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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Amino-6-methylamino-4-aethylmercapto-pyrimidin 6940-38-1 C7H12N4S
    2-Amino-6-methylamino-4-aethylmercapto-pyrimidin
    —— 4-[2-[methyl[4-(phenylthio)pyridin-2-yl]amino]ethoxy]benzaldehyde 607723-99-9 C21H20N2O2S
    4-[2-[methyl[4-(phenylthio)pyridin-2-yl]amino]ethoxy]benzaldehyde
    —— 4,5-Bis-(2-chloro-ethylsulfanyl)-[1,3]dithiole-2-thione 138682-23-2 C7H8Cl2S5
    4,5-Bis-(2-chloro-ethylsulfanyl)-[1,3]dithiole-2-thione
    —— 2-[methyl[4-(phenylthio)pyridin-2-yl]amino]ethanol 607723-81-9 C14H16N2OS
    2-[methyl[4-(phenylthio)pyridin-2-yl]amino]ethanol
    —— 2-chloro-4-thiophenoxypyridine 334010-50-3 C11H8ClNS
    2-chloro-4-thiophenoxypyridine
    —— 4-[2-(methylthio)phenyl]-3-thiosemicarbazide 90180-64-6 C8H11N3S2
    4-[2-(methylthio)phenyl]-3-thiosemicarbazide
    —— 5-(N,N-dimethylamino)-2-(methylsulfanyl)-1-vinylpyrrole 1252928-35-0 C9H14N2S
    5-(N,N-dimethylamino)-2-(methylsulfanyl)-1-vinylpyrrole
    —— 7-chloromethyl-2-methylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidine-5-one 87572-21-2 C7H6ClN3OS2
    7-chloromethyl-2-methylthio-5H-1,3,4-thiadiazolo[3,2-a]pyrimidine-5-one
    —— 2-(4-bromo-phenylsulfanyl)-thioacetamide 59865-84-8 C8H8BrNS2
    2-(4-bromo-phenylsulfanyl)-thioacetamide
    —— 4-(3-Cyano-6-ethyl-5-methyl-pyridin-2-ylsulfanyl)-3-oxo-butyric acid ethyl ester 290299-60-4 C15H18N2O3S
    4-(3-Cyano-6-ethyl-5-methyl-pyridin-2-ylsulfanyl)-3-oxo-butyric acid ethyl ester
    —— 2-(hexafluoroisopropylidene)-3,3-bis(trifluoromethyl)thiirane 20728-39-6 C7F12S
    2-(hexafluoroisopropylidene)-3,3-bis(trifluoromethyl)thiirane
    —— Ph(Sn(n-Bu)3)S(CH2)3OtBu 1190600-14-6 C25H46OSSn
    Ph(Sn(n-Bu)3)S(CH2)3OtBu
    —— (2-Methyl-[1,3]dithiolan-2-yl)-methanol 136062-34-5 C5H10OS2
    (2-Methyl-[1,3]dithiolan-2-yl)-methanol
    —— 2-Amino-6-aethylamino-4-methylmercapto-pyrimidin 6266-69-9 C7H12N4S
    2-Amino-6-aethylamino-4-methylmercapto-pyrimidin
    —— Ph(Sn(n-Bu)3)S(CH2)3OMe 1190600-12-4 C22H40OSSn
    Ph(Sn(n-Bu)3)S(CH2)3OMe
    —— 2-(pyridin-2-ylthio)ethyl 3-oxobutanoate 1256945-14-8 C11H13NO3S
    2-(pyridin-2-ylthio)ethyl 3-oxobutanoate
    —— s-(3-Methylphenyl) methylcarbamothioate 29416-87-3 C9H11NOS
    s-(3-Methylphenyl) methylcarbamothioate
    —— 1,4-dithiepane-2-yl methacrylate 1184287-59-9 C9H14O2S2
    1,4-dithiepane-2-yl methacrylate
    —— N,N′-(2-((2-(bis(4-methoxybenzyl)amino)-4,6-diethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diyl)diacetamide 1268273-28-4 C32H37N7O6S
    N,N′-(2-((2-(bis(4-methoxybenzyl)amino)-4,6-diethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diyl)diacetamide
    —— N-(6-amino-2-((4,6-diethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-56-1 C19H25N7O4S
    N-(6-amino-2-((4,6-diethoxy-2-morpholinopyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— N-(6-amino-2-((4,6-diethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide 1268274-52-7 C20H27N7O3S
    N-(6-amino-2-((4,6-diethoxy-2-(piperidin-1-yl)pyrimidin-5-yl)thio)pyrimidin-4-yl)acrylamide
    —— (4-chloro-2-(methylthio)pyrimidin-5-yl)(cyclopropyl)methanone 1549785-62-7 C9H9ClN2OS
    (4-chloro-2-(methylthio)pyrimidin-5-yl)(cyclopropyl)methanone
    —— 4-hydroxy-2-ethyl-phenylsulfanyl-acetic acid ethyl ester 729590-59-4 C12H16O3S
    4-hydroxy-2-ethyl-phenylsulfanyl-acetic acid ethyl ester
    —— 1-(4-chloro-2-(methylthio)pyrimidin-5-yl)-2,2,2-trifluoroethanone 1549785-57-0 C7H4ClF3N2OS
    1-(4-chloro-2-(methylthio)pyrimidin-5-yl)-2,2,2-trifluoroethanone
    —— 2-Amino-6-aethylamino-4-benzylmercapto-pyrimidin 6940-39-2 C13H16N4S
    2-Amino-6-aethylamino-4-benzylmercapto-pyrimidin
    —— 4-chloro-6-methyl-6,7-dihydro-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-ol 19084-42-5 C7H8ClN3OS
    4-chloro-6-methyl-6,7-dihydro-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-ol
    —— 6-[(4-Chlorobenzyl)sulfanyl]-n4-methylpyrimidine-2,4-diamine 6940-40-5 C12H13ClN4S
    6-[(4-Chlorobenzyl)sulfanyl]-n4-methylpyrimidine-2,4-diamine
    —— 2-(Butylsulfanyl)-4,6-dimethylpyrimidine 55749-27-4 C10H16N2S
    2-(Butylsulfanyl)-4,6-dimethylpyrimidine
    —— 2-Amino-6-methylamino-4-methylmercapto-pyrimidin 89489-14-5 C6H10N4S
    2-Amino-6-methylamino-4-methylmercapto-pyrimidin
    —— 6-(4-fluorophenyl)ethynyl-2-methylthio-4-pyrrolidin-1-ylpyrimidine-5-carbaldehyde 1104638-81-4 C18H16FN3OS
    6-(4-fluorophenyl)ethynyl-2-methylthio-4-pyrrolidin-1-ylpyrimidine-5-carbaldehyde
    —— 2-[(2,6-dichloro-4-pyridinyl)-sulfanyl]acetyl chloride 389880-38-0 C7H4Cl3NOS
    2-[(2,6-dichloro-4-pyridinyl)-sulfanyl]acetyl chloride
    —— 1,1-bis-ethanesulfonyl-cyclohexane 500356-77-4 C10H20O4S2
    1,1-bis-ethanesulfonyl-cyclohexane
    —— bis-(1,2-dimethyl-propyl)-disulfane 57972-82-4 C10H22S2
    bis-(1,2-dimethyl-propyl)-disulfane
    —— (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-2-methyl-3-[(4-methylphenyl)sulfenyl]butanamide 144694-82-6 C12H17NO2S
    (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-2-methyl-3-[(4-methylphenyl)sulfenyl]butanamide
    —— (S<sub>2</sub>,R<sub>3</sub>)-2-hydroxy-2-methyl-3-[(4-methylphenyl)sulfenyl]butanamide 144694-81-5 C12H17NO2S
    (S<sub>2</sub>,R<sub>3</sub>)-2-hydroxy-2-methyl-3-[(4-methylphenyl)sulfenyl]butanamide
    —— 4-chloro-5-amino-6-cyanomethylthiopyrimidine 19144-84-4 C6H5ClN4S
    4-chloro-5-amino-6-cyanomethylthiopyrimidine
    —— 1'-methyl-3-(2-tolyl)-spiro<benzo<b>thiophene-2(3H),4'-piperidine> 132030-79-6 C20H23NS
    1'-methyl-3-(2-tolyl)-spiro<benzo<b>thiophene-2(3H),4'-piperidine>
    —— 2-(5-Methyl-3-phenyl-2-thioxo-2,3-dihydro-thiazolo[4,5-d]pyrimidin-7-ylsulfanyl)-acetamide 141622-27-7 C14H12N4OS3
    2-(5-Methyl-3-phenyl-2-thioxo-2,3-dihydro-thiazolo[4,5-d]pyrimidin-7-ylsulfanyl)-acetamide
    —— 2-Amino-6-methylamino-4-benzylmercapto-pyrimidin 6332-18-9 C12H14N4S
    2-Amino-6-methylamino-4-benzylmercapto-pyrimidin
    —— 3,5-Di(methylthio)-1,2-dithiolium-4-olat 84784-14-5 C5H6OS4
    3,5-Di(methylthio)-1,2-dithiolium-4-olat
    —— 1-ethoxy-1-butylsulfanyl-ethane 23785-42-4 C8H18OS
    1-ethoxy-1-butylsulfanyl-ethane
    —— (Z)-1-Ethoxy-4,4-dimethyl-2-phenylsulfanyl-pent-1-en-3-ol 210416-70-9 C15H22O2S
    (Z)-1-Ethoxy-4,4-dimethyl-2-phenylsulfanyl-pent-1-en-3-ol
    —— (1-(4-fluorophenyl)-2-nitroethyl) phenyl sulfide 110112-60-2 C14H12FNO2S
    (1-(4-fluorophenyl)-2-nitroethyl) phenyl sulfide
    —— (4S,6S,8S,10S,14R,20R)-4,6,8,14,20-pentamethoxy-12-(trimethylendithio)-1-tricosen-10-ol 136368-41-7 C31H60O6S2
    (4S,6S,8S,10S,14R,20R)-4,6,8,14,20-pentamethoxy-12-(trimethylendithio)-1-tricosen-10-ol
    —— 2-(3-bromophenylthio)-N,N-dimethylethanamine 144085-61-0 C10H14BrNS
    2-(3-bromophenylthio)-N,N-dimethylethanamine
    —— (Z)-4-Phenylsulfanyl-3-trimethylsilanylmethyl-but-3-en-2-ol 137845-38-6 C14H22OSSi
    (Z)-4-Phenylsulfanyl-3-trimethylsilanylmethyl-but-3-en-2-ol
    —— (Z)-3-Phenylsulfanyl-2-trimethylsilanylmethyl-propenal 137845-36-4 C13H18OSSi
    (Z)-3-Phenylsulfanyl-2-trimethylsilanylmethyl-propenal
    —— 4-((2-(pyridin-3-yl)thiazol-4-yl)methylthio)aniline 1048364-17-5 C15H13N3S2
    4-((2-(pyridin-3-yl)thiazol-4-yl)methylthio)aniline
    —— (2E,4E,6E)-8,8-dimethyl-2,4,6-tris(phenylthio)nona-2,4,6-trienal 210416-93-6 C29H28OS3
    (2E,4E,6E)-8,8-dimethyl-2,4,6-tris(phenylthio)nona-2,4,6-trienal
    —— (1Z,4Z,6Z)-1-Ethoxy-8,8-dimethyl-2,4,6-tris-phenylsulfanyl-nona-1,4,6-trien-3-ol 210416-92-5 C31H34O2S3
    (1Z,4Z,6Z)-1-Ethoxy-8,8-dimethyl-2,4,6-tris-phenylsulfanyl-nona-1,4,6-trien-3-ol