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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,3,4-Thiadiazol-2-amine, 5-((4-aminophenyl)thio)- 64070-79-7 C8H8N4S2
    1,3,4-Thiadiazol-2-amine, 5-((4-aminophenyl)thio)-
    —— 11-carbamimidoylsulfanylundecyl carbamimidothioate;hydron;dibromide —— C13H30Br2N4S2
    11-carbamimidoylsulfanylundecyl carbamimidothioate;hydron;dibromide
    —— Sulfonium, dimethyl(2-((10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxy)ethyl)-, iodide 64036-96-0 C16H17IN2O2S2
    Sulfonium, dimethyl(2-((10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxy)ethyl)-, iodide
    —— 1-(Carbamimidoylsulfanyl)-2-methoxyethane hydrobromide 64039-34-5 C4H11BrN2OS
    1-(Carbamimidoylsulfanyl)-2-methoxyethane hydrobromide
    —— Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydrochloride 64039-31-2 C19H41ClN2S
    Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydrochloride
    —— 5-(N'-acetylcarbamimidoyl)sulfanylpentyl N'-acetylcarbamimidothioate;hydron;dichloride —— C11H22Cl2N4O2S2
    5-(N'-acetylcarbamimidoyl)sulfanylpentyl N'-acetylcarbamimidothioate;hydron;dichloride
    —— 2-(N,N-Dimethylaminopropyl)-4,4'-dichlorodiphenyl sulfide hydrochloride 63979-98-6 C17H20Cl3NS
    2-(N,N-Dimethylaminopropyl)-4,4'-dichlorodiphenyl sulfide hydrochloride
    —— Sulfide, bis(2-amino-5-chlorophenyl), hydrochloride, hydrate 63979-93-1 C12H13Cl3N2OS
    Sulfide, bis(2-amino-5-chlorophenyl), hydrochloride, hydrate
    —— Ammonium, diisopropylmethyl(2-(10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxyethyl)-, iodide 63977-43-5 C21H28IN3O2S
    Ammonium, diisopropylmethyl(2-(10H-pyrido(3,2-b)(1,4)benzothiazin-10-yl)carbonyloxyethyl)-, iodide
    —— 2-(4-chlorophenyl)sulfanyl-N,N-dimethylpropan-1-amine;hydron;chloride —— C11H17Cl2NS
    2-(4-chlorophenyl)sulfanyl-N,N-dimethylpropan-1-amine;hydron;chloride
    —— 2-[bis(2-methylpropyl)amino]ethyl carbamimidothioate;hydron;dichloride —— C11H27Cl2N3S
    2-[bis(2-methylpropyl)amino]ethyl carbamimidothioate;hydron;dichloride
    —— hydron;10-(N,N,N'-trimethylcarbamimidoyl)sulfanyldecyl N,N,N'-trimethylcarbamimidothioate;dibromide —— C18H40Br2N4S2
    hydron;10-(N,N,N'-trimethylcarbamimidoyl)sulfanyldecyl N,N,N'-trimethylcarbamimidothioate;dibromide
    —— [Amino-[10-[amino(azaniumylidene)methyl]sulfanyldecylsulfanyl]methylidene]azanium;dibromide —— C12H28Br2N4S2
    [Amino-[10-[amino(azaniumylidene)methyl]sulfanyldecylsulfanyl]methylidene]azanium;dibromide
    —— Methyl-phosphonothioic acid O-(2-ethylsulfanyl-6-methyl-pyrimidin-4-yl) ester O-methyl ester 63815-54-3 C9H15N2O2PS2
    Methyl-phosphonothioic acid O-(2-ethylsulfanyl-6-methyl-pyrimidin-4-yl) ester O-methyl ester
    —— Pseudourea, 2-thio-, 4-amino-4-carboxy-n-butyl-, dibromide 63679-72-1 C6H15Br2N3O2S
    Pseudourea, 2-thio-, 4-amino-4-carboxy-n-butyl-, dibromide
    —— 1,3-Diethyl-2-hexadecyl-2-thiopseudourea hydrochloride 63680-38-6 C21H45ClN2S
    1,3-Diethyl-2-hexadecyl-2-thiopseudourea hydrochloride
    —— [Amino-[4-[amino(azaniumylidene)methyl]sulfanylbut-2-ynylsulfanyl]methylidene]azanium;dichloride —— C6H12Cl2N4S2
    [Amino-[4-[amino(azaniumylidene)methyl]sulfanylbut-2-ynylsulfanyl]methylidene]azanium;dichloride
    —— 1-Pyrrolidinepropanamine, N-(4-chloro-2-((4-chlorophenyl)thio)phenyl)-, monohydrochloride, hemihydrate 63716-99-4 C38H48Cl6N4OS2
    1-Pyrrolidinepropanamine, N-(4-chloro-2-((4-chlorophenyl)thio)phenyl)-, monohydrochloride, hemihydrate
    —— Pyridine, 4-(3-(phenylthio)propyl)-, hydrochloride 63681-08-3 C14H16ClNS
    Pyridine, 4-(3-(phenylthio)propyl)-, hydrochloride
    —— [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;diacetate 63679-86-7 C9H21N3O4S
    [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;diacetate
    —— 2-Decyl-1,3-diethyl-2-thiopseudourea hydriodide 63680-31-9 C15H33IN2S
    2-Decyl-1,3-diethyl-2-thiopseudourea hydriodide
    —— N,N'-dimethyl(dodecylsulfanyl)methanimidamide hydrobromide 63680-50-2 C15H33BrN2S
    N,N'-dimethyl(dodecylsulfanyl)methanimidamide hydrobromide
    —— 1,3-Dimethyl-2-tetradecyl-2-thiopseudourea hydrochloride 63680-47-7 C17H37ClN2S
    1,3-Dimethyl-2-tetradecyl-2-thiopseudourea hydrochloride
    —— 2-Decyl-1,3-diethyl-2-thiopseudourea hydrobromide 63680-32-0 C15H33BrN2S
    2-Decyl-1,3-diethyl-2-thiopseudourea hydrobromide
    —— Pseudourea, 1,3-diethyl-2-hexadecyl-2-thio-, hydrobromide 63680-37-5 C21H45BrN2S
    Pseudourea, 1,3-diethyl-2-hexadecyl-2-thio-, hydrobromide
    —— hydron;tetradecyl N,N'-dimethylcarbamimidothioate;bromide —— C17H37BrN2S
    hydron;tetradecyl N,N'-dimethylcarbamimidothioate;bromide
    —— hydron;tetradecyl N,N'-diethylcarbamimidothioate;bromide —— C19H41BrN2S
    hydron;tetradecyl N,N'-diethylcarbamimidothioate;bromide
    —— N,N'-diethyl(dodecylsulfanyl)methanimidamide hydrobromide 63680-49-9 C17H37BrN2S
    N,N'-diethyl(dodecylsulfanyl)methanimidamide hydrobromide
    —— decyl N,N'-dimethylcarbamimidothioate;hydron;chloride —— C13H29ClN2S
    decyl N,N'-dimethylcarbamimidothioate;hydron;chloride
    —— 2-Decyl-1,3-dimethyl-2-thiopseudourea hydrobromide 63680-33-1 C13H29BrN2S
    2-Decyl-1,3-dimethyl-2-thiopseudourea hydrobromide
    —— Orthobenzoic acid, p-(methylthio)-, cyclic ester with 2-(hydroxymethyl)-2-propyl-1,3-propanediol 97720-18-8 C15H20O3S
    Orthobenzoic acid, p-(methylthio)-, cyclic ester with 2-(hydroxymethyl)-2-propyl-1,3-propanediol
    —— Quinolinium, 1-ethyl-6-methyl-2-(phenylthio)-, salt with 4-methylbenzenesulfonic acid (1:1) 63512-57-2 C25H25NO3S2
    Quinolinium, 1-ethyl-6-methyl-2-(phenylthio)-, salt with 4-methylbenzenesulfonic acid (1:1)
    —— 6-carbamimidoylsulfanylhexyl carbamimidothioate;hydron;dibromide —— C8H20Br2N4S2
    6-carbamimidoylsulfanylhexyl carbamimidothioate;hydron;dibromide
    —— 2-Dodecyl-1,3-diethyl-2-thiopseudourea hydrochloride 62214-18-0 C17H37ClN2S
    2-Dodecyl-1,3-diethyl-2-thiopseudourea hydrochloride
    —— Phenol, thiobis[tetrapropylene- 68815-67-8 C36H58O2S
    Phenol, thiobis[tetrapropylene-
    —— butyl N,N-dibutylcarbamimidothioate;hydron;bromide —— C13H29BrN2S
    butyl N,N-dibutylcarbamimidothioate;hydron;bromide
    —— Methanediamine, N,N'-bis[2-[[[(2-aminophenyl)thio]methyl]thio]phenyl]- 68758-72-5 C27H28N4S4
    Methanediamine, N,N'-bis[2-[[[(2-aminophenyl)thio]methyl]thio]phenyl]-
    —— Silver, [bis[(trifluoromethyl)sulfonyl-kappaO]methanato]- 68785-05-7 Ag*C3HF6O4S2
    Silver, [bis[(trifluoromethyl)sulfonyl-kappaO]methanato]-
    —— 4,7-Dimethyl-2-(3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one 68516-80-3 C18H12O2S2
    4,7-Dimethyl-2-(3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one
    —— Thiols, C10-20, gamma-omega-perfluoro 68140-21-6 C10H7F15S
    Thiols, C10-20, gamma-omega-perfluoro
    —— 4-(n-propylthio)-2,3,5-trichloropyridine 60613-17-4 C8H8Cl3NS
    4-(n-propylthio)-2,3,5-trichloropyridine
    —— Pseudourea, 2,2'-(2-butenylene)dithiodi-, dihydrochloride 60784-24-9 C6H14Cl2N4S2
    Pseudourea, 2,2'-(2-butenylene)dithiodi-, dihydrochloride
    —— Nickel, (2-propanol)[[2,2'-(thio-kappaS)bis[4-(1,1,3,3-tetramethylbutyl)phenolato-kappaO]](2-)]- 67763-27-3 C31H48NiO3S
    Nickel, (2-propanol)[[2,2'-(thio-kappaS)bis[4-(1,1,3,3-tetramethylbutyl)phenolato-kappaO]](2-)]-
    —— 2,5-diethoxy-4-(4-methylphenyl)sulfanylbenzenediazonium;hydron;sulfate —— C17H20N2O6S2
    2,5-diethoxy-4-(4-methylphenyl)sulfanylbenzenediazonium;hydron;sulfate
    —— 12-carbamimidoylsulfanyldodecyl carbamimidothioate;hydron;dibromide —— C14H32Br2N4S2
    12-carbamimidoylsulfanyldodecyl carbamimidothioate;hydron;dibromide
    —— Benzenediazonium, 2,5-diethoxy-4-[(4-methylphenyl)thio]- 48193-77-7 C17H19N2O2S+
    Benzenediazonium, 2,5-diethoxy-4-[(4-methylphenyl)thio]-
    —— 3-(1,2-Dimethylpropyl) 1-ethyl thiodicarbonate 65573-08-2 C9H16O3S2
    3-(1,2-Dimethylpropyl) 1-ethyl thiodicarbonate
    —— methyl 2,3,4-trichlorophenyl sulphide 98420-62-3 C7H5Cl3S
    methyl 2,3,4-trichlorophenyl sulphide
    —— 2-Propenamide, N-(6-(1,1-dimethylethyl)-3-(methylthio)-5-oxo-1,2,4-triazin-4(5H)-yl)-N-(1-oxo-2-propenyl)- 90168-77-7 C14H18N4O3S
    2-Propenamide, N-(6-(1,1-dimethylethyl)-3-(methylthio)-5-oxo-1,2,4-triazin-4(5H)-yl)-N-(1-oxo-2-propenyl)-
    —— [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;dibromide 1704-03-6 C5H15Br2N3S
    [Amino(2-azaniumylethylsulfanyl)methylidene]-ethylazanium;dibromide