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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Ethylsulfanyl-5-isopropyl-6-methyl-3H-pyrimidin-4-one 115996-83-3 C10H16N2OS
    2-Ethylsulfanyl-5-isopropyl-6-methyl-3H-pyrimidin-4-one
    —— m-Methylthio-α-methylbenzylalkohol 58114-13-9 C9H12OS
    m-Methylthio-α-methylbenzylalkohol
    —— 5-Benzyl-3-bromomethyl-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-47-6 C16H17BrN2OS
    5-Benzyl-3-bromomethyl-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-Benzyl-2-(2,2-diethoxy-ethylsulfanyl)-5-ethyl-3H-pyrimidin-4-one 199851-93-9 C19H26N2O3S
    6-Benzyl-2-(2,2-diethoxy-ethylsulfanyl)-5-ethyl-3H-pyrimidin-4-one
    —— 5-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-15-8 C17H20N2O2S
    5-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-amino-4-(2-furyl)-2-methylthiopyridine-3,5-dicarbonitrile 161689-60-7 C12H8N4OS
    6-amino-4-(2-furyl)-2-methylthiopyridine-3,5-dicarbonitrile
    —— 2-(methylthiomethoxy)propanal 1268389-97-4 C5H10O2S
    2-(methylthiomethoxy)propanal
    —— (E)-2-(methylthiomethoxy)non-4-en-3-one 1268389-98-5 C11H20O2S
    (E)-2-(methylthiomethoxy)non-4-en-3-one
    —— (5S,6S)-5-(4-Chloro-phenylsulfanyl)-6-methoxy-dihydro-pyran-3-one 140886-26-6 C12H13ClO3S
    (5S,6S)-5-(4-Chloro-phenylsulfanyl)-6-methoxy-dihydro-pyran-3-one
    —— (5S,6S)-6-Methoxy-5-phenylsulfanyl-dihydro-pyran-3-one 140886-22-2 C12H14O3S
    (5S,6S)-6-Methoxy-5-phenylsulfanyl-dihydro-pyran-3-one
    —— (5S,6S)-6-Methoxy-5-p-tolylsulfanyl-dihydro-pyran-3-one 140886-23-3 C13H16O3S
    (5S,6S)-6-Methoxy-5-p-tolylsulfanyl-dihydro-pyran-3-one
    —— 2-((4-(trifluorovinyl)-phenyl)thio)-tetrafluoroethyl bromide 1165890-66-3 C10H4BrF7S
    2-((4-(trifluorovinyl)-phenyl)thio)-tetrafluoroethyl bromide
    —— 6-benzyl-5-ethyl-2-[(furan-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one 951764-41-3 C19H18N2O3S
    6-benzyl-5-ethyl-2-[(furan-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one
    —— tert-butyl-2-{[4-({(2-furylmethyl)[6-(4-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate 881687-24-7 C32H37N3O3S
    tert-butyl-2-{[4-({(2-furylmethyl)[6-(4-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate
    —— 7-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-32-9 C17H20N2O2S
    7-Benzyl-3-ethoxy-6-ethyl-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-75-5 C23H26N4S
    N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 2-(diethylamino)ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;dichloride —— C19H39Cl2N3S
    2-(diethylamino)ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;dichloride
    —— 5-Benzyl-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 199852-12-5 C16H18N2O2S
    5-Benzyl-6-ethyl-3-methoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one
    —— 6-benzyl-5-ethyl-2-[(thiophen-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one 951764-40-2 C19H18N2O2S2
    6-benzyl-5-ethyl-2-[(thiophen-2-ylcarbonylmethyl)thio]pyrimidin-4(3H)-one
    —— 7-Benzyl-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one 199852-33-0 C17H20N2O3S
    7-Benzyl-6-ethyl-3-(2-hydroxy-ethoxy)-2,3-dihydro-thiazolo[3,2-a]pyrimidin-5-one
    —— N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-74-4 C22H24N4S
    N<sup>4</sup>-cyclopentyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 2-Allylsulfanyl-6-benzyl-5-ethyl-3H-pyrimidin-4-one 199852-43-2 C16H18N2OS
    2-Allylsulfanyl-6-benzyl-5-ethyl-3H-pyrimidin-4-one
    —— tert-butyl-2-{[4-({(2-furylmethyl)[6-(3-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate 881687-23-6 C32H37N3O3S
    tert-butyl-2-{[4-({(2-furylmethyl)[6-(3-methylbenzyl)pyrimidin-4-yl]amino}methyl)phenyl]thio}-2-methylpropanoate
    —— O-MTM hydroxylamine hydrochloride 41108-17-2 C2H7NOS*ClH
    O-MTM hydroxylamine hydrochloride
    —— N<sup>4</sup>-phenylmethyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine 778594-76-6 C24H22N4S
    N<sup>4</sup>-phenylmethyl-2-phenylpyrimidine-6-phenylmethanesulfanyl-4,5-diamine
    —— 1,3,5-Triazine-2,4-diamine, 1,6-dihydro-6,6-dimethyl-1-(4-((4-nitrophenyl)thio)phenyl)-, monohydrochloride 13413-53-1 C17H19ClN6O2S
    1,3,5-Triazine-2,4-diamine, 1,6-dihydro-6,6-dimethyl-1-(4-((4-nitrophenyl)thio)phenyl)-, monohydrochloride
    —— 4'-Butoxy-4-aminodiphenylsulfid 62248-51-5 C16H19NOS
    4'-Butoxy-4-aminodiphenylsulfid
    —— 5-amino-4-chloro-2-phenyl-6-phenylmethanesulfanylpyrimidine 778594-73-3 C17H14ClN3S
    5-amino-4-chloro-2-phenyl-6-phenylmethanesulfanylpyrimidine
    —— (4-Hexadecylamino-phenylsulfanyl)-acetic acid 86410-27-7 C24H41NO2S
    (4-Hexadecylamino-phenylsulfanyl)-acetic acid
    —— 2-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-cyclohexyl-6-{[3-(diethylamino)propyl]-amino}pyridine-3,5-dicarbonitrile 1030622-88-8 C30H35ClN6S2
    2-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-cyclohexyl-6-{[3-(diethylamino)propyl]-amino}pyridine-3,5-dicarbonitrile
    —— 2-chloro-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-cyclohexylpyridine-3,5-dicarbonitrile 1030623-71-2 C23H18Cl2N4S2
    2-chloro-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}thio)-4-cyclohexylpyridine-3,5-dicarbonitrile
    —— 4-(4-ethoxy-phenylsulfanyl)-aniline 62248-53-7 C14H15NOS
    4-(4-ethoxy-phenylsulfanyl)-aniline
    —— (S)-2,2,2-Trifluoro-1-p-tolylsulfanylmethyl-ethylamine 177268-09-6 C10H12F3NS
    (S)-2,2,2-Trifluoro-1-p-tolylsulfanylmethyl-ethylamine
    —— ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;bromide —— C15H29BrN2S
    ethyl N,N'-dicyclohexylcarbamimidothioate;hydron;bromide
    —— 2-n-Butylthio-4,5,6-triaminopyrimidin 73000-32-5 C8H15N5S
    2-n-Butylthio-4,5,6-triaminopyrimidin
    —— 2-Methyl-1-(4-methylsulfanyl-phenyl)-3-[3-(2,3,5,6-tetrahydro-imidazo[2,1-b]thiazol-6-yl)-phenyl]-isothiourea 87023-18-5 C20H22N4S3
    2-Methyl-1-(4-methylsulfanyl-phenyl)-3-[3-(2,3,5,6-tetrahydro-imidazo[2,1-b]thiazol-6-yl)-phenyl]-isothiourea
    —— 5-n-propylthio-2-pyrrolylglyoxylic acid ethyl ester 75211-54-0 C11H15NO3S
    5-n-propylthio-2-pyrrolylglyoxylic acid ethyl ester
    —— 1-(3-fluorophenyl)thio-2-bromoethane 333782-25-5 C8H8BrFS
    1-(3-fluorophenyl)thio-2-bromoethane
    —— 3-(methylthiomethoxy)propan-1-ol 1206537-50-9 C5H12O2S
    3-(methylthiomethoxy)propan-1-ol
    —— 4-(methoxymethylthio)butan-1-ol 1206537-46-3 C6H14O2S
    4-(methoxymethylthio)butan-1-ol
    —— 2,2,2-trichloroethyl N-(4-p-methylthiophenyl-2-thiazolyl)carbamate 83758-14-9 C13H11Cl3N2O2S2
    2,2,2-trichloroethyl N-(4-p-methylthiophenyl-2-thiazolyl)carbamate
    —— 5-ethyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one 1075181-62-2 C21H18N2OS2
    5-ethyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one
    —— hydron;methyl N,N'-dicyclohexylcarbamimidothioate;iodide —— C14H26N2S*HI
    hydron;methyl N,N'-dicyclohexylcarbamimidothioate;iodide
    —— 2,5-bis((phenylmethyl)thio)pyridine 85330-77-4 C19H17NS2
    2,5-bis((phenylmethyl)thio)pyridine
    —— 2-hydroxy-2-(4-(methylthio)phenyl)-1-octyl-2,3-dihydro-1H-imidazo[1,2-a]pyrimidin-4-ium bromide 1313613-62-5 Br*C21H30N3OS
    2-hydroxy-2-(4-(methylthio)phenyl)-1-octyl-2,3-dihydro-1H-imidazo[1,2-a]pyrimidin-4-ium bromide
    —— 1,1-dioxothietan-3-amine hydrochloride 1422344-24-8 C3H7NO2S*ClH
    1,1-dioxothietan-3-amine hydrochloride
    —— phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 125654-35-5 C18H28O3SSi
    phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside
    —— 4-nitro-5-phenylthioimidazole 113121-60-1 C9H7N3O2S
    4-nitro-5-phenylthioimidazole
    —— 1-methyl-5-nitro-4-phenylthioimidazole 32057-98-0 C10H9N3O2S
    1-methyl-5-nitro-4-phenylthioimidazole
    —— 6-(4-chlorophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine 1076691-19-4 C23H21ClN2S2
    6-(4-chlorophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine