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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Butyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54456-71-2 C17H19N3O3S
    1-Butyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— 2-(phenylthio)isonicotinonitrile 1019524-32-3 C12H8N2S
    2-(phenylthio)isonicotinonitrile
    —— <i>N</i>-acetyl-sulfanilic acid-[4-(4-nitro-phenylsulfanyl)-anilide] 135209-93-7 C20H17N3O5S2
    <i>N</i>-acetyl-sulfanilic acid-[4-(4-nitro-phenylsulfanyl)-anilide]
    —— isobutyric acid-[4-(4-nitro-phenylsulfanyl)-anilide] 518010-58-7 C16H16N2O3S
    isobutyric acid-[4-(4-nitro-phenylsulfanyl)-anilide]
    —— S-phenyl 2,3-dideoxy-4,6-di-O-methyl-1-thio-α-D-erythro-hex-2-enopyranoside 112247-56-0 C14H18O3S
    S-phenyl 2,3-dideoxy-4,6-di-O-methyl-1-thio-α-D-erythro-hex-2-enopyranoside
    —— isovaleric acid-[4-(4-nitro-phenylsulfanyl)-anilide] 518010-59-8 C17H18N2O3S
    isovaleric acid-[4-(4-nitro-phenylsulfanyl)-anilide]
    —— 1-tert-Butyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-54-4 C17H19N3O3S
    1-tert-Butyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— 1-<2,2-bis(phenylthio)cyclohexyl>-3-methyl-2-pentene 152526-64-2 C24H30S2
    1-<2,2-bis(phenylthio)cyclohexyl>-3-methyl-2-pentene
    —— Trimethyl-((E)-1-phenylsulfanyl-non-1-enyl)-silane 148237-54-1 C18H30SSi
    Trimethyl-((E)-1-phenylsulfanyl-non-1-enyl)-silane
    —— diethyl 2-[3,3-bis(phenylsulfanyl)propyl]-2-(6-oxocyclohex-1-enyl)malonate 459167-87-4 C28H32O5S2
    diethyl 2-[3,3-bis(phenylsulfanyl)propyl]-2-(6-oxocyclohex-1-enyl)malonate
    —— Diethoxy(phenylthio)methane 25604-67-5 C11H16O2S
    Diethoxy(phenylthio)methane
    —— (1-Cyclopropyl-ethylsulfanyl)-benzene 113235-23-7 C11H14S
    (1-Cyclopropyl-ethylsulfanyl)-benzene
    —— S-phenyl 2,3,6-trideoxy-4-O-methyl-1-thio-α-L-erythro-hex-2-enopyranoside 112247-57-1 C13H16O2S
    S-phenyl 2,3,6-trideoxy-4-O-methyl-1-thio-α-L-erythro-hex-2-enopyranoside
    —— 2-Oxo-3-phenylsulfanyl-cyclopentanecarboxylic acid ethyl ester 78424-61-0 C14H16O3S
    2-Oxo-3-phenylsulfanyl-cyclopentanecarboxylic acid ethyl ester
    —— (5-fluoro-2,4-dinitrophenyl)phenylthioether 1246999-91-6 C12H7FN2O4S
    (5-fluoro-2,4-dinitrophenyl)phenylthioether
    —— N-Butylthiopropionamid 2955-70-6 C7H15NS
    N-Butylthiopropionamid
    —— 2-Methylmercapto-5-<4-methoxy-phenylmercapto>-pyrimidin-4-carbonsaeure 25818-48-8 C13H12N2O3S2
    2-Methylmercapto-5-<4-methoxy-phenylmercapto>-pyrimidin-4-carbonsaeure
    —— 4-Acetyl-1-[3-[[2-[N-[6-(1-piperidinyl)pyridin-2-yl]amino]thiazol-5-yl]thio]benzoyl]piperazine 439574-36-4 C26H30N6O2S2
    4-Acetyl-1-[3-[[2-[N-[6-(1-piperidinyl)pyridin-2-yl]amino]thiazol-5-yl]thio]benzoyl]piperazine
    —— Methyl-phenyl-carbamic acid 5-phenylsulfanyl-pyrazol-1-yl ester 548770-00-9 C17H15N3O2S
    Methyl-phenyl-carbamic acid 5-phenylsulfanyl-pyrazol-1-yl ester
    —— Methyl-phenyl-carbamic acid 2-methylsulfanyl-imidazol-1-yl ester 548767-33-5 C12H13N3O2S
    Methyl-phenyl-carbamic acid 2-methylsulfanyl-imidazol-1-yl ester
    —— (1R,2R,4R)-2-(1-cyanocyclopropylcarbamoyl)-4-phenylsulfanylcyclopentanecarboxylic acid ethyl ester 1258451-22-7 C19H22N2O3S
    (1R,2R,4R)-2-(1-cyanocyclopropylcarbamoyl)-4-phenylsulfanylcyclopentanecarboxylic acid ethyl ester
    —— 5-fluoro-2-(phenylthio)benzaldehyde 1158577-41-3 C13H9FOS
    5-fluoro-2-(phenylthio)benzaldehyde
    —— Methyl-phenyl-carbamic acid 2-phenylsulfanyl-imidazol-1-yl ester 548767-51-7 C17H15N3O2S
    Methyl-phenyl-carbamic acid 2-phenylsulfanyl-imidazol-1-yl ester
    —— 1-hydroxy-5-phenylsulfanylpyrazole 548770-01-0 C9H8N2OS
    1-hydroxy-5-phenylsulfanylpyrazole
    —— 4-heptylsulfanyl-phenol 41796-12-7 C13H20OS
    4-heptylsulfanyl-phenol
    —— 2-(ethoxycarbonylmethyl)-3-phenylthiomethyl cyclopentanone 62344-33-6 C16H20O3S
    2-(ethoxycarbonylmethyl)-3-phenylthiomethyl cyclopentanone
    —— 6-ethoxy-5-cyano-2-methylthio-4-thiomorpholino-pyrimidine 56035-96-2 C12H16N4OS2
    6-ethoxy-5-cyano-2-methylthio-4-thiomorpholino-pyrimidine
    —— 4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-59-8 C13H20N4O3S2
    4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 2-(2-benzyl-1,3-dithian-2-yl)acetaldehyde 1258948-52-5 C13H16OS2
    2-(2-benzyl-1,3-dithian-2-yl)acetaldehyde
    —— 4,8-Dithia-spiro[2.5]octan-1-ol 78633-19-9 C6H10OS2
    4,8-Dithia-spiro[2.5]octan-1-ol
    —— 5-cyano-2-methylthio-6-(n-propoxy)-4-thiomorpholino-pyrimidine 56036-00-1 C13H18N4OS2
    5-cyano-2-methylthio-6-(n-propoxy)-4-thiomorpholino-pyrimidine
    —— <2>Thienylmercapto-essigsaeure-amid 14725-29-2 C6H7NOS2
    <2>Thienylmercapto-essigsaeure-amid
    —— 6-methyl-2-methylthio-3-cyanomethyl-4-pyrimidone 148291-50-3 C8H9N3OS
    6-methyl-2-methylthio-3-cyanomethyl-4-pyrimidone
    —— 4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-55-4 C12H18N4O3S2
    4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine 56032-60-1 C13H20N4O4S
    4-(6-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine
    —— 5-cyano-2-methylthio-4-morpholino-6-(n-propoxy)-pyrimidine 56035-99-5 C13H18N4O2S
    5-cyano-2-methylthio-4-morpholino-6-(n-propoxy)-pyrimidine
    —— 2-chloro-8-phenethylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine 77748-97-1 C18H18ClN5S2
    2-chloro-8-phenethylthio-4-thiomorpholino-pyrimido-[5,4-d]-pyrimidine
    —— 4,6-dichloro-5-dichloromethyl-2-methylsulfanyl-pyrimidine 56032-82-7 C6H4Cl4N2S
    4,6-dichloro-5-dichloromethyl-2-methylsulfanyl-pyrimidine
    —— 2-chloro-4-morpholino-8-propylthio-pyrimido-[5,4-d]-pyrimidine 77748-85-7 C13H16ClN5OS
    2-chloro-4-morpholino-8-propylthio-pyrimido-[5,4-d]-pyrimidine
    —— 6-ethoxy-5-cyano-2-methylthio-4-morpholino-pyrimidine 56035-95-1 C12H16N4O2S
    6-ethoxy-5-cyano-2-methylthio-4-morpholino-pyrimidine
    —— 4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine 56032-56-5 C12H18N4O4S
    4-(6-isopropoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-morpholine
    —— 6-methyl-2-methylthio-4-cyanomethoxypyrimidine 148291-49-0 C8H9N3OS
    6-methyl-2-methylthio-4-cyanomethoxypyrimidine
    —— 6-ethoxy-5-cyano-2-methylthio-4-(1,1-dioxido-thiomorpholino)-pyrimidine 56035-94-0 C12H16N4O3S2
    6-ethoxy-5-cyano-2-methylthio-4-(1,1-dioxido-thiomorpholino)-pyrimidine
    —— methylthioketene 67730-68-1 C3H4S
    methylthioketene
    —— 2-chloro-8-cyclohexylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine 77748-90-4 C16H20ClN5OS
    2-chloro-8-cyclohexylthio-4-morpholino-pyrimido-[5,4-d]-pyrimidine
    —— 4-ethoxy-2-methylsulfanyl-6-(1-oxo-1λ<sup>4</sup>-thiomorpholin-4-yl)-pyrimidine-5-carbaldehyde 56032-84-9 C12H17N3O3S2
    4-ethoxy-2-methylsulfanyl-6-(1-oxo-1λ<sup>4</sup>-thiomorpholin-4-yl)-pyrimidine-5-carbaldehyde
    —— 4-(6-<i>sec</i>-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 56032-63-4 C13H20N4O3S2
    4-(6-<i>sec</i>-butoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine
    —— 4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide 56032-44-1 C11H16N4O5S2
    4-(6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1,1-dioxide
    —— 4-ethoxy-2-methylsulfanyl-6-thiomorpholin-4-yl-pyrimidine-5-carbaldehyde 56032-83-8 C12H17N3O2S2
    4-ethoxy-2-methylsulfanyl-6-thiomorpholin-4-yl-pyrimidine-5-carbaldehyde
    —— 4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-morpholine 56032-52-1 C12H18N4O4S
    4-(2-methylsulfanyl-5-nitro-6-propoxy-pyrimidin-4-yl)-morpholine