsulfanyl)but-1-yl]-N-[1(S)-phenylethyl]amine
    —— 5-benzyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134294-99-8 C17H21NO2S
    5-benzyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 5-acetyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one 134295-16-2 C12H17NO3S
    5-acetyl-5-ethylthio-4-(pyrrolidin-1-yl)furan-2(5H)-one
    —— 2-<Chlorfluor(trifluormethylthio)methylthio>pyrrol 62665-32-1 C6H4ClF4NS2
    2-<Chlorfluor(trifluormethylthio)methylthio>pyrrol
    —— 5-phenylthiothiophene-2-carboxylic acid 79504-97-5 C11H8O2S2
    5-phenylthiothiophene-2-carboxylic acid
    —— methyl ethylsulfonylacetate 42271-27-2 C5H10O4S
    methyl ethylsulfonylacetate
    —— (Z)-3-Fluoro-4-phenylsulfanyl-but-3-en-2-one 167965-53-9 C10H9FOS
    (Z)-3-Fluoro-4-phenylsulfanyl-but-3-en-2-one
    —— 2-(hexylthio)pyrimidine-4,5,6-triamine 1260177-43-2 C10H19N5S
    2-(hexylthio)pyrimidine-4,5,6-triamine
    —— 5-Nitroso-4,6-diamino-2-benzylmercapto-pyrimidin 52222-45-4 C11H11N5OS
    5-Nitroso-4,6-diamino-2-benzylmercapto-pyrimidin
    —— 2-Isopropylsulfonyl-ethylbromid 5755-75-9 C5H11BrO2S
    2-Isopropylsulfonyl-ethylbromid
    —— 2-n-Butylthio-5-nitroso-4,6-diaminopyrimidin 73000-29-0 C8H13N5OS
    2-n-Butylthio-5-nitroso-4,6-diaminopyrimidin
    —— 2-(isopropylsulfonyl)ethanol 98288-49-4 C5H12O3S
    2-(isopropylsulfonyl)ethanol
    —— 2-Isopropylmercapto-ethylbromid 5755-62-4 C5H11BrS
    2-Isopropylmercapto-ethylbromid
    —— 2,4-Bis-(2-methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-57-4 C20H17NS4
    2,4-Bis-(2-methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— 1-[4-(2-Methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-ethanone 147089-46-1 C14H13NOS2
    1-[4-(2-Methyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-ethanone
    —— 4-Benzylsulfanyl-5-(4-methyl-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine 212621-49-3 C19H15N3OS2
    4-Benzylsulfanyl-5-(4-methyl-oxazol-2-yl)-2-thiophen-2-yl-pyrimidine
    —— 5-(4-chlorophenyl)-3-(methylthio)isoxazole 120803-16-9 C10H8ClNOS
    5-(4-chlorophenyl)-3-(methylthio)isoxazole
    —— 2,2'-Dimesyloxy-N-methyldipropylamine picrylsulfonate 3545-54-8 C15H24N4O13S3
    2,2'-Dimesyloxy-N-methyldipropylamine picrylsulfonate
    —— 4-Benzylsulfanyl-5-(2H-tetrazol-5-yl)-2-thiophen-2-yl-pyrimidine 212621-45-9 C16H12N6S2
    4-Benzylsulfanyl-5-(2H-tetrazol-5-yl)-2-thiophen-2-yl-pyrimidine
    —— dimethyl-thiocarbamic acid S-(4-bromo-3,5-dimethyl-phenyl) ester 872254-86-9 C11H14BrNOS
    dimethyl-thiocarbamic acid S-(4-bromo-3,5-dimethyl-phenyl) ester