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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-methyl-4-(4'-methylphenyl)thio-5-nitroimidazole 113121-62-3 C11H11N3O2S
    1-methyl-4-(4'-methylphenyl)thio-5-nitroimidazole
    —— (2-Benzylsulfanyl-6-methyl-pyrimidin-4-yloxy)-acetic acid methyl ester 115996-86-6 C15H16N2O3S
    (2-Benzylsulfanyl-6-methyl-pyrimidin-4-yloxy)-acetic acid methyl ester
    —— (6-methyl-2-methylthio-4-pyrimidinyloxy)acetic acid amide 54069-05-5 C8H11N3O2S
    (6-methyl-2-methylthio-4-pyrimidinyloxy)acetic acid amide
    —— 2-ethyl-2-(1-hydroxybutyl)-1,3-dithiane 74647-07-7 C10H20OS2
    2-ethyl-2-(1-hydroxybutyl)-1,3-dithiane
    —— [3-(3-bromo-propane-1-sulfonyl)-propoxy]-tert-butyl-dimethyl-silane 1426800-40-9 C12H27BrO3SSi
    [3-(3-bromo-propane-1-sulfonyl)-propoxy]-tert-butyl-dimethyl-silane
    —— 3-[3-(tert-butyl-dimethyl-silanyloxy)-propane-1-sulfonyl]-propan-1-ol 1426800-36-3 C12H28O4SSi
    3-[3-(tert-butyl-dimethyl-silanyloxy)-propane-1-sulfonyl]-propan-1-ol
    —— 4,6,4',6'-tetramethyl-2,2'-propane-1,3-diylbissulfanyl-bis-pyrimidine 14961-46-7 C15H20N4S2
    4,6,4',6'-tetramethyl-2,2'-propane-1,3-diylbissulfanyl-bis-pyrimidine
    —— (2-Phenylsulfanyl-2-trimethylsilanylethynyl-cyclopropyl)-methanol 138806-40-3 C15H20OSSi
    (2-Phenylsulfanyl-2-trimethylsilanylethynyl-cyclopropyl)-methanol
    —— hydron;prop-2-enyl N,N'-dicyclohexylcarbamimidothioate;bromide —— C16H29BrN2S
    hydron;prop-2-enyl N,N'-dicyclohexylcarbamimidothioate;bromide
    —— 2-isothiocyanato-2,<i>N</i>,<i>N</i>-trimethyl-thiopropionamide 61796-06-3 C7H12N2S2
    2-isothiocyanato-2,<i>N</i>,<i>N</i>-trimethyl-thiopropionamide
    —— 4-pyridylsulfanyl phthalonitrile 808118-81-2 C13H7N3S
    4-pyridylsulfanyl phthalonitrile
    —— 3-tert-butyl-6-[(2,4-difluorophenyl)thio][1,2,4]triazolo[4,3-a]pyridine 876372-60-0 C16H15F2N3S
    3-tert-butyl-6-[(2,4-difluorophenyl)thio][1,2,4]triazolo[4,3-a]pyridine
    —— 2-[(3,4-dimethoxyphenyl)thio]pyrimidine 646511-20-8 C12H12N2O2S
    2-[(3,4-dimethoxyphenyl)thio]pyrimidine
    —— 2-(3,4-dimethoxyphenylthio)benzaldoxime 128958-96-3 C15H15NO3S
    2-(3,4-dimethoxyphenylthio)benzaldoxime
    —— dimethyldibenzotetrathiafulvalene 67855-76-9 C16H12S4
    dimethyldibenzotetrathiafulvalene
    —— (E)-1,1,1-Trifluoro-3-phenylsulfanyl-hept-5-en-2-one 177272-38-7 C13H13F3OS
    (E)-1,1,1-Trifluoro-3-phenylsulfanyl-hept-5-en-2-one
    —— 2,4-diamino-5-methyl-6-(3',4'-dimethoxyphenylsulfanyl)furo[2,3-d]pyrimidine 1217309-60-8 C15H16N4O3S
    2,4-diamino-5-methyl-6-(3',4'-dimethoxyphenylsulfanyl)furo[2,3-d]pyrimidine
    —— 2,4-diamino-5-isopropyl-6-(3',4'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-19-4 C17H21N5O2S
    2,4-diamino-5-isopropyl-6-(3',4'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 2-chloro-4-(3-nitrophenylsulphanyl)pyrimidine 213747-78-5 C10H6ClN3O2S
    2-chloro-4-(3-nitrophenylsulphanyl)pyrimidine
    —— 2,4-diamino-5-propyl-6-(3',4'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-11-6 C17H21N5O2S
    2,4-diamino-5-propyl-6-(3',4'-dimethoxyphenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 7-(methylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide 494226-34-5 C8H8N4OS
    7-(methylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide
    —— Trimethyl-(7-phenylsulfanyl-bicyclo[4.1.0]hept-7-ylethynyl)-silane 138806-42-5 C18H24SSi
    Trimethyl-(7-phenylsulfanyl-bicyclo[4.1.0]hept-7-ylethynyl)-silane
    —— methyl 4-methylbicyclo<2.2.2>oct-1-yl sulphoxide 54798-86-6 C10H18OS
    methyl 4-methylbicyclo<2.2.2>oct-1-yl sulphoxide
    —— (2-chlorothiazol-5-yl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate 1107009-17-5 C25H19ClF2N2S4
    (2-chlorothiazol-5-yl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate
    —— 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionamide 1107011-23-3 C21H17F2NS3
    3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionamide
    —— 4-Methyl-3-(methylthio)-1,2,4-triazol 21094-61-1 C4H7N3S
    4-Methyl-3-(methylthio)-1,2,4-triazol
    —— 1-triethylsilyl-3-phenylthio-1-propene 78750-39-7 C15H24SSi
    1-triethylsilyl-3-phenylthio-1-propene
    —— Trimethyl-(6-phenylsulfanyl-bicyclo[3.1.0]hex-6-ylethynyl)-silane 138806-41-4 C17H22SSi
    Trimethyl-(6-phenylsulfanyl-bicyclo[3.1.0]hex-6-ylethynyl)-silane
    —— Trimethyl <3-octyl-3-(phenylthio)prop-1-ynyl>silane 146916-44-1 C20H32SSi
    Trimethyl <3-octyl-3-(phenylthio)prop-1-ynyl>silane
    —— 3-<(E)-3-(Phenylthio)-2-methyl-1-propenyl>cyclohexanone 140926-65-4 C16H20OS
    3-<(E)-3-(Phenylthio)-2-methyl-1-propenyl>cyclohexanone
    —— (1-Methyl-2-phenylsulfanyl-2-trimethylsilanylethynyl-cyclopropyl)-methanol 138806-43-6 C16H22OSSi
    (1-Methyl-2-phenylsulfanyl-2-trimethylsilanylethynyl-cyclopropyl)-methanol
    —— S-Methyl-N-sek.butyl-isothioharnstoff 105208-39-7 C6H14N2S
    S-Methyl-N-sek.butyl-isothioharnstoff
    —— 2-amino-4-methyl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one 16025-03-9 C7H8N4OS
    2-amino-4-methyl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one
    —— 2-thioglyceraldehyde 15890-66-1 C3H6O2S
    2-thioglyceraldehyde
    —— 4-((phenylthio)methyl)-1H-1,2,3-triazole 1256164-24-5 C9H9N3S
    4-((phenylthio)methyl)-1H-1,2,3-triazole
    —— tert-Butyl 2-hydroxy-6-Phenylthiohex-4-ynylether 1098093-05-0 C16H22O2S
    tert-Butyl 2-hydroxy-6-Phenylthiohex-4-ynylether
    —— 6-phenylthio-3-hexyn-1-ol 144512-00-5 C12H14OS
    6-phenylthio-3-hexyn-1-ol
    —— 1-(4-chlorophenyl)-4-(phenylthio)but-2-yn-1-ol 1005787-72-3 C16H13ClOS
    1-(4-chlorophenyl)-4-(phenylthio)but-2-yn-1-ol
    —— 4-benzenesulfenylbut-2-ynal diethyl acetal 647009-97-0 C14H18O2S
    4-benzenesulfenylbut-2-ynal diethyl acetal
    —— Bis-<2-methyl-penten-(2)-yl-(1)>-sulfid 90850-90-1 C12H22S
    Bis-<2-methyl-penten-(2)-yl-(1)>-sulfid
    —— 1-isopentyl-5-((phenylthio)methyl)-1H-1,2,3-triazole 1280497-45-1 C14H19N3S
    1-isopentyl-5-((phenylthio)methyl)-1H-1,2,3-triazole
    —— 1-mercapto-4-methylbicyclo<2.2.2>octane 39825-77-9 C9H16S
    1-mercapto-4-methylbicyclo<2.2.2>octane
    —— ethyl (2-phenylthio)-2-(trifluoromethyl)-3,4-pentadienoate 134427-78-4 C14H13F3O2S
    ethyl (2-phenylthio)-2-(trifluoromethyl)-3,4-pentadienoate
    —— methyl 4-methylbicyclo<2.2.2>oct-1-yl sulphone 69855-48-7 C10H18O2S
    methyl 4-methylbicyclo<2.2.2>oct-1-yl sulphone
    —— 1-methylmercapto-4-methylbicyclo<2.2.2>octane 54461-02-8 C10H18S
    1-methylmercapto-4-methylbicyclo<2.2.2>octane
    —— 4-cyano-4-(5-fluoro-3-methylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran 179421-08-0 C13H14FNOS
    4-cyano-4-(5-fluoro-3-methylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran
    —— (Z)-3-(Methoxymethoxy)-5-(phenylthio)-4,6-heptadien-1-ol 128845-55-6 C15H20O3S
    (Z)-3-(Methoxymethoxy)-5-(phenylthio)-4,6-heptadien-1-ol
    —— 4-Methylthio-3-phenyl-5-cyano-1,3-thiazoline-2-thione 125011-70-3 C11H8N2S3
    4-Methylthio-3-phenyl-5-cyano-1,3-thiazoline-2-thione
    —— methyl 4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-4-ylthio)picolinate 1034922-37-6 C25H30N6O4S2
    methyl 4-(2-(5-(1-(tert-butoxycarbonyl)piperidin-4-ylamino)pyridin-2-ylamino)thiazol-4-ylthio)picolinate
    —— methyl 4-(2-(5-aminopyridin-2-ylamino)thiazol-4-ylthio)picolinate 1034922-35-4 C15H13N5O2S2
    methyl 4-(2-(5-aminopyridin-2-ylamino)thiazol-4-ylthio)picolinate